Dataset Information

A high-performance Al-air fuel cell using a mesh-encapsulated anode via Al–Zn energy transfer

ABSTRACT: Summary Aluminum-air fuel cells attract more attention because of their high specific energy, low cost, and friendly environment. However, the problems of hydrogen evolution corrosion and low anode efficiency of aluminum-air fuel cells remain unresolved. Herein, we propose an aluminum-air fuel cell using a mesh-encapsulated anode, where the energy redistribution can be achieved and the discharge performance of the fuel cell can be highly improved. The results show that the highest inhibition efficiency is 73.930% when the aluminum plate is immersed in 6 M potassium hydroxide solution containing 100% zinc oxide. The highest anode efficiency is up to 61.740% when the fuel cell using a mesh-encapsulated anode is discharged at 20 mA/cm2, which is more than 2 times than that of no mesh, and the highest capacity can reach 1839.842 mAh/g, which is 101.623% higher than before optimization. Thus, our studies are very instructive for the large-scale application of aluminum-air fuel cells. Graphical abstract Highlights • The energy redistribution strategy is proposed to inhibit Al self-corrosion• A structure of mesh-encapsulated anode is designed to utilize the energy of dead zinc• The anode efficiency of Al-air fuel cell is up to 61.740% at 20 mA/cm2• The capacity of Al-air fuel cell can reach 1839.842 mAh/g at 20 mA/cm2 Engineering; Materials application; Devices

SUBMITTER: Wei M

PROVIDER: S-EPMC8567389 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:This paper concerns the development of water-compatible fluorescent imaging probes with tunable photonic properties that can be excited at a single wavelength. Bichromophoric cassettes 1a-1c consisting of a BODIPY donor and a cyanine acceptor were prepared using a simple synthetic route, and their photophysical properties were investigated. Upon excitation of the BODIPY moiety at 488 nm the excitation energy is transferred through an acetylene bridge to the cyanine dye acceptor, which emits light at approximately 600, 700, and 800 nm, i.e., with remarkable dispersions. This effect is facilitated by efficient energy transfer that gives a "quasi-Stokes" shift between 86 and 290 nm, opening a huge spectral window for imaging. The emissive properties of the cassettes depend on the energy-transfer (ET) mechanism: the faster the transfer, the more efficient it is. Measurements of rates of ET indicate that a through-bond ET takes place in the cassettes 1a and 1b that is 2 orders of magnitude faster than the classical through-space, Förster ET. In the case of cassette 1c, however, both mechanisms are possible, and the rate measurements do not allow us to discern between them. Thus, the cassettes 1a-1c are well suited for multiplexing experiments in biotechnological methods that involve a single laser excitation source. However, for widespread application of these probes, their solubility in aqueous media must be improved. Consequently, the probes were encapsulated in calcium phosphate/silicate nanoparticles (diameter ca. 22 nm) that are freely dispersible in water. This encapsulation process resulted in only minor changes in the photophysical properties of the cassettes. The system based on cassette 1a was chosen to probe how effectively these nanoparticles could be used to deliver the dyes into cells. Encapsulated cassette 1a permeated Clone 9 rat liver cells, where it localized in the mitochondria and fluoresced through the acceptor part, i.e., red. Overall, this paper reports readily accessible, cyanine-based through-bond ET cassettes that are lypophilic but can be encapsulated to form nanoparticles that disperse freely in water. These particles can be used to enter cells and to label organelles.

Project description:Aluminum can enhance heat release of energetic composite in theory. However, the commonly used micron aluminum powder has several short comings like incomplete reaction and low reaction rate. Meanwhile, outer oxide shell of nano Al particle is thicker than micro Al, which leads to low active aluminum content and insufficient heat release. On the basis of previous research, reported fluoropolymers modified Al particles were compared and suitable F2311was chosen. Sub-micron scale Al (median particle size around 200 nm) was regarded as optimum coated object in consideration of activity content of aluminum powder changing with particle size. The super fine Al powder was prepared by electrical explosion method, and encapsulated in situ by selected fluorine rubber F2311. The experiments on thermal stability demonstrated F2311 coating thickness should be no less than 3.6 nm. These results were further confirmed by EXPLO5 thermo dynamic calculation. Calculated results showed that reaction characters of F2311 encapsulated Al exceeded conventional nano Al regardless of combustion and explosion. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), laser particle size analyzer and X-ray photoelectron spectroscopy (XPS) were used to characterize coated products' morphology, particle size distribution and interfacial bonding information. The results showed that the coated samples were generally spherical shape, with median particle size of 217.7 nm and coating thickness of 3.6 nm. The coating shell contained a small amount of alumina and aluminum fluoride besides fluoropolymer. The non-isothermal dynamic equations of Al/F2311 and Al/Al2O3 were deduced by TG/DSC simultaneous thermal analysis. Compared with conventional nano-Al, the apparent activation energy of Al/F2311 decreased by 45 kJ/mol and the first exothermic peak temperature was about 10 °C earlier. Moreover, heat release was nearly twice as conventional nano-Al. TG-DSC-MS coupled measurements certified that active Al was enveloped by 'fluorine atmosphere' while F2311 decomposed in range of 200-400 °C. Alumina was replaced with aluminum fluoride inside coating layer during 400-550 °C, which broadened the diffusion path and then accelerated the permeation of oxidizing gas. In addition, the exothermic of Al-F was obviously larger than Al-O. Consequently, the oxidation reaction was activated rapidly, especially in initial exothermic period. Fluoropolymer encapsulated sub-micron sized Al was a latent highly activity energetic fuel and a potential candidate for aluminum powder.

Dataset Information

A high-performance Al-air fuel cell using a mesh-encapsulated anode via Al–Zn energy transfer

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure