Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Plasmon-enabled N₂ photofixation on partially reduced Ti₃C₂ MXene.

ABSTRACT: Benefiting from the superior conductivity, rich surface chemistry and tunable bandgap, Ti₃C₂ MXene has become a frontier cocatalyst material for boosting the efficiency of semiconductor photocatalysts. It has been theoretically predicted to be an ideal material for N₂ fixation. However, the realization of N₂ photofixation with Ti₃C₂ as a host photocatalyst has so far remained experimentally challenging. Herein, we report on a sandwich-like plasmon- and an MXene-based photocatalyst made of Au nanospheres and layered Ti₃C₂, and demonstrate its efficient N₂ photofixation in pure water under ambient conditions. The abundant low-valence Ti (Ti^(4-x)+) sites in partially reduced Ti₃C₂ (r-Ti₃C₂) produced by surface engineering through H₂ thermal reduction effectively capture and activate N₂, while Au nanospheres offer plasmonic hot electrons to reduce the activated N₂ into NH₃. The Ti^(4-x)+ active sites and plasmon-generated hot electrons work in tandem to endow r-Ti₃C₂/Au with remarkably enhanced N₂ photofixation activity. Importantly, r-Ti₃C₂/Au exhibits ultrahigh selectivity without the occurrence of competing H₂ evolution. This work opens up a promising route for the rational design of efficient MXene-based photocatalysts.

SUBMITTER: Chang B

PROVIDER: S-EPMC8386658 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

High Modulation Depth Enabled by Mo2Ti2C3Tx MXene for Q-Switched Pulse Generation in a Mid-Infrared Fiber Laser.

Project description:Two-dimensional (2D) materials show great promise as saturable absorbers (SAs) for ultrafast fiber lasers. However, the relatively low modulation depth and poor stability of some 2D materials, such as graphene and black phosphorus, restrict their applications in the mid-infrared pulse generation. Herein, we first report a novel 2D double transition metal carbide, denoted as Mo2Ti2C3Tx MXene, as the saturable absorber (SA) for a passively Q-switched mid-infrared fiber laser. Due to the unique four-metal atomic layer structure, the Mo2Ti2C3Tx exhibits superior saturable absorption properties, particularly with a higher modulation depth (40% at 2796 nm) than most of the other reported 2D SA materials. After incorporating the MXene SA with an erbium-doped fiber system, the passively Q-switched pulses were achieved with a repetition rate of 157.3 kHz, the shortest pulse width of 370 ns, and single-pulse energy of 1.92 μJ, respectively. Such results extend the MXene-based SAs as promising candidates for advanced photonic devices.

| S-EPMC9025076 | biostudies-literature

Theoretical Analysis of Magnetic Coupling in the Ti2C Bare MXene.

Project description:The nature of the electronic ground state of the Ti2C MXene is unambiguously determined by making use of density functional theory-based calculations including hybrid functionals together with a stringent computational setup providing numerically converged results up to 1 meV. All the explored density functionals (i.e., PBE, PBE0, and HSE06) consistently predict that the Ti2C MXene has a magnetic ground state corresponding to antiferromagnetic (AFM)-coupled ferromagnetic (FM) layers. A spin model, with one unpaired electron per Ti center, consistent with the nature of the chemical bond emerging from the calculations, is presented in which the relevant magnetic coupling constants are extracted from total energy differences of the involved magnetic solutions using an appropriate mapping approach. The use of different density functionals enables us to define a realistic range for the magnitude of each of the magnetic coupling constants. The intralayer FM interaction is the dominant term, but the other two AFM interlayer couplings are noticeable and cannot be neglected. Thus, the spin model cannot be reduced to include nearest-neighbor interactions only. The Néel temperature is roughly estimated to be in the 220 ± 30 K, suggesting that this material can be used in practical applications in spintronics and related fields.

| S-EPMC9969871 | biostudies-literature

Ion Selectivity, Current, and Water Flow Regulation in Ti3C2 MXene Nanopores.

Project description:Recent years have seen a growing interest in zero-dimensional (0D) transport phenomena occurring across two-dimensional (2D) materials for their potential applications to nanopore technology such as ion separation and molecular sensing. Herein, we investigate ion transport through 1 nm-wide nanopores in Ti3C2 MXene using molecular dynamics simulations. The high polarity and fish-bone arrangement of the Ti3C2 MXene offer a built-in potential and an atomic-scale distortion to the nanopore, causing an adsorption preference for cations. Our observation of variable cation-specific ion selectivity and Coulomb blockade highlights the complex interplay between adsorption affinity and cation size. The cation-specific ion selectivity can induce both the ion current and electro-osmotic water transmission, which can be regulated by tailoring the ions' preferential pathways through electric field tilting. Our finding underscores the pivotal role of the atomic arrangement of MXenes in 0D ion transport and provides fundamental insight into the application of 2D material in nanopores-based technologies.

| S-EPMC11311525 | biostudies-literature

Deformation of and Interfacial Stress Transfer in Ti3C2 MXene-Polymer Composites.

