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Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries.


ABSTRACT: Defect engineering is a strategy that is attracting widespread attention for the possibility of modifying battery active materials in order to improve the cycling stability of the electrodes. However, accurate investigation and quantification of the effect of the defects on the electrochemical energy storage performance of the cell are not trivial tasks. Herein, we report the quantification of vanadium-defective clusters (i.e., up to 5.7%) in the V2O3 lattice via neutron and X-ray powder diffraction measurements, positron annihilation lifetime spectroscopy, and synchrotron-based X-ray analysis. When the vanadium-defective V2O3 is employed as cathode active material in an aqueous Zn coin cell configuration, capacity retention of about 81% after 30,000 cycles at 5 A g-1 is achieved. Density functional theory calculations indicate that the vanadium-defective clusters can provide favorable sites for reversible Zn-ion storage. Moreover, the vanadium-defective clusters allow the storage of Zn ions in V2O3, which reduces the electrostatic interaction between the host material and the multivalent ions.

SUBMITTER: Zhu K 

PROVIDER: S-EPMC8617200 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature

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Defect engineering on V<sub>2</sub>O<sub>3</sub> cathode for long-cycling aqueous zinc metal batteries.

Zhu Kefu K   Wei Shiqiang S   Shou Hongwei H   Shen Feiran F   Chen Shuangming S   Zhang Pengjun P   Wang Changda C   Cao Yuyang Y   Guo Xin X   Luo Mi M   Zhang Hongjun H   Ye Bangjiao B   Wu Xiaojun X   He Lunhua L   Song Li L  

Nature communications 20211125 1


Defect engineering is a strategy that is attracting widespread attention for the possibility of modifying battery active materials in order to improve the cycling stability of the electrodes. However, accurate investigation and quantification of the effect of the defects on the electrochemical energy storage performance of the cell are not trivial tasks. Herein, we report the quantification of vanadium-defective clusters (i.e., up to 5.7%) in the V<sub>2</sub>O<sub>3</sub> lattice via neutron an  ...[more]

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