Synthesis of Two-Dimensional C-C Bonded Truxene-Based Covalent Organic Frameworks by Irreversible Bronsted Acid-Catalyzed Aldol Cyclotrimerization.

ABSTRACT: The synthesis of new C-C bonded two-dimensional (2D) covalent organic frameworks (COFs) is highly desirable. Here, a simple but effective synthetic strategy has been developed using an irreversible Brønsted acid-catalyzed aldol cyclotrimerization reaction by virtue of truxene as a linkage. Nonolefin C-C bonded 2D truxene-based covalent organic frameworks (Tru-COFs) were constructed by polymerization of 1,3,5-triindanonebenzene (TDB). The structure formation was confirmed by wide-angle X-ray scattering, Fourier-transform infrared spectroscopy, and solid-state ¹³C CP/MAS NMR. The results showed that the Tru-COFs were porous (645 m²/g) and chemically stable. Benzyl methylene in conjugated Tru-COFs more effectively produced photoinduced radicals than the model truxene compound. Due to the radical photoresponsiveness, Tru-COFs were efficient catalysts for photocatalytic oxidation of sulfides. We expect that this will provide a new synthetic methodology to obtain C-C bonded functional 2D COFs.

SUBMITTER: Zhang Q 

PROVIDER: S-EPMC8435030 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature