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Zinc Polyaleuritate Ionomer Coatings as a Sustainable, Alternative Technology for Bisphenol A-Free Metal Packaging.

ABSTRACT: Sustainable coatings for metal food packaging were prepared from ZnO nanoparticles (obtained by the thermal decomposition of zinc acetate) and a naturally occurring polyhydroxylated fatty acid named aleuritic (or 9,10,16-trihydroxyhexadecanoic) acid. Both components reacted, originating under specific conditions zinc polyaleuritate ionomers. The polymerization of aleuritic acid into polyaleuritate by a solvent-free, melt polycondensation reaction was investigated at different times (15, 30, 45, and 60 min), temperatures (140, 160, 180, and 200 °C), and proportions of zinc oxide and aleuritic acid (0:100, 5:95, 10:90, and 50:50, w/w). Kinetic rate constants calculated by infrared spectroscopy decreased with the amount of Zn due to the consumption of reactive carboxyl groups, while the activation energy of the polymerization decreased as a consequence of the catalyst effect of the metal. The adhesion and hardness of coatings were determined from scratch tests, obtaining values similar to robust polymers with high adherence. Water contact angles were typical of hydrophobic materials with values ≥94°. Both mechanical properties and wettability were better than those of bisphenol A (BPA)-based resins and most likely are related to the low migration values determined using a hydrophilic food simulant. The presence of zinc provided a certain degree of antibacterial properties. The performance of the coatings against corrosion was studied by electrochemical impedance spectroscopy at different immersion times in an aqueous solution of NaCl. Considering the features of these biobased lacquers, they can be potential materials for bisphenol A-free metal packaging.

SUBMITTER: Morselli D

PROVIDER: S-EPMC8611806 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Zinc oxide nanoparticles (ZnONP) were synthesized and characterized using SEM, EDAX, DLS and UV-Vis spectra. Its use as a nanofertilizer as an alternative to conventional zinc sulphate (ZnSO4.7H2O) was evaluated in five Zn-deficient soils with a variable pH range (7.2-8.7). For this, the carbon of the soil microbial biomass (SMBC), the bacterial population, the nutrient dynamics and the biometric parameters of the wheat crop were assessed. The varying dosages (0, 100, 200 and 500 mg/L), sizes (30-100 nm), and the spherical shape of ZnONPs were evaluated in comparison to ZnSO4.7H2O levels. Results showed the maximum SMBC and bacterial population at 100 mg/L of ZnONPs but a sharp decline at higher concentrations. In addition, soil application of ZnONPs at 5 mg/kg produced a higher root elongation (4.3-8.8%), shoot elongation (3.5-4.0%), total chlorophyll (4.9-5.6%), grain yield (1.7-2.3%) and grain Zn-content (1.6-2.1%) in comparison to the conventional ZnSO4.7H2O at 10 mg/L. ZnONPs at 100 mg/L produced a higher soil microbial biomass carbon (3.9-4.6%), bacterial population (7.2-9.0%), germination (22%) and grain Zn-content (17.9-20%) as compared to the conventional ZnSO4.7H2O at 0.5%. The higher grain Zn-contents could be attributed to the small size and high surface area of ZnONPs resulting in easy entry into the plant system either through root or foliar by penetrating the pores present in the cell membranes. Conversely, the conventional ZnSO4.7H2O, due to its larger size and higher solubility as compared to ZnONPs, has low retention in plant systems, high surface run-off and low fertilizer efficiency. Thus, the authors concluded to apply spherically synthesized ZnONPs (average size-36.7 nm) at 5 mg/kg in the soil application and 100 mg/L in the foliar application for maintaining SMBC and bacterial population, improving total chlorophyll, and grain Zn-contents and overall sustaining wheat production in Zn-deficient neutral and alkaline soils.Supplementary informationThe online version contains supplementary material available at 10.1007/s13205-021-02861-1.

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Zinc Polyaleuritate Ionomer Coatings as a Sustainable, Alternative Technology for Bisphenol A-Free Metal Packaging.

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