Unconventional Disorder by Femtosecond Laser Irradiation in Fe₂O₃.

ABSTRACT: This paper demonstrates that femtosecond laser-irradiated Fe₂O₃ materials containing a mixture of α-Fe₂O₃ and ε-Fe₂O₃ phases showed significant improvement in their photoelectrochemical performance and magnetic and optical properties. The absence of Raman-active vibrational modes in the irradiated samples and the changes in charge carrier emission observed in the photocurrent density results indicate an increase in the density of defects and distortions in the crystalline lattice when compared to the nonirradiated ones. The magnetization measurements at room temperature for the nonirradiated samples revealed a weak ferromagnetic behavior, whereas the irradiated samples exhibited a strong one. The optical properties showed a reduction in the band gap energy and a higher conductivity for the irradiated materials, causing a higher current density. Due to the high performance observed, it can be applied in dye-sensitized solar cells and water splitting processes. Quantum mechanical calculations based on density functional theory are in accordance with the experimental results, contributing to the elucidation of the changes caused by femtosecond laser irradiation at the molecular level, evaluating structural, energetic, and vibrational frequency parameters. The surface simulations enable the construction of a diagram that elucidates the changes in nanoparticle morphologies.

SUBMITTER: Souza JC 

PROVIDER: S-EPMC8552326 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature