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Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth-oxy-3-(2-phenyl-hydrazinyl-idene)-1-benzo-furan-2(3H)-one.

ABSTRACT: In the title compound, C₁₅H₁₂N₂O₃, pairs of mol-ecules are linked into dimers by N-H⋯O hydrogen bonds, forming an R ² ₂(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π-π stacking inter-actions between the centroids of the benzene and furan rings of their 2,3-di-hydro-1-benzo-furan ring systems. Furthermore, there exists a C-H⋯π inter-action that consolidates the crystal packing. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (40.7%), O⋯H/H⋯O (24.7%), C⋯H/H⋯C (16.1%) and C⋯C (8.8%).

SUBMITTER: Atioglu Z

PROVIDER: S-EPMC8423015 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of (3Z)-7-meth-oxy-3-(2-phenyl-hydrazinyl-idene)-1-benzo-furan-2(3H)-one.

Atioğlu Zeliha Z Akkurt Mehmet M Askerova Ulviyya F UF Mukhtarova Sevinc H SH Askerov Rizvan K RK Mlowe Sixberth S

Acta crystallographica. Section E, Crystallographic communications 20210806 Pt 9

In the title compound, C15H12N2O3, pairs of mol-ecules are linked into dimers by N-H⋯O hydrogen bonds, forming an R 2 2(12) ring motif, with the dimers stacked along the a axis. These dimers are connected through π-π stacking inter-actions between the centroids of the benzene and furan rings of their 2,3-di-hydro-1-benzo-furan ring systems. Furthermore, there exists a C-H⋯π inter-action that consolidates the crystal ...[more]

PMID: 34584760

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