Browse
Submit Data
Databases
API
Help

Dataset Information

24 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

High Capacity and Fast Kinetics of Potassium-Ion Batteries Boosted by Nitrogen-Doped Mesoporous Carbon Spheres.

ABSTRACT: In view of rich potassium resources and their working potential, potassium-ion batteries (PIBs) are deemed as next generation rechargeable batteries. Owing to carbon materials with the preponderance of durability and economic price, they are widely employed in PIBs anode materials. Currently, porosity design and heteroatom doping as efficacious improvement strategies have been applied to the structural design of carbon materials to improve their electrochemical performances. Herein, nitrogen-doped mesoporous carbon spheres (MCS) are synthesized by a facile hard template method. The MCS demonstrate larger interlayer spacing in a short range, high specific surface area, abundant mesoporous structures and active sites, enhancing K-ion migration and diffusion. Furthermore, we screen out the pyrolysis temperature of 900 °C and the pore diameter of 7 nm as optimized conditions for MCS to improve performances. In detail, the optimized MCS-7-900 electrode achieves high rate capacity (107.9 mAh g^-1 at 5000 mA g^-1) and stably brings about 3600 cycles at 1000 mA g^-1. According to electrochemical kinetic analysis, the capacitive-controlled effects play dominant roles in total storage mechanism. Additionally, the full-cell equipped MCS-7-900 as anode is successfully constructed to evaluate the practicality of MCS.

SUBMITTER: Zheng J

PROVIDER: S-EPMC8363726 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Nickel Hollow Spheres Concatenated by Nitrogen-Doped Carbon Fibers for Enhancing Electrochemical Kinetics of Sodium-Sulfur Batteries.

Project description:The high energy density of room temperature (RT) sodium-sulfur batteries (Na-S) usually rely on the efficient conversion of polysulfide to sodium sulfide during discharging and sulfur recovery during charging, which is the rate-determining step in the electrochemical reaction process of Na-S batteries. In this work, a 3D network (Ni-NCFs) host composed by nitrogen-doped carbon fibers (NCFs) and Ni hollow spheres is synthesized by electrospinning. In this novel design, each Ni hollow unit not only can buffer the volume fluctuation of S during cycling, but also can improve the conductivity of the cathode along the carbon fibers. Meanwhile, the result reveals that a small amount of Ni is polarized during the sulfur-loading process forming a polar Ni-S bond. Furthermore, combining with the nitrogen-doped carbon fibers, the Ni-NCFs composite can effectively adsorb soluble polysulfide intermediate, which further facilitates the catalysis of the Ni unit for the redox of sodium polysulfide. In addition, the in situ Raman is employed to supervise the variation of polysulfide during the charging and discharging process. As expected, the freestanding S@Ni-NCFs cathode exhibits outstanding rate capability and excellent cycle performance.

| S-EPMC7029643 | biostudies-literature

Nitrogen-Doped Cobalt Pyrite Yolk-Shell Hollow Spheres for Long-Life Rechargeable Zn-Air Batteries.

Project description:Limited by the sluggish four-electron transfer process, designing high-performance nonprecious electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is urgently desired for efficient rechargeable Zn-air batteries (ZABs). Herein, the successful synthesis of porous nitrogen-doped cobalt pyrite yolk-shell nanospheres (N-CoS2 YSSs) is reported. Benefiting from the abundant porosity of the porous yolk-shell structure and unique electronic properties by nitrogen doping, the as-prepared N-CoS2 YSSs possess more exposed active surface, thus giving rise to superior activity for reversible oxygen electrocatalysis and outstanding cycling stability (more than 165 h at 10 mA cm-2) in ZABs, exceeding the commercial Pt/C and RuO2 hybrid catalysts. Moreover, the assembled ZABs, delivering a specific capacity of 640 mAh gZn -1, can be used for practical devices. This work provides a novel tactic to engineer sulfides as high efficiency and promising bifunctional oxygen electrocatalysts for advanced metal-air batteries.

| S-EPMC7675189 | biostudies-literature

Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries.

Project description:Potassium-ion batteries are a promising alternative to lithium-ion batteries. However, it is challenging to achieve fast charging/discharging and long cycle life with the current electrode materials because of the sluggish potassiation kinetics. Here we report a soft carbon anode, namely highly nitrogen-doped carbon nanofibers, with superior rate capability and cyclability. The anode delivers reversible capacities of 248 mAh g-1 at 25 mA g-1 and 101 mAh g-1 at 20 A g-1, and retains 146 mAh g-1 at 2 A g-1 after 4000 cycles. Surface-dominated K-storage is verified by quantitative kinetics analysis and theoretical investigation. A full cell coupling the anode and Prussian blue cathode delivers a reversible capacity of 195 mAh g-1 at 0.2 A g-1. Considering the cost-effectiveness and material sustainability, our work may shed some light on searching for K-storage materials with high performance.

| S-EPMC5928078 | biostudies-literature

Highly Dispersed Cobalt Nanoparticles Embedded in Nitrogen-Doped Graphitized Carbon for Fast and Durable Potassium Storage.