Project description:Transitional metal carbides and nitrides (MXenes) have promise for incorporation into multifunctional composites due to their high electrical conductivity and excellent mechanical and tribological properties. It is unclear, however, to what extent MXenes are also able to improve the mechanical properties of the composites and, if so, what would be the optimal flake size and morphology. Herein, Ti3C2Tx MXene is demonstrated to be indeed a good candidate for mechanical reinforcement in polymer matrices. In the present work, the strain-induced Raman band shifts of mono-/few-/multilayer MXenes flakes have been used to study the mechanical properties of MXene and the interlayer/interfacial stress transfer on a polymer substrate. The mechanical performance of MXene was found to be less dependent upon flake thickness compared to that of graphene. This enables Ti3C2Tx MXene to offer an efficient mechanical reinforcement to a polymer matrix with a flake length of >10 μm and a thickness of 10s of nanometers. Therefore, the degree of exfoliation of MXenes is not as demanding as other two-dimensional (2D) materials for the purpose of mechanical enhancement in polymers. In addition, the active surface chemistry of MXene facilitates possible functionalization to enable a stronger interface with polymers for applications, such as strain engineering and mechanical enhancement, and in materials including membranes, coatings, and textiles.

| S-EPMC9171720 | biostudies-literature

Sprayable Ti3C2 MXene hydrogel for wound healing and drug release system.

Project description:Wound healing is a critical process that facilitates the body's recovery from injuries and helps prevent infections, thereby maintaining overall tissue and organ functionality. However, delayed wound healing owing to various factors can lead to bacterial infections and secondary complications. In this study, a ciprofloxacin (CIP)-loaded MXene/sodium alginate (SA) hydrogel was fabricated to inhibit bacterial infections and enhance wound healing. The hydrogel was formulated in a sprayable state by blending CIP-loaded MXene (CIP-MX) with SA. This hydrogel was found to exhibit excellent photothermal conversion capability and biocompatibility under near-infrared (NIR) irradiation. In addition, the hydrogel enabled controlled drug release based on NIR irradiation, ultimately enabling improved antibacterial activity. Based on the in vitro and in vivo experiments, the CIP-loaded MXene/SA hydrogel (CIP-MX@Gel) accelerated wound healing. Overall, the CIP-MX@Gel has excellent potential as an effective wound healing material.

| S-EPMC10755543 | biostudies-literature

Ultrafast, One-Step, Salt-Solution-Based Acoustic Synthesis of Ti3C2 MXene.

Project description:The current quest for two-dimensional transition metal carbides and nitrides (MXenes) has been to circumvent the slow, hazardous, and laborious multistep synthesis procedures associated with conventional chemical MAX phase exfoliation. Here, we demonstrate a one-step synthesis method with local Ti3AlC2 MAX to Ti3C2Tz MXene conversion on the order of milliseconds, facilitated by proton production through solution dissociation under megahertz frequency acoustic excitation. These protons combined with fluorine ions from LiF to selectively etch the MAX phase into MXene, whose delamination is aided by the acoustic forcing. These results have important implications for the future applicability of MXenes, which crucially depend on the development of more efficient synthesis procedures. For proof-of-concept, we show that flexible electrodes fabricated by this method exhibit comparable electrochemical performance to that previously reported.

| S-EPMC8034768 | biostudies-literature

Ultraefficiently Calming Cytokine Storm Using Ti3C2T x MXene.

Project description:During the global outbreak of COVID-19 pandemic, "cytokine storm" conditions are regarded as the fatal step resulting in most mortality. Hemoperfusion is widely used to remove cytokines from the blood of severely ill patients to prevent uncontrolled inflammation induced by a cytokine storm. This article discoveres, for the first time, that 2D Ti3C2T x MXene sheet demonstrates an ultrahigh removal capability for typical cytokine interleukin-6. In particular, MXene shows a 13.4 times higher removal efficiency over traditional activated carbon absorbents. Molecular-level investigations reveal that MXene exhibits a strong chemisorption mechanism for immobilizing cytokine interleukin-6 molecules, which is different from activated carbon absorbents. MXene sheet also demonstrates excellent blood compatibility without any deleterious side influence on the composition of human blood. This work can open a new avenue to use MXene sheets as an ultraefficient hemoperfusion absorbent to eliminate the cytokine storm syndrome in treatment of severe COVID-19 patients.

| S-EPMC7995020 | biostudies-literature

Versatile Ti3C2T x MXene for free-radical scavenging.

