Ontology highlight
ABSTRACT:
SUBMITTER: Han J
PROVIDER: S-EPMC8565393 | biostudies-literature | 2021 Nov
REPOSITORIES: biostudies-literature
Han Jingqi J Cheng Shun-Cheung SC Yiu Shek-Man SM Tse Man-Kit MK Ko Chi-Chiu CC
Chemical science 20211005 42
A new class of luminescent bis(bipyridyl) Ru(ii) pyridyl acyclic carbene complexes with environmentally-sensitive dimerization equilibrium have been developed. Owing to the involvement of the orbitals of the diaminocarbene ligand in the emissive excited state, the phosphorescence properties of these complexes are strongly affected by H-bonding interactions with various H-bonding donor/acceptor molecules. With the remarkable differences in the emission properties of the monomer, dimer, and H-bond ...[more]