Ozonation of Decalin as a Model Saturated Cyclic Molecule: A Spectroscopic Study.
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ABSTRACT: Ozonolysis is used for oxidation of a model cyclic molecule-decalin, which may be considered as an analog of saturated cyclic molecules present in heavy oil. The conversion of decalin exceeds 50% with the highest yield of formation of acids about 15-17%. Carboxylic acids, ketones/aldehydes, and alcohols are produced as intermediate products. The methods of UV-visible, transmission IR, attenuated total reflection IR-spectroscopy, NMR and mass-spectrometry were used to identify reaction products and unravel a possible reaction mechanism. The key stage of the process is undoubtedly the activation of the first C-H bond and the formation of peroxide radicals.
SUBMITTER: Ershov BG
PROVIDER: S-EPMC8469405 | biostudies-literature |
REPOSITORIES: biostudies-literature
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