Unknown

Dataset Information

0

Electrochemical oxidation of ferricyanide.


ABSTRACT: We report the electrochemical oxidation of ferricyanide, [FeIII(CN)6]3- and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of [FeIII(CN)6]3- is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction elimination to give cis-[FeIII(CN)4(CH3CN)2]1- as stable product in acetonitrile. Speciation of the oxidation product by DFT calculations is underpinned by good agreement to experimental data.

SUBMITTER: Cheah MH 

PROVIDER: S-EPMC8629995 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC1185823 | biostudies-other
| S-EPMC3971654 | biostudies-literature
| S-EPMC6533286 | biostudies-literature
| S-EPMC7832140 | biostudies-literature
| S-EPMC8497995 | biostudies-literature
| S-EPMC10719393 | biostudies-literature
| S-EPMC4004216 | biostudies-literature
| S-EPMC5465511 | biostudies-literature
| S-EPMC6884519 | biostudies-literature
| S-EPMC7363609 | biostudies-literature