Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Voltage-controlled NiO/ZnO p-n heterojunction diode: a new approach towards selective VOC sensing.

ABSTRACT: Metal oxide resistive gas sensors suffer from poor selectivity that restricts their practical applicability. Conventional sensor arrays are used to improve selectivity which increased the system complexity. Here, we have proposed a novel NiO/ZnO-based p-n junction single-diode device for selective sensing of several volatile organic compounds (VOCs) simultaneously by tuning bias voltage. The operating voltage was varied between 3 and 5 volts to achieve selective sensing of 2-propanol (19.1 times for 95 ppm with response and recovery times of 70 s and 55 s respectively' at 3 volts), toluene (20.1 times for 95 ppm with response and recovery times of 100 s and 60 s respectively, at 4 volts), and formaldehyde (11.2 times for 95 ppm with response and recovery times of 88 s and 54 s respectively, at 5 volts). A probable mechanism of the tunable selectivity with operating bias voltage due to increase in surface carriers with increasing voltage was hence put forth. Thus, this device may play an important role to develop future selective multiple VOC sensor thereby replacing standard sensor arrays.

SUBMITTER: Dey S

PROVIDER: S-EPMC8433462 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Integrated spectral photocurrent density and reproducibility analyses of excitonic ZnO/NiO heterojunction.

Project description:In this data article, the excitonic ZnO/NiO heterojunction device (Patel et al., 2017) [1] was measured for the integrated photocurrent density and reproducibility. Photograph of the prepared devices of ZnO/NiO on the FTO/glass is presented. Integrated photocurrent density as a function of photon energy from the sunlight is presented. Quantum efficiency measurement system (McScienceK3100, Korea) compliance with International Measurement System was employed to measure ZnO/NIO devices. These data are shown for the 300-440 nm of segment of the sunlight (AM1.5G, http://rredc.nrel.gov/solar/spectra/am1.5/). Reproducibility measure of ZnO/NiO device was presented for nine devices with the estimated device performance parameters including the open circuit voltage, short circuit current density, fill factor and power conversion efficiency.

| S-EPMC5614732 | biostudies-literature

Self-powered p-NiO/n-ZnO heterojunction ultraviolet photodetectors fabricated on plastic substrates.

Project description:A self-powered ultraviolet (UV) photodetector (PD) based on p-NiO and n-ZnO was fabricated using low-temperature sputtering technique on indium doped tin oxide (ITO) coated plastic polyethylene terephthalate (PET) substrates. The p-n heterojunction showed very fast temporal photoresponse with excellent quantum efficiency of over 63% under UV illumination at an applied reverse bias of 1.2 V. The engineered ultrathin Ti/Au top metal contacts and UV transparent PET/ITO substrates allowed the PDs to be illuminated through either front or back side. Morphology, structural, chemical and optical properties of sputtered NiO and ZnO films were also investigated.

| S-EPMC4759661 | biostudies-literature

Hybrid quadrupole plasmon induced spectrally pure ultraviolet emission from a single AgNPs@ZnO:Ga microwire based heterojunction diode.

Project description:Ultraviolet light-emitting materials and devices with high-efficiency are required for many applications. One promising way to enhance the ultraviolet luminescence efficiency is by incorporating plasmonic nanostructures. However, a large energy mismatch between the plasmons and the light emitters greatly limits the direct realization of light enhancement. In this work, a single Ga-doped ZnO microwire prepared with large-sized Ag nanoparticle (the diameter d ∼ 200 nm) deposition (AgNPs@ZnO:Ga MW) was utilized to construct a high-performance heterojunction diode, with p-GaN serving as the hole injection layer. In addition to enhanced optical output, the emission spectra also revealed that typical near-band-edge (NBE) emission with higher wavelength stability centered around 378.0 nm was achieved, accompanied by narrowing of the spectral linewidth to around 10 nm. Thus, the interfacial and p-GaN emissions were successfully suppressed. The spectral profile of the emission spectra of the heterojunction diodes precisely matched the photoluminescence spectrum of the single ZnO:Ga MW, which indicates that the single ZnO:Ga MW can act as the active region for the radiative recombination of electrons and holes in the diode operation. In the emission mechanism, hybrid quadrupole plasmons induce the generation of hot electrons, which are then injected into the conduction band of the neighboring ZnO:Ga and are responsible for the NBE-type emission of the single MW based heterojunction diode. This novel emission enhancement and modulation principle can aid in the design and development of new types of luminescent materials and devices with high-efficiency, spectral stability and spectral purity.

| S-EPMC9417069 | biostudies-literature

A greener approach towards the development of graphene-Ag loaded ZnO nanocomposites for acetone sensing applications.

