Origin and Geochemical Implications of Hopanoids in Saline Lacustrine Crude Oils from Huanghekou East Sag and Laizhouwan Northeastern Sag, Bohai Bay Basin.

ABSTRACT: A suite of low-mature crude oils (five high-sulfur oils and six low-sulfur oils) from the Huanghekou and the Laizhouwan Sags, Bohai Bay Basin, are analyzed to investigate the fate of the hopanoids. Abundant hopanes, such as secohopanes, 25-norhopanes, benzohopanes, aromatized secohopanes, and sulfide hopanes, are identified, and their carbon isotope compositions are determined. Varying ¹³C isotope values of C₃₁ hopane (-38.7-34.0‰) and C_29-30 hopanes (-38.5-31.5‰) suggest different bacterial sources of these compounds. The presence of 25-norhopanes with enriched heavy carbon isotopes in severely biodegraded oils suggests that they are microbially mediated products. The detection of the isotopically depleted C₂₉ and C₃₀ D-ring-8,14-seco

SUBMITTER: Niu C 

PROVIDER: S-EPMC8600536 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature