Dataset Information

Electrochemically Deposited Amorphous Cobalt-Nickel-Doped Copper Oxide as an Efficient Electrocatalyst toward Water Oxidation Reaction.

ABSTRACT: Production of hydrogen through water splitting is one of the green and the most practical solutions to cope with the energy crisis and greenhouse effect. However, oxygen evolution reaction (OER) being a sluggish step, the use of precious metal-based catalysts is the main impediment toward the viability of water splitting. In this work, amorphous copper oxide and doped binary- and ternary-metal oxides (containing Co^II, Ni^II, and Cu^II) have been prepared on the surface of fluorine-doped tin oxide by a facile electrodeposition route followed by thermal treatment. The fabricated electrodes have been employed as efficient binder-free OER electrocatalysts possessing a high electrochemical surface area due to their amorphous nature. The cobalt-nickel-doped copper oxide (ternary-metal oxide)-based electrode showed promising OER activity with a high current density of 100 mA cm^-2 at 1.65 V versus RHE that escalates to 313 mA cm^-2 at 1.76 V in alkaline media at pH 14. The high activity of the ternary-metal oxide-based electrode was further supported by a smaller semicircle in the Nyquist plot. Furthermore, all metal-oxide-based electrodes offered high stability when tested for continuous production of oxygen for 50 h. This work highlights the synthesis of efficient and cost-effective amorphous metal-based oxide catalysts to execute electrocatalytic OER employing an electrodeposition approach.

SUBMITTER: Asghar MA

PROVIDER: S-EPMC8340103 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:The development of efficient and stable earth-abundant water oxidation catalysts is vital for economically feasible water-splitting systems. Cobalt phosphate (CoPi)-based catalysts belong to the relevant class of nonprecious electrocatalysts studied for the oxygen evolution reaction (OER). In this work, an in-depth investigation of the electrochemical activation of CoPi-based electrocatalysts by cyclic voltammetry (CV) is presented. Atomic layer deposition (ALD) is adopted because it enables the synthesis of CoPi films with cobalt-to-phosphorous ratios between 1.4 and 1.9. It is shown that the pristine chemical composition of the CoPi film strongly influences its OER activity in the early stages of the activation process as well as after prolonged exposure to the electrolyte. The best performing CoPi catalyst, displaying a current density of 3.9 mA cm-2 at 1.8 V versus reversible hydrogen electrode and a Tafel slope of 155 mV/dec at pH 8.0, is selected for an in-depth study of the evolution of its electrochemical properties, chemical composition, and electrochemical active surface area (ECSA) during the activation process. Upon the increase of the number of CV cycles, the OER performance increases, in parallel with the development of a noncatalytic wave in the CV scan, which points out to the reversible oxidation of Co2+ species to Co3+ species. X-ray photoelectron spectroscopy and Rutherford backscattering measurements indicate that phosphorous progressively leaches out the CoPi film bulk upon prolonged exposure to the electrolyte. In parallel, the ECSA of the films increases by up to a factor of 40, depending on the initial stoichiometry. The ECSA of the activated CoPi films shows a universal linear correlation with the OER activity for the whole range of CoPi chemical composition. It can be concluded that the adoption of ALD in CoPi-based electrocatalysis enables, next to the well-established control over film growth and properties, to disclose the mechanisms behind the CoPi electrocatalyst activation.

Dataset Information

Electrochemically Deposited Amorphous Cobalt-Nickel-Doped Copper Oxide as an Efficient Electrocatalyst toward Water Oxidation Reaction.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets