Pesticides pollution and risk assessment of river Ganga: A review.
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ABSTRACT:
SUBMITTER: Shah ZU
PROVIDER: S-EPMC8367800 | biostudies-literature |
REPOSITORIES: biostudies-literature
Similar Datasets
Project description:The present work aimed to predict the fate of two pesticides, copper (Cu) and glyphosate in a Mediterranean basin with an intermittent river and to assess the ecotoxicological risk related to their presence in water bodies coupling field measurements of streamflow and pesticide concentrations, and an eco-hydrological model. The Soil and Water Assessment Tool (SWAT) model was calibrated and, subsequently used to assess predicted environmental concentrations of pesticides in surface waters. The ecotoxicological risk related to the presence of Cu and glyphosate in surface water was assessed at the reach scale by using the Toxicity to Exposure Ratio approach (TER). Measurements of glyphosate concentrations (< 0.5 μg l-1) exceeded the maximum European threshold of environmental quality standards for pesticides (EQS) of 0.1 μg l-1. High concentrations of glyphosate were predicted in the wet season and in September, when glyphosate is mostly used in vineyards and olive grove productions. Acute risk (TER < 100) associated with the presence of glyphosate was detected for several reaches. High concentrations of Cu (< 6.5 μg l-1), mainly used as a fungicide in vineyards, were predicted in several river reaches. The results of the ecotoxicological risk assessment revealed that November and January were the critical months during which most of the river reaches showed a chronic risk associated with the presence of Cu.
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Project description:The Sado basin (~8000 km2) is an area where intensive agriculture occurs. However, this region still has few data about the water levels of priority pesticides such as fungicides, herbicides, and insecticides. Therefore, water samples were collected every two months at nine sites along the Sado River Estuary and analyzed by GC-MS/MS to determine the influx of pesticides in that ecosystem. More than 87% of the pesticides were quantified, and 42% and 72% were above the maximum totals established by the European Directives 98/83/EC and 2013/39/EU, respectively. Fungicides (91%), herbicides (87%), and insecticides (85%) attained average annual amounts of ≈3.2 µg/L, ≈1.0 µg/L, and ≈12.8 µg/L, respectively. A mathematical approach was used to evaluate the hazard of the pesticide mixture at the maximum concentrations found in this area. The assessment identified invertebrates as the most at-risk trophic level and identified two chemicals (chlorpyriphos and cyfluthrin) as the primary culprits. This assumption was supported by acute in vivo assays using Daphnia magna. These observations, and the high concentrations of phosphates, indicate that the status of the Sado waters poses environmental and potential human health risks.
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Project description:Impact of barge movement on phytoplankton abundance and biomass was assessed in the lower stretch of river Ganga, popularly known as Bhagirathi-Hooghly river, during April 2016 to March, 2017. Based on the magnitude of tide, intensity of shipping and boating activities, the stretch from Baranagar to Lalbag (278 km), located at latitude (22°38'33.41"N to 24°10'59.75"N) and longitude (88°21'21.29"E to 88°16'5.65"E) was divided into three zones viz. zone-I (Baranagar to Barrackpore), zone II (Triveni to Balagarh) and zone III (Nabadweep to Lalbag). Water samples were collected randomly from six stations covering 22 barge movements at their passage at three different time intervals viz., 30 minutes before 'barge movement', during 'barge movement' and 30 minutes after 'barge movement'. Analysis revealed the presence of 52 phytoplankton taxa belonged to 5 phylum during the study period. The abundance of phytoplankton was highest in zone-I followed by zone III and the zone II. A 44% decrease (1,997 ±1,510 ul-1) in phytoplankton abundance was observed during 'barge movement' with respect to normal condition (3,513 ± 2,239 ul-1) which could be due to propeller turbulence in the passage. Cell damage study revealed 21% damage in phytoplankton cell structure in 'during barge' followed by 'after barge' (10%) condition compared to natural state (6%). Study revealed that phytoplankton biomass (Chlorophyll a) was influenced by 'barge movement' in the sampling stretches and the impact was assessed by one way ANOVA. The effect was found significant at Barrackpore (p <0.01), Triveni (p <0.01), Balagarh (p <0.01) and Lalbag (p <0.01) where as it was insignificant at Baranagar and Nabadweep, which may be due to continuous and existing boat trafficking at Baranagar and Nabadweep. Two way ANOVA computed using 'barge movement' and sampling stations showed significant (p<0.01) effect on magnitude of Chl a concentrations in the sampling locations. Thus, the 'barge movement' influenced phytoplankton abundance and biomass, it had a detrimental effect on phytoplankton cell architecture also. The data set of this work serves as foundation information to understand the ecological implications augmented barge induced environmental disturbances in waterways. This is the first such study which depicts the impact of 'barge movement' on aquatic food chain linkages in Bhagirathi- Hooghly river.
