Ontology highlight
ABSTRACT:
SUBMITTER: Canton M
PROVIDER: S-EPMC8323096 | biostudies-literature | 2021 Jul
REPOSITORIES: biostudies-literature
Canton Martina M Groppi Jessica J Casimiro Lorenzo L Corra Stefano S Baroncini Massimo M Silvi Serena S Credi Alberto A
Journal of the American Chemical Society 20210720 29
We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices. ...[more]