Unknown

Dataset Information

0

Protecting-group-free S-glycosylation towards thioglycosides and thioglycopeptides in water.


ABSTRACT: A facile and green S-glycosylation method has been developed featuring protecting-group-free and proceeding-in-water like enzymatic synthesis. Glycosylation of fluoride donors with thiol sugar acceptors using Ca(OH)2 as a promoter afforded various thioglycosides in good yields with exclusive stereoselectivity. This method also enabled the successful production of S-linked oligosaccharides and S-linked glycopeptides.

SUBMITTER: Zhang GL 

PROVIDER: S-EPMC8423405 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC8111381 | biostudies-literature
| S-EPMC5496566 | biostudies-other
| S-EPMC3762507 | biostudies-literature
| S-EPMC6155830 | biostudies-literature
| S-EPMC8252117 | biostudies-literature
| S-EPMC5941281 | biostudies-literature
| S-EPMC5426439 | biostudies-literature
| S-EPMC2742709 | biostudies-literature
| S-EPMC3869274 | biostudies-literature
| S-EPMC5969221 | biostudies-other