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Harvesting High-Quality White-Light Emitting and Remarkable Emission Enhancement in One-Dimensional Halide Perovskites Upon Compression.

ABSTRACT: The pressure induced emission (PIE) behavior of halide perovskites has attracted extensive interest due to its potential application in pressure sensors and trademark security. However, the PIE phenomenon of white-light-emitting hybrid perovskites (WHPs) is rare, and that at pressures above 10.0 GPa has never been reported. Here, we effectively adjusted the perovskite to emit high-quality "cold" or "warm" white light and successfully realized pressure-induced emission (PIE) upon even higher pressure up to 35.1 GPa in one-dimensional halide perovskite C₄N₂H₁₄PbCl₄. We reveal that the degree of structural distortion and the rearrangement of the multiple self-trapped states position are consistent with the intriguing photoluminescence variation, which is further supported by in situ high-pressure synchrotron X-ray diffraction experiments and time-resolved photoluminescence decay dynamics data. The underlying relationship between octahedron behavior and emission plays a key role to obtain high-quality white emission perovskites. We anticipate that this work enhances our understanding of structure-dependent self-trapped exciton (STE) emission characteristics and stimulates the design of high-performance WHPs for next generation white LED lighting devices.

SUBMITTER: Fang Y

PROVIDER: S-EPMC8395689 | biostudies-literature |

REPOSITORIES: biostudies-literature

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