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Novel Porous Rhodium Metal-Organic Aerogel for Efficient Removal of Organic Dyes and Catalysis of Si-H Insertion Reactions.

ABSTRACT: Metal-organic gels (MOGs) are attracting increasing attention for removal of organic dyes from aqueous solution and for catalysis of Si-H insertion reactions. Herein, we report that a reaction of porphyrin derivative 1 with Rh₂(OAc)₄ generates stable metal-organic gels and subsequent subcritical carbon dioxide drying affords metal-organic aerogels. Owing to their micro- and mesoporosity, the aerogels adsorbed dyes. Moreover, aerogel I catalyzed Si-H insertion reactions to give organosilicon compounds in high yields.

SUBMITTER: Fu HG

PROVIDER: S-EPMC8515819 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature

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Novel Porous Rhodium Metal-Organic Aerogel for Efficient Removal of Organic Dyes and Catalysis of Si-H Insertion Reactions.

Fu Hong-Guang HG You Jinmao J

ACS omega 20210928 40

Metal-organic gels (MOGs) are attracting increasing attention for removal of organic dyes from aqueous solution and for catalysis of Si-H insertion reactions. Herein, we report that a reaction of porphyrin derivative 1 with Rh2(OAc)4 generates stable metal-organic gels and subsequent subcritical carbon dioxide drying affords metal-organic aerogels. Owing to their micro- and mesoporosity, the aerogels adsorbed dyes. Moreover, aerogel I catalyzed Si-H insertion reactio ...[more]

PMID: 34661030

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