Project description:We report a facile, green synthesis of graphene/Ag/ZnO nanocomposites and their use as acetone sensors via a medicinal plant extraction assisted precipitation process. The choice of plant extract in combination with metal nitrates led to self-sustaining colloid chemistry. Along with the green synthesis strategy, structural, morphological and gas sensing properties are described.

| S-EPMC9073528 | biostudies-literature

New Insights towards High-Temperature Ethanol-Sensing Mechanism of ZnO-Based Chemiresistors.

Project description:In this work, we investigate ethanol (EtOH)-sensing mechanisms of a ZnO nanorod (NRs)-based chemiresistor using a near-ambient-pressure X-ray photoelectron spectroscopy (NAP-XPS). First, the ZnO NRs-based sensor was constructed, showing good performance on interaction with 100 ppm of EtOH in the ambient air at 327 °C. Then, the same ZnO NRs film was investigated by NAP-XPS in the presence of 1 mbar oxygen, simulating the ambient air atmosphere and O2/EtOH mixture at the same temperature. The partial pressure of EtOH was 0.1 mbar, which corresponded to the partial pressure of 100 ppm of analytes in the ambient air. To better understand the EtOH-sensing mechanism, the NAP-XPS spectra were also studied on exposure to O2/EtOH/H2O and O2/MeCHO (MeCHO = acetaldehyde) mixtures. Our results revealed that the reaction of EtOH with chemisorbed oxygen on the surface of ZnO NRs follows the acetaldehyde pathway. It was also demonstrated that, during the sensing process, the surface becomes contaminated by different products of MeCHO decomposition, which decreases dc-sensor performance. However, the ac performance does not seem to be affected by this phenomenon.

| S-EPMC7582869 | biostudies-literature

Gate-tunable carbon nanotube-MoS2 heterojunction p-n diode.

Project description:The p-n junction diode and field-effect transistor are the two most ubiquitous building blocks of modern electronics and optoelectronics. In recent years, the emergence of reduced dimensionality materials has suggested that these components can be scaled down to atomic thicknesses. Although high-performance field-effect devices have been achieved from monolayered materials and their heterostructures, a p-n heterojunction diode derived from ultrathin materials is notably absent and constrains the fabrication of complex electronic and optoelectronic circuits. Here we demonstrate a gate-tunable p-n heterojunction diode using semiconducting single-walled carbon nanotubes (SWCNTs) and single-layer molybdenum disulfide as p-type and n-type semiconductors, respectively. The vertical stacking of these two direct band gap semiconductors forms a heterojunction with electrical characteristics that can be tuned with an applied gate bias to achieve a wide range of charge transport behavior ranging from insulating to rectifying with forward-to-reverse bias current ratios exceeding 10(4). This heterojunction diode also responds strongly to optical irradiation with an external quantum efficiency of 25% and fast photoresponse <15 ?s. Because SWCNTs have a diverse range of electrical properties as a function of chirality and an increasing number of atomically thin 2D nanomaterials are being isolated, the gate-tunable p-n heterojunction concept presented here should be widely generalizable to realize diverse ultrathin, high-performance electronics and optoelectronics.

| S-EPMC3831469 | biostudies-literature

Ag2S-Sensitized NiO-ZnO Heterostructures with Enhanced Visible Light Photocatalytic Activity and Acetone Sensing Property.

Project description:Visible light-driven Ag2S-grafted NiO-ZnO ternary nanocomposites are synthesized using a facile and cost-effective homogeneous precipitation method. The structural, morphological, and optical properties were extensively studied, confirming the formation of ternary nanocomposites. The surface area of the synthesized nanocomposites was calculated by electrochemical double-layer capacitance (C dl). Ternary Ag2S/NiO-ZnO nanocomposites showed excellent visible light photocatalytic property which increases further with the concentration of Ag2S. The maximum photocatalytic activity was shown by 8% Ag2S/NiO-ZnO with a RhB degradation efficiency of 95%. Hydroxyl and superoxide radicals were found to be dominant species for photodegradation of RhB, confirmed by scavenging experiments. It is noteworthy that the recycling experiments demonstrated high stability and recyclable nature of the photocatalyst. Moreover, the electrochemical results indicated that the prepared nanocomposite exhibits remarkable activity toward detection of acetone. The fabricated nanocomposite sensor showed high sensitivity (4.0764 μA mmol L-1 cm-2) and a lower detection limit (0.06 mmol L-1) for the detection of acetone. The enhanced photocatalytic and the sensing property of Ag2S/NiO-ZnO can be attributed to the synergistic effects of strong visible light absorption, excellent charge separation, and remarkable surface properties.

| S-EPMC6682037 | biostudies-literature

NH3 Sensor Based on 3D Hierarchical Flower-Shaped n-ZnO/p-NiO Heterostructures Yields Outstanding Sensing Capabilities at ppb Level.

Project description:Hierarchical three-dimensional (3D) flower-like n-ZnO/p-NiO heterostructures with various ZnxNiy molar ratios (Zn5Ni1, Zn2Ni1, Zn1Ni1, Zn1Ni2 and Zn1Ni5) were synthesized by a facile hydrothermal method. Their crystal phase, surface morphology, elemental composition and chemical state were comprehensively investigated by XRD, SEM, EDS, TEM and XPS techniques. Gas sensing measurements were conducted on all the as-developed ZnxNiy-based sensors toward ammonia (NH3) detection under various working temperatures from 160 to 340 °C. In particular, the as-prepared Zn1Ni2 sensor exhibited superior NH3 sensing performance under optimum working temperature (280 °C) including high response (25 toward 100 ppm), fast response/recovery time (16 s/7 s), low detection limit (50 ppb), good selectivity and long-term stability. The enhanced NH3 sensing capabilities of Zn1Ni2 sensor could be attributed to both the specific hierarchical structure which facilitates the adsorption of NH3 molecules and produces much more contact sites, and the improved gas response characteristics of p-n heterojunctions. The obtained results clear demonstrated that the optimum n-ZnO/p-NiO heterostructure is indeed very promising sensing material toward NH3 detection for different applications.

| S-EPMC7506851 | biostudies-literature

Enhanced NO2 Sensing Performance of ZnO-SnO2 Heterojunction Derived from Metal-Organic Frameworks.

Project description:Nitrogen dioxide (NO2) is the major reason for acid rain and respiratory illness in humans. Therefore, rapid, portable, and effective detection of NO2 is essential. Herein, a novel and simple method to construct a ZnO-SnO2 heterojunction is fabricated by pyrolysis of bimetallic metal organic frameworks. The sensitivity of ZnO-SnO2 heterojunction towards 0.2 ppm NO2 under 180 °C is 37, which is 3 times that of pure ZnO and SnO2. The construction of heterojunction speeds up the response-recovery process, and this kind of material exhibits lower detection limit. The construction of heterojunction can significantly improve the NO2 sensitivity. The selectivity, stability, and moisture resistance of ZnO-SnO2 heterojunction are carried out. This could enable the realization of highly selective and sensitive portable detection of NO2.

| S-EPMC9658193 | biostudies-literature

High-Performance Deep Ultraviolet Photodetector Based on NiO/β-Ga2O3 Heterojunction.

Project description:Ultraviolet (UV) photodetector has attracted extensive interests due to its wide-ranging applications from defense technology to optical communications. The use of wide bandgap metal oxide semiconductor materials is of great interest in the development of UV photodetector due to their unique electronic and optical properties. In this work, deep UV photodetector based on NiO/β-Ga2O3 heterojunction was developed and investigated. The β-Ga2O3 layer was prepared by magnetron sputtering and exhibited selective orientation along the family of ([Formula: see text] 01) crystal plane after annealing. The photodetector demonstrated good performance with a high responsivity (R) of 27.43 AW-1 under a 245-nm illumination (27 μWcm-2) and the maximum detectivity (D*) of 3.14 × 1012 cmHz1/2 W-1, which was attributed to the p-NiO/n-β-Ga2O3 heterojunction.

| S-EPMC7036083 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data