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Facile Synthesis Strategy from Sludge-Derived Extracellular Polymeric Substances to Nitrogen-Doped Graphene Oxide-Like Material and Quantum Dots.

ABSTRACT: Extracellular polymeric substances (EPS) are microbial aggregates derived from waste sewage sludge accumulated in sewage treatment plants, which provides natural, renewable, and abundant carbon, nitrogen, oxygen sources for the development of carbon materials to achieve the value-added utilization of waste sewage sludge resources. In this work, a nitrogen-doped graphene oxide (GO)-like material (N-GO) was simply produced using EPS as starting materials. A facile H₂O₂ oxidation-assisted method (room temperature) was developed to synthesize nitrogen-doped GO-like quantum dots (N-GOQDs) with strong tunable fluorescence from N-GO for the first time. This approach eliminates the conventional use of toxic chemicals, concentrated acids as well as expensive equipment, and strict condition requirements, which provides new insights into the synthesis of N-GO and N-GOQDs. In addition, this H₂O₂-assisted method was further demonstrated to prepare yellow fluorescent GO quantum dots (GOQDs) from GO successfully. The as-prepared N-GO shows excellent adsorption capacity for removing organic matters (malachite green, rhodamine B, and methylene blue) from water in 10 min. The water-soluble N-GOQDs were demonstrated to be a low toxicity and good biocompatibility fluorescence probe for bioimaging.

SUBMITTER: Lin Q

PROVIDER: S-EPMC8482497 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:The current research mainly focuses on transforming low-quality waste into value-added nanomaterials and investigating various ways of utilising them. The hydrothermal preparation of highly fluorescent N-doped carbon dots (N-CDs) was obtained from the carboxymethylcellulose (CMC) of oil palm empty fruit bunches and linear-structured polyethyleneimines (LPEI). Transmission electron microscopy (TEM) analysis showed that the obtained N-CDs had an average size of 3.4 nm. The N-CDs were monodispersed in aqueous solution and were strongly fluorescent under the irradiation of ultra-violet light. A detailed description of the morphology and shape was established using Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS). It was shown that LPEI were successfully tuned the fluorescence (PL) properties of CDs in both the intrinsic and surface electronic structures, and enhanced the quantum yield (QY) up to 44%. The obtained N-CDs exhibited remarkable PL stability, long lifetime and pH-dependence behaviour, with the excitation/emission maxima of 350/465.5 nm. Impressively, PL enhancement and blue-shifted emission could be seen with the dilution of the original N-CDs solution. The obtained N-CDs were further applied as fluorescent probe for the identification of Cu2+ in aqueous media. The mechanism could be attributed to the particularly high thermodynamic affinity of Cu2+ for the N-chelate groups over the surface of N-CDs and the fast metal-to-ligand binding kinetics. The linear relationship between the relative quenching rate and the concentration of Cu2+ were applied between 1-30 µM, with a detection limit of 0.93 µM. The fluorescent probe was successfully applied for the detection of Cu2+ in real water. Moreover, a solid-state film of N-CDs was prepared in the presence of poly (vinyl alcohol) (PVA) polymer and found to be stable even after 72-h of continuous irradiation to UV-lamp. In contrast to the aqueous N-CDs, the composite film showed only an excitation independent property, with enhanced PL QY of around 47%. Due to the strong and stable emission nature of N-CDs in both aqueous and solid conditions, the obtained N-CDs are ideal for reducing the overall preparation costs and applying them for various biological and environmental applications in the future.

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Facile Synthesis Strategy from Sludge-Derived Extracellular Polymeric Substances to Nitrogen-Doped Graphene Oxide-Like Material and Quantum Dots.

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