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Superionicity, disorder, and bandgap closure in dense hydrogen chloride.


ABSTRACT: [Figure: see text].

SUBMITTER: Binns J 

PROVIDER: S-EPMC8442878 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Hydrogen bond networks play a crucial role in biomolecules and molecular materials such as ices. How these networks react to pressure directs their properties at extreme conditions. We have studied one of the simplest hydrogen bond formers, hydrogen chloride, from crystallization to metallization, covering a pressure range of more than 2.5 million atmospheres. Following hydrogen bond symmetrization, we identify a previously unknown phase by the appearance of new Raman modes and changes to x-ray  ...[more]

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