Project description:Potassium-ion batteries (KIBs) have great potential for applications in large-scale energy storage devices. However, the larger radius of K+ leads to sluggish kinetics and inferior cycling performance, severely restricting its practical applicability. Herein, we propose a rational strategy involving a Prussian blue analogue-derived graphitized carbon anode with fast and durable potassium storage capability, which is constructed by encapsulating cobalt nanoparticles in nitrogen-doped graphitized carbon (Co-NC). Both experimental and theoretical results show that N-doping effectively promotes the uniform dispersion of cobalt nanoparticles in the carbon matrix through Co-N bonds. Moreover, the cobalt nanoparticles and strong Co-N bonds synergistically form a three-dimensional conductive network, increase the number of adsorption sites, and reduce the diffusion energy barrier, thereby facilitating the adsorption and the diffusion kinetics. These multiple effects lead to enhanced reversible capacities of 305 and 208.6 mAh g-1 after 100 and 300 cycles at 0.05 and 0.1 A g-1, respectively, demonstrating the applicability of the Co-NC anode for KIBs.

| S-EPMC8187504 | biostudies-literature

Mesoporous hollow carbon spheres for lithium-sulfur batteries: distribution of sulfur and electrochemical performance.

Project description:Hollow carbon spheres (HCS) with a nanoporous shell are promising for the use in lithium-sulfur batteries because of the large internal void offering space for sulfur and polysulfide storage and confinement. However, there is an ongoing discussion whether the cavity is accessible for sulfur. Yet no valid proof of cavity filling has been presented, mostly due to application of unsuitable high-vacuum methods for the analysis of sulfur distribution. Here we describe the distribution of sulfur in hollow carbon spheres by powder X-ray diffraction and Raman spectroscopy along with results from scanning electron microscopy and nitrogen physisorption. The results of these methods lead to the conclusion that the cavity is not accessible for sulfur infiltration. Nevertheless, HCS/sulfur composite cathodes with areal sulfur loadings of 2.0 mg·cm-2 were investigated electrochemically, showing stable cycling performance with specific capacities of about 500 mAh·g-1 based on the mass of sulfur over 500 cycles.

| S-EPMC5082344 | biostudies-literature

First-principles computational investigation of nitrogen-doped carbon nanotubes as anode materials for lithium-ion and potassium-ion batteries.

Project description:Significant research efforts, mostly experimental, have been devoted to finding high-performance anode materials for lithium-ion and potassium-ion batteries; both graphitic carbon-based and carbon nanotube-based materials have been generating huge interest. Here, first-principles calculations are performed to investigate the possible effects of doping defects and the varying tube diameter of carbon nanotubes (CNTs) on their potential for battery applications. Both adsorption and migration of Li and K are studied for a range of pristine and nitrogen-doped CNTs, which are further compared with 2D graphene-based counterparts. We use detailed electronic structure analyses to reveal that different doping defects are advantageous for carbon nanotube-based and graphene-based models, as well as that curved CNT walls help facilitate the penetration of potassium through the doping defect while showing a negative effect on that of lithium.

| S-EPMC9064600 | biostudies-literature

Nitrogen-doped hollow carbon spheres with tunable shell thickness for high-performance supercapacitors.

Project description:Nitrogen-doped hollow carbon spheres (NHCSs) are well prepared by using Cu2O microspheres as a hard template and 3-aminophenol formaldehyde resin polymer as carbon and nitrogen precursors. The thickness of the carbon shell can be easily controlled in the range of 15-84 nm by simply adjusting the weight ratios of the precursors to Cu2O microspheres, and the Cu2O templates can also be further reused. Physicochemical characterization demonstrates that the obtained NHCSs possess a well-developed hollow spherical structure, thin carbon shell and high nitrogen doping content. Due to these characteristics, when further utilized as electrodes for supercapacitors, the NHCSs with the carbon shell thickness of 15 nm show a high capacitance of 263.6 F g-1 at 0.5 A g-1, an outstanding rate performance of 122 F g-1 at 20 A g-1 and an excellent long-term cycling stability with only 9.8% loss after 1000 cycles at 5 A g-1 in 6 M KOH aqueous electrolyte. This finding may push forward the development of carbon materials, exhibiting huge potential for electrochemical energy storage applications.

| S-EPMC9055434 | biostudies-literature

Facile Synthesis of Nitrogen-Doped Microporous Carbon Spheres for High Performance Symmetric Supercapacitors.

