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Synthesis, crystal structure and magnetic properties of poly[[diaqua{μ6-2-[bis-(carboxyl-atometh-yl)amino]-terephthalato}-dicobalt(II)] 1.6-hydrate].


ABSTRACT: The asymmetric unit of the polymeric title compound {[Co2(C12H7NO8)(H2O)2]·1.6H2O} n comprises two CoII ions, which are coordinated by fully deprotonated 2-aminodi-acetic terephthalic acid (adtp4-) and terminal water mol-ecules in distorted octa-hedral N1O5 and O6 coordination environments. The title compound features tetra-nuclear CoII units bridged by κ 3 O:O:O'- and κ 3 O:O,O'-carboxyl-ate groups, which are joined into ribbons via syn-anti carboxyl-ate bridges. The parallel adtp4- ligands with an alternately reversed arrangement further link adjacent CoII ribbons into (010) layers, which are assembled into a three-dimensional supra-molecular network via inter-molecular hydrogen bonds. The disordered water solvent mol-ecules are situated in channels parallel to [100]. Magnetic measurements and analyses reveal that the title compound displays anti-ferromagnetic behaviour. The purity of the title compound was characterized by X-ray powder diffraction.

SUBMITTER: Ma J 

PROVIDER: S-EPMC8423006 | biostudies-literature |

REPOSITORIES: biostudies-literature

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