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Project description:To examine the residual and distributions of tetracycline antibiotics in the Weihe River, SPE-UPLC (solid phase extraction-ultra performance liquid chromatography with UV-Vis detection) was employed to analyze the oxytetracycline (OTC), chlortetracycline (CTC), and minocycline (MC) of 41 surface water and 35 sediment samples collected from main streams, tributaries, and main sewage outlets. The results showed that: (1) The order of residual levels of tetracycline antibiotics in water and sediment from high to low was the following: OTC > CTC > MC., considering the water solubilities are 313 mg/L, 630 mg/L, and 50200mg/L and octanol water partition coefficients (Kow) are 7.94, 4.16, and 1.12 for OTC, CTC, and MC, respectively. Thus, the distribution of antibiotics was not only related to the basic properties of antibiotics, but also some environmental factors. The concentrations of OTC in water and sediment were in the range of 1.56⁻87.89 ng/L and 6.13⁻45.38 ng/g (mean value of 16.13 ng/L and 20.60 ng/g), respectively; while CTC was 1.07⁻26.78 ng/L and 6.17⁻32.29 ng/g (mean value of 4.96 ng/L and 14.48 ng/g), respectively; and MC was 0.28⁻12.35 ng/L and 4.80⁻29.74 ng/g (mean value of 1.70 ng/L and 12.96 ng/g), respectively. There were maximum concentrations in all sewage outlets. Compared with other areas in China, tetracyclines residual in the Weihe river were at a medium level; (2) in spatial distribution, the levels of tetracyclines in water and sediment from the middle and upper reaches were higher than the lower reaches. Meanwhile, the sewage outfalls and livestock farm waste water discharge appeared to be the main sources of tetracycline antibiotics in the Weihe River; (3) ecological risk assessment revealed that in main streams and tributaries, OTC and CTC may be at a low ecological risk level; while in sewage outfalls, they may represent a medium ecological risk level.
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Project description:The intensive use of organophosphorus pesticides (OPPs) causes concern among authorities in different countries, as many of them, remaining unchanged for a long time, pose a threat to environmental sustainability. This study assessed the spatio-temporal trends of nine OPPs in the water dissolved phase (WDP), suspended particulate matter (SPM), and sediment samples from the Sele River estuary, Southern Italy. Samples were collected in 10 sampling sites during four seasons. The highest levels were found at the mouth (mean value 28.25 ng L-1 as WDP + SPM) and then decreased moving southwards to the Mediterranean Sea. Moreover, highest concentrations were detected in the warm season (July) with a mean value of 27.52 ng L-1. The load contribution to the Mediterranean Sea was evaluated in about 61.5 kg year-1, showing that the river was an important source of OPPs through discharge into the sea. The risk assessment revealed that no high-risk indices for the general-case scenario were observed, but for the worst-case scenario, potential risks were associated with chlorpyrifos, pyrimifos-methyl, and parathion, suggesting that OPP contamination should not be neglected. This study makes up the first record of OPPs in the surface waters of the Sele River and provides helpful data as a starting point for future studies.
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Project description:Anthropogenic pollution plays an important part in deteriorating the water quality of rivers all over the world, especially in urban areas of Africa where water quality monitoring is still seriously constrained by the limited test facility and capability. In this study, for evaluating the impact of urbanization on the river water quality, we investigated four typical urban rivers of Tanzania through the upper-urban-down gradient assessment approach and analyzed by water quality index (WQI) and statistical methods. The physicochemical indices monitored in these rivers revealed that the contents of those indicators of TN, TP, PO43-, NH4+, CODMn, and NO3- were accumulated significantly in the lower reaches of the cities, which indicated the life-type pollution characteristics in such urban rivers of Africa. The following main conclusions are achieved from this study. The water quality of 30% of the investigated river sections is in the medium to good status based on the subjective WQI with sensory factors included. Moreover, the sections with obvious water quality decline are mainly limited to the river segments within the urban central area, and severe pollution of water bodies is closely related to large cities, indicating an increasing pollution tendency with the quickly growing population. Therefore, to help formulate water pollution control policies in response to the rapid urban expansion in African countries, it is necessary to adopt an economical and feasible method to carry out early monitoring of surface water quality timely.
