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Photoenhanced Water Electrolysis in Separate O₂ and H₂ Cells Using Pseudocapacitive Electrodes.

ABSTRACT: Water electrolysis has received much attention in recent years as a means of sustainable H₂ production. However, many challenges remain in obtaining high-purity H₂ and making large-scale production cost-effective. This study provides a strategy for integrating a two-cell water electrolysis system with solar energy storage. In our proposed system, CuO-Cu(OH)₂/Cu₂O was used as a redox mediator between oxygen and hydrogen evolution components. The system not only overcame the gas-mixing issue but also showed high gas generation performance. The redox reaction (charge/discharge) of CuO-Cu(OH)₂/Cu₂O led to a significant increase (51%) in the initial rate of H₂ production from 111.7 μmol h^-1 cm^-2 in the dark to 168.9 μmol h^-1 cm^-2 under solar irradiation. The effects of light on the redox reaction of CuO-Cu(OH)₂/Cu₂O during water electrolysis were investigated by in situ X-ray absorption and photoemission spectroscopy. These results suggest that surface oxygen vacancies are created under irradiation and play an important role in increased capacitance and gas generation. These findings provide a new path to direct storage of abundant solar energy and low-cost sustainable hydrogen production.

SUBMITTER: Musikajaroen S

PROVIDER: S-EPMC8340381 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Any substantial move of energy sources from fossil fuels to renewable resources requires large scale storage of excess energy, for example, via power to fuel processes. In this respect electrochemical reduction of CO2 may become very important, since it offers a method of sustainable CO production, which is a crucial prerequisite for synthesis of sustainable fuels. Carbon dioxide reduction in solid oxide electrolysis cells (SOECs) is particularly promising owing to the high operating temperature, which leads to both improved thermodynamics and fast kinetics. Additionally, compared to purely chemical CO formation on oxide catalysts, SOECs have the outstanding advantage that the catalytically active oxygen vacancies are continuously formed at the counter electrode, and move to the working electrode where they reactivate the oxide surface without the need of a preceding chemical (e.g., by H2) or thermal reduction step. In the present work, the surface chemistry of (La,Sr)FeO3-? and (La,Sr)CrO3-? based perovskite-type electrodes was studied during electrochemical CO2 reduction by means of near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) at SOEC operating temperatures. These measurements revealed the formation of a carbonate intermediate, which develops on the oxide surface only upon cathodic polarization (i.e., under sufficiently reducing conditions). The amount of this adsorbate increases with increasing oxygen vacancy concentration of the electrode material, thus suggesting vacant oxygen lattice sites as the predominant adsorption sites for carbon dioxide. The correlation of carbonate coverage and cathodic polarization indicates that an electron transfer is required to form the carbonate and thus to activate CO2 on the oxide surface. The results also suggest that acceptor doped oxides with high electron concentration and high oxygen vacancy concentration may be particularly suited for CO2 reduction. In contrast to water splitting, the CO2 electrolysis reaction was not significantly affected by metallic particles, which were exsolved from the perovskite electrodes upon cathodic polarization. Carbon formation on the electrode surface was only observed under very strong cathodic conditions, and the carbon could be easily removed by retracting the applied voltage without damaging the electrode, which is particularly promising from an application point of view.

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Photoenhanced Water Electrolysis in Separate O₂ and H₂ Cells Using Pseudocapacitive Electrodes.

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Dataset Information

Photoenhanced Water Electrolysis in Separate O2 and H2 Cells Using Pseudocapacitive Electrodes.

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OmicsDI is part of the ELIXIR infrastructure

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Photoenhanced Water Electrolysis in Separate O₂ and H₂ Cells Using Pseudocapacitive Electrodes.