Dataset Information

Crystallographic characterization of rare-earth cyano-tri-phenyl-borate complexes and the cyano-borates [NCBPh₃]^1-, [NCBPh₂Me]^1-, and [NCBPh₂(μ-O)BPh₂]¹.

ABSTRACT: The investigation of the coordination chemistry of rare-earth metal complexes with cyanide ligands led to the isolation and crystallographic characterization of the Ln ^III cyano-tri-phenyl-borate complexes di-chlorido-(cyano-tri-phenyl-borato-κN)tetra-kis-(tetra-hydro-furan-κO)lanthanide(III), [LnCl₂(C₁₉H₁₅BN)(C₄H₈O)₄] [lanthanide (Ln) = dysprosium (Dy) and yttrium Y)] from reactions of LnCl₃, KCN, and NaBPh₄. Attempts to independently synthesize the tetra-ethyl-ammonium salt of (NCBPh₃)^- from BPh₃ and [NEt₄][CN] in THF yielded crystals of the phenyl-substituted cyclic borate, tetra-ethyl-aza-nium 2,2,4,6-tetra-phe

SUBMITTER: Dumas MT

PROVIDER: S-EPMC8340972 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

Crystallographic characterization of rare-earth cyano-tri-phenyl-borate complexes and the cyano-borates [NCBPh₃]^1-, [NCBPh₂Me]^1-, and [NCBPh₂(μ-O)BPh₂]¹.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Crystallographic characterization of rare-earth cyano-tri-phenyl-borate complexes and the cyano-borates [NCBPh3]1-, [NCBPh2Me]1-, and [NCBPh2(μ-O)BPh2]1.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystallographic characterization of rare-earth cyano-tri-phenyl-borate complexes and the cyano-borates [NCBPh₃]^1-, [NCBPh₂Me]^1-, and [NCBPh₂(μ-O)BPh₂]¹.