Dataset Information

Core-Shell Structured Magnetic Carboxymethyl Cellulose-Based Hydrogel Nanosorbents for Effective Adsorption of Methylene Blue from Aqueous Solution.

ABSTRACT: This article reports effective removal of methylene blue (MB) dyes from aqueous solutions using a novel magnetic polymer nanocomposite. The core-shell structured nanosorbents was fabricated via coating Fe₃O₄ nanoparticles with a layer of hydrogel material, that synthesized by carboxymethyl cellulose cross-linked with poly(acrylic acid-co-acrylamide). Some physico-chemical properties of the nanosorbents were characterized by various testing methods. The nanosorbent could be easily separated from aqueous solutions by an external magnetic field and the mass fraction of outer hydrogel shell was 20.3 wt%. The adsorption performance was investigated as the effects of solution pH, adsorbent content, initial dye concentration, and contact time. The maximum adsorption capacity was obtained at neutral pH of 7 with a sorbent dose of 1.5 g L^-1. The experimental data of MB adsorption were fit to Langmuir isotherm model and Pseudo-second-order kinetic model with maximum adsorption of 34.3 mg g^-1. XPS technique was applied to study the mechanism of adsorption, electrostatic attraction and physically adsorption may control the adsorption behavior of the composite nanosorbents. In addition, a good reusability of 83.5% MB recovering with adsorption capacity decreasing by 16.5% over five cycles of sorption/desorption was observed.

SUBMITTER: Zhou Y

PROVIDER: S-EPMC8466880 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:Microporous- and mesoporous-activated carbons were produced from longan seed biomass through physical activation with CO2 under the same activation conditions of time and temperature. The specially prepared mesoporous carbon showed the maximum porous properties with the specific surface area of 1773 m2/g and mesopore volume of 0.474 cm3/g which accounts for 44.1% of the total pore volume. These activated carbons were utilized as porous adsorbents for the removal of methylene blue (MB) from an aqueous solution and their effectiveness was evaluated for both the adsorption kinetics and capacity. The adsorption kinetic data of MB were analyzed by the pseudo-first-order model, the pseudo-second-order model, and the pore-diffusion model equations. It was found that the adsorption kinetic behavior for all carbons tested was best described by the pseudo-second-order model. The effective pore diffusivity (De) derived from the pore-diffusion model had the values of 4.657 × 10-7-6.014 × 10-7 cm2/s and 4.668 × 10-7-19.920 × 10-7 cm2/s for the microporous- and mesoporous-activated carbons, respectively. Three well-known adsorption models, namely the Langmuir, Freundlich and Redlich-Peterson equations were tested with the experimental MB adsorption isotherms, and the results showed that the Redlich-Peterson model provided the overall best fitting of the isotherm data. In addition, the maximum capacity for MB adsorption of 1000 mg/g was achieved with the mesoporous carbon having the largest surface area and pore volume. The initial pH of MB solution had virtually no effect on the adsorption capacity and removal efficiency of the methylene blue dye. Increasing temperature over the range from 35 to 55 °C increased the adsorption of methylene blue, presumably caused by the increase in the diffusion rate of methylene blue to the adsorption sites that could promote the interaction frequency between the adsorbent surface and the adsorbate molecules. Overall, the high surface area mesoporous carbon was superior to the microporous carbon in view of the adsorption kinetics and capacity, when both carbons were used for the removal of MB from an aqueous solution.

Dataset Information

Core-Shell Structured Magnetic Carboxymethyl Cellulose-Based Hydrogel Nanosorbents for Effective Adsorption of Methylene Blue from Aqueous Solution.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure