Unknown

Dataset Information

0

Unbalanced 2D Chiral Crystallization of Pentahelicene Propellers and Their Planarization into Nanographenes.


ABSTRACT: The chiral self-assembly of trispentahelicene propellers on a gold surface has been investigated in ultrahigh vacuum by means of scanning tunneling microscopy and time-of-flight secondary ion mass spectrometry. The trispentahelicene propellers aggregate into mirror domains with an enantiomeric ratio of 2 : 1. Thermally induced cyclodehydrogenation leads to planarization into nanographenes, which self-assemble into closed-packed layers with two different azimuths. Further treatment induces in part dimerization and trimerization by intermolecular cyclodehydrogenation.

SUBMITTER: Voigt J 

PROVIDER: S-EPMC8362048 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC7898383 | biostudies-literature
| S-EPMC8119938 | biostudies-literature
| S-EPMC8456895 | biostudies-literature
| S-EPMC10729892 | biostudies-literature
| S-EPMC8100267 | biostudies-literature
| S-EPMC1301389 | biostudies-other
| S-EPMC5658384 | biostudies-literature
| S-EPMC3128831 | biostudies-literature
| S-EPMC11313125 | biostudies-literature
| S-EPMC6897542 | biostudies-literature