Project description:MXene, as an emerging two-dimensional (2D) material with ultrathin structure and fascinating physiochemical properties, has been widely explored in broad applications. Versatile functions of MXenes are continuously explored. This work presents distinctive feature of MXene-Ti3C2T x nanosheets for free-radical (FRs) scavenging that never reported before. We demonstrated the mechanism and equation in regard to the reaction between Ti3C2T x and H2O2, which was applied to design colorimetric H2O2 strip assay with good performance. The good FRs scavenging capability of Ti3C2T x , including a series of reactive oxygen species (ROS) and reactive nitrogen species (RNS), was systemically confirmed. The antioxidation capability of Ti3C2T x for protecting cells from oxidative damage was demonstrated using the oxidative damage model of alpha mouse liver 12 (AML-12) cells. This original work provides huge opportunities for MXenes in FR-related biomedical applications.Electronic supplementary materialSupplementary material (further details of the experimental procedures, investigation of the reaction between Ti3C2T x and other oxidants, the characterization of endocytosis of cells for Ti3C2T x , and the comparison of different antioxidants for scavenging free radicals) is available in the online version of this article at 10.1007/s12274-021-3751-y.

| S-EPMC8427154 | biostudies-literature

Solution-Processed Ti3 C2 Tx MXene Antennas for Radio-Frequency Communication.

Project description:Highly integrated, flexible, and ultrathin wireless communication components are in significant demand due to the explosive growth of portable and wearable electronic devices in the fifth-generation (5G) network era, but only conventional metals meet the requirements for emerging radio-frequency (RF) devices so far. Here, it is reported on Ti3 C2 Tx MXene microstrip transmission lines with low-energy attenuation and patch antennas with high-power radiation at frequencies from 5.6 to 16.4 GHz. The radiation efficiency of a 5.5 µm thick MXene patch antenna manufactured by spray-coating from aqueous solution reaches 99% at 16.4 GHz, which is about the same as that of a standard 35 µm thick copper patch antenna at about 15% of its thickness and 7% of the copper weight. MXene outperforms all other materials evaluated for patch antennas to date. Moreover, it is demonstrated that an MXene patch antenna array with integrated feeding circuits on a conformal surface has comparable performance with that of a copper antenna array at 28 GHz, which is a target frequency in practical 5G applications. The versatility of MXene antennas in wide frequency ranges coupled with the flexibility, scalability, and ease of solution processing makes MXene promising for integrated RF components in various flexible electronic devices.

| S-EPMC9119193 | biostudies-literature

Dynamic response study of Ti3C2-MXene films to shockwave and impact forces.

Project description:MXenes (Titanium Carbide, Ti3C2-MXene) are two-dimensional nanomaterials that are known for their conductivity, film-forming ability, and elasticity. Though literature reports the possibility of usage of Ti3C2-MXenes for sensor development, the material properties and response need be studied in detail for designing sensors to measure dynamic variables like force, displacement, etc., in a dynamic environment. Ti3C2-MXenes due to their good electro-mechanical properties can be used for manufacturing sensing elements for engineering and biomedical applications. This paper focuses on an investigation of the dynamic response properties of Ti3C2-MXenes subjected to shockwave and impact forces. A supersonic shockwave (Mach number: 1.68, peak overpressure: 234.3 kPa) produced in a shock tube acts as an external force on the Ti3C2-MXene film placed inside the shock tube. In the experiment performed, the response time of the Ti3C2-MXene film sample has been observed to be in the range of few microseconds (∼7 μs) for the high-velocity shock. In a separate experiment, Ti3C2-MXene film samples are subjected to low-velocity impact forces through a ball drop test. The results from the ball drop test provide a response time in the range of few milliseconds (average ∼1.5 ms). In this novel demonstration, the Ti3C2-MXene film sample responds well for both low-velocity mechanical impact as well as high-velocity shockwave impact. Further, the repeatability of the dynamic response of the Ti3C2-MXene film sample is discussed along with its significant piezoresistive behavior. This work provides the basis for sensor development to measure the dynamic phenomena of pressure changes, acoustic emissions, structural vibrations, etc.

| S-EPMC9055921 | biostudies-literature