Unknown

Dataset Information

0

Nitrogen-Based Linkers with a Mesitylene Core: Synthesis and Characterization.


ABSTRACT: Mesitylene was used as a core in seven new tritopic nitrogen containing linkers. Three of the linkers, each containing three nitrile groups, were obtained through Suzuki, Sonogashira and Heck-type coupling reactions. Next, these were converted to tetrazol-5-yl moieties by the cycloaddition of sodium azide to the nitrile functionalities. The last linker, containing three 1,2,3-triazol-4-yl moieties, was synthesized by the Huisgen cycloaddition of phenyl azide to the corresponding alkyne. The latter was obtained via a Corey-Fuchs reaction sequence from the previously reported formyl derivative. As the proof of concept for their potential in MOF design, one of the nitriles was used to build an Ag-based network.

SUBMITTER: Bahrin LG 

PROVIDER: S-EPMC8512016 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC9417690 | biostudies-literature
| S-EPMC3023059 | biostudies-literature
| S-EPMC2546486 | biostudies-literature
| S-EPMC3212248 | biostudies-literature
| S-EPMC10975036 | biostudies-literature
| S-EPMC7590618 | biostudies-literature
| S-EPMC7317814 | biostudies-literature
| S-EPMC8871358 | biostudies-literature
| S-EPMC6085822 | biostudies-other
| S-EPMC7435895 | biostudies-literature