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Electrochemical Performance of Orthorhombic CsPbI₃ Perovskite in Li-Ion Batteries.

ABSTRACT: A facile solution process was employed to prepare CsPbI₃ as an anode material for Li-ion batteries. Rietveld refinement of the X-ray data confirms the orthorhombic phase of CsPbI₃ at room temperature. As obtained from bond valence calculations, strained bonds between Pb and I are identified within PbI₆ octahedral units. Morphological study shows that the as-prepared δ-CsPbI₃ forms a nanorod-like structure. The XPS analysis confirm the presence of Cs (3d, 4d), Pb (4d, 4f, 5d) and I (3p, 3d, 4d). The lithiation process involves both intercalation and conversion reactions, as confirmed by cyclic voltammetry (CV) and first-principles calculations. Impedance spectroscopy coupled with the distribution function of relaxation times identifies charge transfer processes due to Li metal foil and anode/electrolyte interfaces. An initial discharge capacity of 151 mAhg^-1 is found to continuously increase to reach a maximum of ~275 mAhg^-1 at 65 cycles, while it drops to ~240 mAhg^-1 at 75 cycles and then slowly decreases to 235 mAhg^-1 at 100 cycles. Considering the performance and structural integrity during electrochemical performance, δ-CsPbI₃ is a promising material for future Li-ion battery (LIB) application.

SUBMITTER: Kaisar N

PROVIDER: S-EPMC8510073 | biostudies-literature |

REPOSITORIES: biostudies-literature

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