Project description:Nitrogen-doped microporous carbon spheres (NMCSs) are successfully prepared via carbonization and KOH activation of phenol-formaldehyde resin polymer spheres synthesized by a facile and time-saving one-step hydrothermal strategy using triblock copolymer Pluronic F108 as a soft template under the Stöber-like method condition. The influence of the ethanol/water volume ratios and carbonation temperatures on the morphologies, pore structures and electrochemical performances of the prepared NMCSs are investigated systematically. The optimal NMCSs have a large specific surface area of 1517 m2 g- 1 with a pore volume of 0.8 cm3 g- 1. The X-ray photo-electron spectroscopy analysis reveals a suitable nitrogen-doped content of 2.6 at.%. The as-prepared NMCSs used as supercapacitor electrode materials exhibit an outstanding specific capacitance of 416 F g- 1 at a current density of 0.2 A g- 1, also it shows an excellent charge/discharge cycling stability with 96.9% capacitance retention after 10,000 cycles. The constructed symmetric supercapacitors using PVA/KOH as the gel electrolyte can deliver a specific capacitance of 60.6 F g- 1 at current density of 1 A g- 1. A maximum energy density of 21.5 Wh kg- 1 can be achieved at a power density of 800 W kg- 1, and the energy density still maintains 13.3 Wh kg- 1 even at a high power density of 16 kW kg- 1. The results suggest that this work can open up a facile and effective way to synthesize the NMCSs for electrode materials of high performance energy storage devices.

| S-EPMC6172159 | biostudies-literature

Nitrogen Doped Carbon Nanosheets Encapsulated in situ Generated Sulfur Enable High Capacity and Superior Rate Cathode for Li-S Batteries.

Project description:Lithium-sulfur batteries (LSBs), with large specific capacity (1,675 mAh g-1), are regarded as the most likely alternative to the traditional Lithium-ion batteries. However, the intrinsical insulation and dramatic volume change of sulfur, as well as serious shuttle effect of polysulfides hinder their practical implementation. Herein, we develop three-dimensional micron flowers assembled by nitrogen doped carbon (NC) nanosheets with sulfur encapsulated (S@NC-NSs) as a promising cathode for Li-S to overcome the forementioned obstacles. The in situ generated S layer adheres to the inner surface of the hollow and micro-porous NC shell with fruitful O/N containing groups endowing both efficient physical trapping and chemical anchoring of polysulfides. Meanwhile, such a novel carbon shell helps to bear dramatic volume change and provides a fast way for electron transfer during cycling. Consequently, the S@NC-NSs demonstrate a high capacity (1,238 mAh g-1 at 0.2 C; 1.0 C = 1,675 mA g-1), superior rate performance with a capacity retention of 57.8% when the current density increases 25 times from 0.2 to 5.0 C, as well as outstanding cycling performance with an ultralow capacity fading of only 0.064% after 200 cycles at a high current density of 5.0 C.

| S-EPMC6168012 | biostudies-literature

MOF-Derived CoSe<sub>2</sub>@N-Doped Carbon Matrix Confined in Hollow Mesoporous Carbon Nanospheres as High-Performance Anodes for Potassium-Ion Batteries.

Project description:In this work, a novel vacuum-assisted strategy is proposed to homogenously form Metal-organic frameworks within hollow mesoporous carbon nanospheres (HMCSs) via a solid-state reaction. The method is applied to synthesize an ultrafine CoSe2 nanocrystal@N-doped carbon matrix confined within HMCSs (denoted as CoSe2@NC/HMCS) for use as advanced anodes in high-performance potassium-ion batteries (KIBs). The approach involves a solvent-free thermal treatment to form a Co-based zeolitic imidazolate framework (ZIF-67) within the HMCS templates under vacuum conditions and the subsequent selenization. Thermal treatment under vacuum facilitates the infiltration of the cobalt precursor and organic linker into the HMCS and simultaneously transforms them into stable ZIF-67 particles without any solvents. During the subsequent selenization process, the "dual confinement system", composed of both the N-doped carbon matrix derived from the organic linker and the small-sized pores of HMCS, can effectively suppress the overgrowth of CoSe2 nanocrystals. Thus, the resulting uniquely structured composite exhibits a stable cycling performance (442 mAh g-1 at 0.1 A g-1 after 120 cycles) and excellent rate capability (263 mAh g-1 at 2.0 A g-1) as the anode material for KIBs.

| S-EPMC8187686 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data