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Project description:Clean rivers and healthy aquatic life symbolize that the ecosystem is functioning well. The Ganga River has shown signs of rejuvenation and a significant improvement on many parameters, following the eight-week nationwide lockdown due to coronavirus pandemic. Since industrial units and commercial establishments were closed, water was not being lifted by them with a negligible discharge of industrial wastewater. It was observed that during the lockdown period most of the districts falling under the Ganga basin observed 60% excess rainfall than the normal, which led to increased discharge in the river, further contributing towards the dilution of pollutants. Further, data analysis of live storages in the Ganga Basin revealed that the storage during the beginning of the third phase of lockdown was almost double than the storage during the same period the previous year. Analysis of the storage data of the last ten years revealed that the storage till May 6, 2020 was 82.83% more than the average of the previous ten years, which meant that more water was available for the river during the lockdown period. The impact could be seen in terms of increased dissolved oxygen (DO) and reduced biological oxygen demand (BOD), Faecal coliform, Total coliform and nitrate (NO3-) concentration. A declining trend in nitrate concentration was observed in most of the locations due to limited industrial activities and reduction in agricultural run-off due to harvesting season. The gradual transformation in the quality of the water has given a sign of optimism from the point of restoration. Yet, it is believed that this improvement in water quality is 'short-lived' and quality would deteriorate once the normal industrial activities are resumed, indicating a strong influence of untreated commercial-industrial wastewater. The paper concludes that the river can be rejuvenated if issues of wastewater and adequate flow releases are addressed.
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Project description:Direct sewage discharge can cause severe damage to the water environment of the river. However, the impacts of dissolved organic matter (DOM) in the discharge on the original pattern of DOM and the distribution of heavy metals (HMs) in the river are little known. How to monitor such areas in a long-term and systematic manner also needs to be urgently addressed. In this paper, we characterized the DOM of the sediments in the WWTPs (wastewater treatment plants)-river integrated zone by ultraviolet-visible absorption spectroscopy (UV-vis), three-dimensional excitation-emission matrix (3D-EEM) combined with parallel factor (PARAFAC) method. The effects of WWTP on receiving waters were investigated, and the potential link between DOM and HM pollution was explored. Hg (Igeo: 3.94 ± 0.65; EF: 44.83 ± 31.11), Cd (Igeo: 1.81 ± 0.69; EF: 8.02 ± 2.97), Cu (Igeo: 1.61 ± 0.83; EF: 6.85 ± 2.37), Zn (Igeo: 1.55 ± 0.54; EF: 7.24 ± 3.58), and Ni (Igeo: 1.46 ± 0.56; EF: 6.12 ± 1.99) in rivers were the primary risk sources of HM. The combined pollution risk indicates that the WWTPs-river integrated area is in a high pollution risk state. Moreover, α(254) has a significant correlation with pollution indicators and can be used as a proxy indicator. These results help to understand better the impact of WWTPs on receiving water bodies and the potential connection between DOM and HM pollution and provide new ideas for monitoring the water environment in highly polluted areas.
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Project description:This study reports the data on the contamination caused by polycyclic aromatic hydrocarbons (PAHs) drained from the Volturno River. The seasonal and spatial distribution of PAHs in water and sediment samples was assessed. The 16 PAHs were determined in the water dissolved phase (DP), suspended particulate matter (SPM), and sediments. A multidimensional statistical approach was used to identify three pollution composite indicators. Contaminant discharges of PAHs into the sea were calculated in about 3158.2 kg/year. Total concentrations of PAHs varied in ranges 434.8 to 872.1 ng g-1 and 256.7 to 1686.3 ng L-1 in sediment samples and in water (DP + SPM), respectively. The statistical results indicated that the PAHs mainly had a pyrolytic source. Considering the sediment quality guidelines (SQGs), the water environmental quality standards (USEPA EQS), and risk quotient (RQ), the Volturno River would be considered as an area in which the environmental integrity is possibly at risk.
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Project description:The assessment of residential exposure to agricultural pesticides is a major issue for public health, regulatory and management purposes. In recent years, research into this field has developed considerably. The purpose of this scoping review is to provide an overview of scientific literature characterizing residential exposure to agricultural pesticides and to identify potential gaps in this research area. This work was conducted according to the JBI and PRISMA guidelines. Three databases were consulted. At least two experts selected the eligible studies. Our scoping review enabled us to identify 151 articles published between 1988 and 2019 dealing with the assessment of residential exposure to agricultural pesticides. Of these, 98 (64.9%) were epidemiological studies investigating possible links between pesticide exposure and the onset of adverse health effects, principally cancers and reproductive outcomes. They predominantly used Geographic Information Systems and sometimes surveys or interviews to calculate surrogate exposure metrics, the most common being the amounts of pesticides applied or the surface area of crops around the dwelling. Twenty-six (17.2%) were observational measurement studies conducted to quantify levels of pesticide exposure and identify their possible determinants. These studies assessed exposure by measuring pesticides in biological and environmental matrices, mostly in urines and house dust. Finally, we found only eight publications (5.3%) that quantified the risk to human health due to residential exposure for management purposes, in which exposure was mainly determined using probabilistic models. Pesticide exposure appears to be largely correlated with the spatial organization of agriculture activities in a territory. The determinants and routes of exposure remain to be explored to improve the conduct of epidemiological and risk assessment studies and to help prevent future exposures. Improvement could be expected from small-scale studies combining different methods of exposure assessment.
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