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Construction of a Phytic Acid-Silica System in Wood for Highly Efficient Flame Retardancy and Smoke Suppression.

ABSTRACT: The intrinsic flammability of wood restricts its application in various fields. In this study, we constructed a phytic acid (PA)-silica hybrid system in wood by a vacuum-pressure impregnation process to improve its flame retardancy and smoke suppression. The system was derived from a simple mixture of PA and silica sol. Fourier transform infrared spectroscopy (FTIR) indicated an incorporation of the PA molecules into the silica network. Thermogravimetric (TG) analysis showed that the system greatly enhanced the char yield of wood from 1.5% to 32.1% (in air) and the thermal degradation rates were decreased. The limiting oxygen index (LOI) of the PA/silica-nanosol-treated wood was 47.3%. Cone calorimetry test (CCT) was conducted, which revealed large reductions in the heat release rate and smoke production rate. The appearance of the second heat release peak was delayed, indicating the enhanced thermal stability of the char residue. The mechanism underlying flame retardancy was analyzed by field-emission scanning electron microscope coupled with energy-dispersive spectroscopy (SEM-EDS), FTIR, and TG-FTIR. The improved flame retardancy and smoke-suppression property of the wood are mainly attributed to the formation of an intact and coherent char residue with crosslinked structures, which can protect against the transfer of heat and mass (flammable gases, smoke) during burning. Moreover, the hybrid system did not significantly alter the mechanical properties of wood, such as compressive strength and hardness. This approach can be extended to fabricate other phosphorus and silicon materials for enhancing the fire safety of wood.

SUBMITTER: Chen Z

PROVIDER: S-EPMC8347795 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:To improve the fire hazard of epoxy resin (EP), phosphomolybdate (PMoA), as a classical Keggin cluster, was successfully intercalated into Mg, Al, and Zn layered double hydrotalcite (LDH) by the reconstruction method, and it was denoted as MgAlZn-LDH-PMoA. The structure and morphology of MgAlZn-LDH-PMoA were characterized by X-ray diffraction and Fourier transform infrared spectroscopy. Subsequently, hexa(4-aminophenoxy)cyclotriphosphazene (HACP) was prepared and characterized as a high-performance organic flame retardant, which is rich in flame elements phosphorus and nitrogen. The synergistic effects of MgAlZn-LDH-PMoA and HACP on the fire safety of EP composites loaded with different amounts of flame retardant hybrids were studied in detail. Thermogravimetric analysis showed that the char residue of these EP composites increased significantly. Compared with the EP matrix filled with only MgAlZn-LDH-PMoA or HACP, the incorporation of MgAlZn-LDH-PMoA and HACP had a synergistic effect on promoting char formation of EP composites. Particularly, the char yield of EP7 is as high as 29.0%. Furthermore, the synergistic effects of incorporation of MgAlZn-LDH-PMoA with HACP were investigated using the cone calorimeter combustion tests. The results showed that the total heat release and peak heat release rate of the EP composites remarkably declined by 35.2 and 50.9%, respectively, with a loading of 7 wt % hybrid flame retardant. Moreover, the hybrid flame retardants also showed an obvious inhibitory effect on the total smoke production and the release of toxic CO gas. The detailed analysis of the residual char indicated that the main mechanism for improving the flame retardancy and smoke suppression performance is due to both the catalytic carbonization of MgAlZn-LDH-PMoA and phosphoric acid compounds and physical barrier function of the char layer. In addition, the molybdenum oxides produced from [PMo12O40]3- during combustion can not only increase the yield and compactness of the char layer but also reduce the release of CO through a redox reaction, which has important application value to reduce the fire hazard.

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Construction of a Phytic Acid-Silica System in Wood for Highly Efficient Flame Retardancy and Smoke Suppression.

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