Mechanisms of Tebuconazole Adsorption in Profiles of Mineral Soils.

ABSTRACT: The study attempted to identify the soil components and the principal adsorption mechanisms that bind tebuconazole in mineral soils. The KF values of the Freundlich isotherm determined in 18 soils from six soil profiles in batch experiments after 96 h of shaking ranged from 1.11 to 16.85 μg1-1/n (mL)1/n g-1, and the exponent 1/n values from 0.74 to 1.04. The adsorption of tebuconazole was inversely correlated with the soil pH. Both neutral and protonated forms of this organic base were adsorbed mainly on the fraction of humins. The adsorption of the protonated form increased in the presence of hydrogen cations adsorbed in the soil sorption sites. Fourier transform infrared spectroscopy coupled with the molecular modeling studies and partial least squares regression analysis indicated that

SUBMITTER: Siek M 

PROVIDER: S-EPMC8398351 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature