Electrolyte/Structure-Dependent Cocktail Mediation Enabling High-Rate/Low-Plateau Metal Sulfide Anodes for Sodium Storage.

ABSTRACT: As promising anodes for sodium-ion batteries, metal sulfides ubiquitously suffer from low-rate and high-plateau issues, greatly hindering their application in full-cells. Herein, exemplifying carbon nanotubes (CNTs)-stringed metal sulfides superstructure (CSC) assembled by nano-dispersed SnS₂ and CoS₂ phases, cocktail mediation effect similar to that of high-entropy materials is initially studied in ether-based electrolyte to solve the challenges. The high nano-dispersity of metal sulfides in CSC anode underlies the cocktail-like mediation effect, enabling the circumvention of intrinsic drawbacks of different metal sulfides. By utilizing ether-based electrolyte, the reversibility of metal sulfides is greatly improved, sustaining a long-life effectivity of cocktail-like mediation. As such, CSC effectively overcomes low-rate flaw of SnS₂ and high-plateau demerit of CoS₂, simultaneously realizes a high rate and a low plateau. In half-cells, CSC delivers an ultrahigh-rate capability of 327.6 mAh g^-1_anode at 20 A g^-1, far outperforming those of monometallic sulfides (SnS₂, CoS₂) and their mixtures. Compared with CoS₂ phase and SnS₂/CoS₂ mixture, CSC shows remarkably lowered average charge voltage up to ca. 0.62 V. As-assembled CSC//Na_1.5VPO_4.8F_0.7 full-cell shows a good rate capability (0.05 ~ 1.0 A g^-1, 120.3 mAh g^-1_electrode at 0.05 A g^-1) and a high average discharge voltage up to 2.57 V, comparable to full-cells with alloy-type anodes. Kinetics analysis verifies that the cocktail-like mediation effect largely boosts the charge transfer and ionic diffusion in CSC, compared with single phase and mixed phases. Further mechanism study reveals that alternative and complementary electrochemical processes between nano-dispersed SnS₂ and CoS₂ phases are responsible for the lowered charge voltage of CSC. This electrolyte/structure-dependent cocktail-like mediation effect effectively enhances the practicability of metal sulfide anodes, which will boost the development of high-rate/-voltage sodium-ion full batteries.

SUBMITTER: Tang Y 

PROVIDER: S-EPMC8371071 | biostudies-literature |

REPOSITORIES: biostudies-literature