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Synthesis and characterization of manganese ferrite from low grade manganese ore through solid state reaction route.

ABSTRACT: Manganese ferrite spinel has been synthesized by using low grade manganese ore and ferric oxide as sources of manganese oxide and iron oxide through solid state reaction route by taking manganese and iron mole ratio of 1:2 respectively. The impact of sintering temperature on phase composition and particle size is investigated. Similarly, the impact of frequency on dielectric constant, dielectric loss, AC (alternating current) conductivity and tangent losses is also investigated. The results shows the presence of spinel structure manganese ferrite (MnFe₂O₄) as the major phase for the sample sintered at 1200 °C. It has been established that the crystallite size increase with rise in sintering temperature. The surface morphology of the sample sintered at 1200 °C show pyramidal and triangular shape grains. The dielectric constant (ε') and dielectric losses (ε'') were observed to decrease with increasing the sintering temperature and frequency. Furthermore, the AC (alternating current) conductivity was found to rise with rise in applied frequency. On the other hand, the tangent losses falls considerably with rise in applied frequency.

SUBMITTER: Ahmad S

PROVIDER: S-EPMC8355231 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:In this study, a combination of alkali roasting and hydrothermal treatment is used as a method of gangue (Si, Al, and P) removal from iron ores as a means to upgrade low-grade iron ore (limonite) into a high-grade iron ore with low gangue content, low porosity, and high Fe and Fe2O3 content to enhance the sustainable development of iron and steel industries. The effects of the combined treatments (NaOH hydrothermal treatment and H2O/NaOH hydrothermal treatment of the alkali roasted sample), the iron ore type, their physical properties, and their calcination/roasting temperatures on the removal extent of gangue are investigated. The extent of Si, Al, and P removal by subjecting iron ores to a 5 M NaOH hydrothermal treatment at 300 °C reached 10-91%, 39-70%, and 38-76%, respectively. When the iron ores are roasted with NaOH at 350 °C, ?-FeOOH in limonite transfers to NaFeO2. On the other hand, for alkali roasted iron ores that inherently contain Fe2O3, Fe2O3 and Na2CO3 are also observed after the roasting treatment. Higher Al and P removal extents are observed for H2O leaching at room temperature in the prepared roasted samples (Roasting/H2O_RT) as compared to NaOH hydrothermal treatment, whereas that of Si is low for all samples, except the iron ore with the highest Fe content. After the H2O leaching process, the Fe form is found to be in the amorphous form for all samples, except for the iron ore sample of the highest Fe content. The reason for this is thought to be due to the large amount of unreacted Fe2O3 with NaOH during the roasting process. The specific surface area significantly increases after the Roasting/H2O_RT treatment in all samples due to the dehydration of goethite (?-FeOOH ? Fe2O3 + H2O) during the roasting treatment and gangue removal during H2O leaching. When the roasted samples are supplied for hydrothermal treatment by H2O at 300 °C (Roasting/H2O_SC), the removal rate of Si and P increases as compared with the Roasting/H2O_RT treatment. The influence of temperatures of calcination and the roasting treatment on the extent of gangue removal in 5 M NaOH hydrothermal, Roasting/H2O_RT, and Roasting/H2O_SC treatments is small. When NaOH hydrothermal treatment is carried out on the samples that have undergone the Roasting/H2O_RT treatment, a gangue removal extent of above 70-97% was achieved, except for the iron ore with the lowest P content, which had the largest loss of ignition and the lowest Fe content. In addition, it is revealed that low-grade iron ore with a high pore properties, ?-FeOOH content, and gangue content can be upgraded to a high-grade iron ore with a low pore property (low specific surface area and pore volume), high Fe2O3 content, and low gangue content using the above method. Therefore, this method is promising as a method for upgrading low-grade iron ore.

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Synthesis and characterization of manganese ferrite from low grade manganese ore through solid state reaction route.

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