Synthesis and electronic structure analysis of the actinide allenylidenes, [{(NR₂)₃}An(CCCPh₂)]^- (An = U, Th; R = SiMe₃).

ABSTRACT: The reaction of [AnCl(NR₂)₃] (An = U, Th, R = SiMe₃) with in situ generated lithium-3,3-diphenylcyclopropene results in the formation of [{(NR₂)₃}An(CH[double bond, length as m-dash]C[double bond, length as m-dash]CPh₂)] (An = U, 1; Th, 2) in good yields after work-up. Deprotonation of 1 or 2 with LDA/2.2.2-cryptand results in formation of the anionic allenylidenes, [Li(2.2.2-cryptand)][{(NR₂)₃}An(CCCPh₂)] (An = U, 3; Th, 4). The calculated ¹³C NMR chemical shifts of the C_α, C_β, and C_γ nuclei in 2 and 4 nicely reproduce the experimentally assigned order, and exhibit a characteristic spin

SUBMITTER: Kent GT 

PROVIDER: S-EPMC8580070 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature