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Poultry Feather Waste as Bio-Based Cross-Linking Additive for Ethylene Propylene Diene Rubber.

ABSTRACT: Most rubbers used today rely on sulphur as a cross-linking agent and carbon black from fossil resources to modify the mechanical properties. A very promising substitute can be found in natural keratins such as feathers. These are not only tough, but also contain a relevant amount of sulphur in the form of disulphide bridges. The present study shows that these can be activated under vulcanisation conditions and then bind covalently to EPDM rubber to form a cross-linked network. Feathers were cut into lengths of 0.08, 0.2, and 1 mm and incorporated at 38, 69, or 100 phr into EPDM mixtures containing either no carbon black or no carbon black nor sulphur. The presence of feather cuttings increases the tensile and compressive strength as well as the hardness, and reduces the rebound resilience. Due to their high (approximately 17%) nitrogen content, the feathers also improve the thermal stability of the composite, as the main degradation step is shifted from 400 °C to 470 °C and the decomposition is significantly slowed down. Since elastomers are a large market and feathers in particular are a high-volume waste, the combination of these two offers enormous ecological and economic prospects.

SUBMITTER: Brenner M

PROVIDER: S-EPMC8623415 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Phlogopite-Reinforced Natural Rubber (NR)/Ethylene-Propylene-Diene Monomer Rubber (EPDM) Composites with Aminosilane Compatibilizer.

Project description:Rubber compounding with two or more components has been extensively employed to improve various properties. In particular, natural rubber (NR)/ethylene-propylene-diene monomer rubber (EPDM) blends have found use in tire and automotive parts. Diverse fillers have been applied to NR/EPDM blends to enhance their mechanical properties. In this study, a new class of mineral filler, phlogopite, was incorporated into an NR/EPDM blend to examine the mechanical, curing, elastic, and morphological properties of the resulting material. The combination of aminoethylaminopropyltrimethoxysilane (AEAPS) and stearic acid (SA) compatibilized the NR/EPDM/phlogopite composite, further improving various properties. The enhanced properties were compared with those of NR/EPDM/fillers composed of silica or carbon black (CB). Compared with the NR/EPDM/silica composite, the incompatibilized NR/EPDM/phlogopite composite without AEAPS exhibited poorer properties, but NR/EPDM/phlogopite compatibilized by AEAPS and SA showed improved properties. Most properties of the compatibilized NR/EPDM/phlogopite composite were similar to those of the NR/EPDM/CB composite, except for the lower abrasion resistance. The NR/EPDM/phlogopite/AEAPS rubber composite may potentially be used in various applications by replacing expensive fillers, such as CB.

| S-EPMC8309489 | biostudies-literature

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| S-EPMC9051154 | biostudies-literature

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| S-EPMC8509601 | biostudies-literature

The Contribution of BaTiO<sub>3</sub> to the Stability Improvement of Ethylene-Propylene-Diene Rubber: Part I-Pristine Filler.

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| S-EPMC10181093 | biostudies-literature

Commercial Initiation of Feather Hydrolysate as Supreme Fertilizer: A Smart Bio-Cleaning Strategy of Poultry Waste.

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Project description:A Gram-stain-negative, rod-shaped, non-motile, non-spore-forming, aerobic, yellow-pigmented bacterium was isolated from chicken feather waste collected from an abattoir in Bloemfontein, South Africa. A polyphasic taxonomy study was used to describe and name the bacterial isolate, strain 1_F178T. The 16S rRNA gene sequence analysis and sequence comparison data indicated that strain 1_F178T was a member of the genus Chryseobacterium and was closely related to Chryseobacterium jejuense (99.1%) and Chryseobacterium nakagawai (98.7%). Overall genome similarity metrics (average nucleotide identity, digital DNA-DNA hybridization and average amino acid identity) revealed greatest similarity to the C. jejuense and C. nakagawai type strains but were below the threshold for species delineation. Genome sequencing revealed a genome size of 6.18 Mbp and a G+C content of 35.6 mol%. The major respiratory quinone and most abundant polar lipid of strain 1_F178T were menaquinone-6 and phosphatidylethanolamine, respectively. Strain 1_F178T had a typical fatty acid composition for Chryseobacterium species. On the basis of physiological, genotypic, phylogenetic and chemotaxonomic data, strain 1_F178T constitutes a novel species of Chryseobacterium, for which the name Chryseobacterium pennae sp. nov. is proposed. The type strain is 1_F178T (=LMG 30779T=KCTC 62759T).

| S-EPMC8489843 | biostudies-literature

Highly Deformable Porous Electromagnetic Wave Absorber Based on Ethylene-Propylene-Diene Monomer/Multiwall Carbon Nanotube Nanocomposites.

Project description:The need for electromagnetic interference (EMI) shields has risen over the years as the result of our digitally and highly connected lifestyle. This work reports on the development of one such shield based on vulcanized rubber foams. Nanocomposites of ethylene-propylene-diene monomer (EPDM) rubber and multiwall carbon nanotubes (MWCNTs) were prepared via hot compression molding using a chemical blowing agent as foaming agent. MWCNTs accelerated the cure and led to high shear-thinning behavior, indicative of the formation of a 3D interconnected physical network. Foamed nanocomposites exhibited lower electrical percolation threshold than their solid counterparts. Above percolation, foamed nanocomposites displayed EMI absorption values of 28-45 dB in the frequency range of the X-band. The total EMI shielding efficiency of the foams was insignificantly affected by repeated bending with high recovery behavior. Our results highlight the potential of cross-linked EPDM/MWCNT foams as a lightweight EM wave absorber with high flexibility and deformability.

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Effects of MWCNTs on Char Layer Structure and Physicochemical Reaction in Ethylene Propylene Diene Monomer Insulators.

Project description:As one of the most promising ablative fillers, multi-walled carbon nanotubes (MWCNTs) have been used to improve the ablative resistance of Ethylene-Propylene-Diene Monomer (EPDM) insulators by facilitating the carbothermal reduction reaction of silica. However, the contribution of MWCNTs to char layer structure of the insulators was unclear. In this work, the effects of MWCNTs on char layer structure and ablative resistance were investigated in different EPDM-based insulators with and without silica. The results showed that adding only 3 phr MWCNTs can reduce the linear ablation rate of EPDM-based insulators without silica by 31.7%, while 6 phr MWCNTs are required to obtain similar results in EPDM-based insulators with silica. The char layer morphology of the two insulators gradually evolved into a dense porous structure as MWCNTs content increased, but their formation mechanisms were different. The XRD and Raman spectrum showed that different physicochemical reactions occurred around MWCNTs under different charring components. The proposed ablation mechanism was further verified by designing alternating multilayer distribution of MWCNTs and silica. This work can guide the construction of desirable char layer structure for increasing the ablative resistance of EPDM-based insulators.

| S-EPMC9330200 | biostudies-literature

Efficient Keratinolysis of Poultry Feather Waste by the Halotolerant Keratinase from Salicola Marasensis.

Project description:Sustainable development in the bio-treatment of large-scale biomass bulks requires high performance enzymes adapted to extreme conditions. An extracellular keratinolytic extract was obtained from the culture broth of a halotolerant strain of Salicola marasensis. Keratin hydrolyzing activity of the concentrated enzyme extract was observed on a 100 mg of pretreated feather waste. The concentrated enzyme was able to hydrolyze the poultry feathers by 25% after 12 h incubation. The bio-waste material was optimally hydrolyzed at pH 9 and temperature of 40 °C. Among reductants, 1,4-dithiothreitol, L-cysteine, 2-mercaptoethanol, glutathione, and sodium sulfate showed the most remarkable effect on the bio-waste keratinolysis, while the tested surfactants and urea had no significant effect on the keratinolytic activity. Hexane and hexadecane indicated strong effect on keratinase activity and bio-treatment in the presence of 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) as a hydrophobic ionic liquid resulted in a maximal of 80% extraction yield of soluble proteins from feathers. Considering the stability of the extracellular keratinolytic content in [BMIM][PF6], the observed keratinase activity was noteworthy suggesting that the secreted enzyme may contribute to the bioconversion of feather wastes.

| S-EPMC7059026 | biostudies-literature

Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids.

Project description:The EPDM (ethylene-propylene-diene monomer) hybrids with improved thermal and radiation strengths containing 1 and 5 phr of polyhedral oligomeric silsesquioxane (vinyl-POSS, Ov-POSS) and/or 2 phr of microalgae (Chlorella vulgaris (CV) and Spirulinaplatensis (SP)) powders were investigated in respect to their thermal stability after γ-irradiation. The material durability under accelerated degradation was qualified by chemiluminescence and gelation, which prove the contribution of inorganic filler and microalgae extracts on the increase of hybrid thermal stability, as well as the interaction between added components (POSS and CV or SP). The activation energies and the durabilities under accelerated degradation were calculated, indicating their suitable usage as appropriate materials in various applications. The reported results indicate the improvement effect of both microalgal powders on the oxidation strength, but the contribution of Spirulinaplatensis grabs attention on its efficient effects upon the prevention of degradation under accelerated aging conditions. The thermal performances of the tested EPDM based hybrids are remarkably ameliorated, if the certain formulation includes Ov-POSS (5 phr) and Spirulinaplatensis (2 phr), certifying its suitability for the pertinent applications.

| S-EPMC8747662 | biostudies-literature

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