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Role of Fe Species of Ni-Based Catalysts for Efficient Low-Temperature Ethanol Steam Reforming.

ABSTRACT: The suppression of methane and coke formation over Ni-based catalysts for low temperature ethanol steam reforming remains challenging. This paper describes the structural evolution of Fe-modified Ni/MgAl₂O₄ catalysts and the influence of iron species on methane and coke suppression for low temperature ethanol steam reforming. Ni-Fe alloy catalysts are gradually oxidized by water to generate Ni-rich alloy and γ-Fe₂O₃ species at steam-to-carbon ratio of 4. The electron transfer from iron to nickel within Ni-Fe alloy weakens the CO adsorption and effectively alleviates the CO/CO₂ methanation. The oxidation capacity of γ-Fe₂O₃ species promotes the transformation of ethoxy to acetate groups to avoid methane formation and the elimination of carbon deposits for anticoking. Ni10Fe10/MgAl₂O₄ shows a superior performance with a highest H₂ yield of 4.6 mol/mol ethanol at 400 °C for 15 h. This research could potentially provide instructions for the design of Ni-based catalysts for low-temperature ethanol steam reforming.

SUBMITTER: Wu Y

PROVIDER: S-EPMC8479767 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:The effect of OH-groups on the surface of a Ni catalyst for low-temperature (473 K) steam reforming of methane in an electric field (EF) was investigated. Ni-doped YSZ (Zr0.65Y0.05Ni0.3O2) was chosen as a highly active catalyst for this purpose. The effects on catalyst activity of adding hydrogen and steam in the pre-treatment were assessed with and without EF. When an EF was applied, activity increased irrespective of the electronic state of Ni, whereas the metallic Ni state was necessary for activity without EF. Furthermore, the highest activity with EF was observed for the pre-treatment with a mixture of H2 and H2O. Investigation of the superiority using XPS measurements showed an increase in the amount of Ni(OH)2, OH groups and H2O near the surface after the activity test, which are regarded as the reaction sites with EF. This finding suggests that a pre-treatment with steam increases the surface OH groups and Ni(OH)2 on the Ni catalyst, and enhances surface proton conduction, thereby improving the activity. The effect of OH-groups on the surface of a Ni catalyst for low-temperature (473 K) steam reforming of methane in an electric field (EF) was investigated.

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Project description:Dry reforming of methane (DRM) is a promising reaction able to convert greenhouse gases (CO2 and CH4) into syngas: an important chemical feedstock. Several difficulties limit the applicability of DRM in conventional thermal catalytic reactions; it is an endothermic reaction that requires high temperatures, resulting in high carbon deposition and a low H2/CO ratio. Catalysis with the application of an electric field (EF) at low temperatures can resolve these difficulties. Synergistic effects with alloys have also been reported for reactions promoted by the application of EF. Therefore, the synergistic effects of low-temperature DRM and Ni–Fe bimetallic catalysts were investigated using various methods and several characterisations (XRD, XPS, FE-STEM, etc.), which revealed that Ni–Fe binary catalysts show high performance in low-temperature DRM. In particular, the Ni0.8Fe0.2 catalyst supported on CeO2 was found to carry out DRM in EF effectively and selectively by virtue of its bimetallic characteristics. Dry reforming of methane (DRM) is a promising reaction able to convert greenhouse gases (CO2 and CH4) into syngas: an important chemical feedstock.

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