Unknown

Dataset Information

0

Crystal structures of three N-(pyridine-2-carbon-yl)pyridine-2-carboxamides as potential ligands for supra-molecular chemistry.

ABSTRACT: The synthesis and single-crystal X-ray structures of three N-(pyridine-2-carbon-yl)pyridine-2-carboxamide imides, with or without F atoms on the 3-position of the pyridine rings are reported, namely, N-(pyridine-2-carbon-yl)pyridine-2-carboxamide, C12H9N3O2 (1), N-(3-fluoro-pyridine-2-carbon-yl)pyridine-2-carboxamide, C12H8FN3O2 (2), and 3-fluoro-N-(3-fluoro-pyridine-2-carbon-yl)pyridine-2-carboxamide, C12H7F2N3O2 (3). The above-mentioned compounds were synthesized by a mild, general procedure with an excellent yield, providing straightforward access to symmetrical and/or asymmetrical heterocyclic ureas. The crystal structures of 1 and 2 are isomorphous, showing similar packing arrangements, i.e. double layers of parallel (face-to-face) mol-ecules alternating with analogous, but perpendicularly oriented, double layers. In contrast, the crystal structure of 3, containing a fluoro- group at the 3-position of both pyridine rings, shows mol-ecular arrangements in a longitudinal, tubular manner along the c axis, with the aromatic pyridine and carbon-yl/fluorine moieties facing towards each other.

SUBMITTER: Xu X 

PROVIDER: S-EPMC8423013 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structures of three <i>N</i>-(pyridine-2-carbon-yl)pyridine-2-carboxamides as potential ligands for supra-molecular chemistry.

Xu Xiaowen X   Hoogenboom Richard R   Van Hecke Kristof K  

Acta crystallographica. Section E, Crystallographic communications 20210824 Pt 9

The synthesis and single-crystal X-ray structures of three <i>N</i>-(pyridine-2-carbon-yl)pyridine-2-carboxamide imides, with or without F atoms on the 3-position of the pyridine rings are reported, namely, <i>N</i>-(pyridine-2-carbon-yl)pyridine-2-carboxamide, C<sub>12</sub>H<sub>9</sub>N<sub>3</sub>O<sub>2</sub> (<b>1</b>), <i>N</i>-(3-fluoro-pyridine-2-carbon-yl)pyridine-2-carboxamide, C<sub>12</sub>H<sub>8</sub>FN<sub>3</sub>O<sub>2</sub> (<b>2</b>), and 3-fluoro-<i>N</i>-(3-fluoro-pyridine-  ...[more]

Similar Datasets

Unknown Crystal structures of three <i>N</i>-(3-acetyl-phen-yl)quinoline-2-carboxamides.
| S-EPMC5458296 | biostudies-literature
Unknown The crystal structures of three pyrazine-2,5-dicarb-oxamides: three-dimensional supra-molecular structures.
| S-EPMC5418794 | biostudies-literature
Unknown Extracting Crystal Chemistry from Amorphous Carbon Structures.
| S-EPMC5413819 | biostudies-literature
Unknown The crystal structures of four N-(4-halophen-yl)-4-oxo-4H-chromene-3-carboxamides.
| S-EPMC4331845 | biostudies-literature
Unknown Crystal structures of three platinacyclic complexes bearing isopropyl eugenoxyacetate and pyridine derivatives.
| S-EPMC7336793 | biostudies-literature
Unknown The crystal structures of three clozapinium salts: different mol-ecular configurations, and supra-molecular assembly in one, two and three dimensions.
| S-EPMC4438793 | biostudies-literature
Unknown Crystal structures of three N-ar-yl-2,2,2-tri-bromo-acetamides.
| S-EPMC4555380 | biostudies-literature
Unknown Crystal structures of three N-(aryl-sulfon-yl)-4-fluoro-benzamides.
| S-EPMC4910346 | biostudies-literature
Unknown Two coordination modes of Cu(II) in a binuclear complex with N-(pyridin-2-yl-carbon-yl)pyridine-2-carboxamidate ligands.
| S-EPMC3470158 | biostudies-literature
Unknown Crystal structure of 4-(anthracen-9-yl)pyridine.
| S-EPMC8183450 | biostudies-literature