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Optimization of process parameters of self-purging microwave pyrolysis of corn cob for biochar production.

ABSTRACT: Microwave pyrolysis offers rapid and low-cost technology to upgrade agro-forestry residues to high-value products. I-optimal experimental design was used to determine the optimal combination of microwave power and exposure time to maximize biochar yield from corn cob. A validation experiment at optimal conditions of 600 W and 6.9 min produced an average yield of 56.98% on a dry and ash-free basis, agrees with the predicted value (3.43% error) and confirms the adequacy of the model yield equation. Characterization of biochar product revealed an organized mesoporous structure with a carbon content of 62.68%, surface area of 3.05 m²/g, pore volume of 0.003 cm³/g, capacitance range of 27.14-53.99 μF/g, energy density range of 6.0 × 10^-7 - 1.2 × 10^-6 Wh/kg, and power density range of 9.4 × 10^-4 - 2.49 × 10^-3 W/kg. The biochar produced would require further process to be considered for various industrial applications.

SUBMITTER: Quillope JCC

PROVIDER: S-EPMC8640472 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature

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Optimization of process parameters of self-purging microwave pyrolysis of corn cob for biochar production.

Quillope John Christian C JCC Carpio Rowena B RB Gatdula Kristel M KM Detras Monet Concepcion M MCM Doliente Stephen S SS

Heliyon 20211117 11

Microwave pyrolysis offers rapid and low-cost technology to upgrade agro-forestry residues to high-value products. I-optimal experimental design was used to determine the optimal combination of microwave power and exposure time to maximize biochar yield from corn cob. A validation experiment at optimal conditions of 600 W and 6.9 min produced an average yield of 56.98% on a dry and ash-free basis, agrees with the predicted value (3.43% error) and confirms the adequacy of the model yield equation ...[more]

PMID: 34901490

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Project description:Soil heavy metal contamination is a severe issue. The detrimental impact of contaminated heavy metals on the ecosystem depends on the chemical form of heavy metals. Biochar produced at 400 °C (CB400) and 600 °C (CB600) from corn cob was applied to remediate Pb and Zn in contaminated soil. After a one month amendment with biochar (CB400 and CB600) and apatite (AP) with the ratio of 3%, 5%, 10%, and 3:3% and 5:5% of the weight of biochar and apatite, the untreated and treated soil were extracted using Tessier's sequence extraction procedure. The five chemical fractions of the Tessier procedure were the exchangeable fraction (F1), carbonate fraction (F2), Fe/Mn oxide fraction (F3), organic matter (F4), and residual fraction (F5). The concentration of heavy metals in the five chemical fractions was analyzed using inductively coupled plasma mass spectroscopy (ICP-MS). The results showed that the total concentration of Pb and Zn in the soil was 3023.70 ± 98.60 mg kg-1 and 2034.33 ± 35.41 mg kg-1, respectively. These figures were 15.12 and 6.78 times higher than the limit standard set by the United States Environmental Protection Agency (U.S. EPA 2010), indicating the high level of contamination of Pb and Zn in the studied soil. The treated soil's pH, OC, and EC increased significantly compared to the untreated soil (p > 0.05). The chemical fraction of Pb and Zn was in the descending sequence of F2 (67%) > F5 (13%) > F1 (10%) > F3 (9%) > F4 (1%) and F2~F3 (28%) > F5 (27%) > F1 (16%) > F4 (0.4%), respectively. The amendment of BC400, BC600, and apatite significantly reduced the exchangeable fraction of Pb and Zn and increased the other stable fractions including F3, F4, and F5, especially at the rate of 10% of biochar and a combination of 5:5% of biochar and apatite. The effects of CB400 and CB600 on the reduction in the exchangeable fraction of Pb and Zn were almost the same (p > 0.05). The results showed that CB400, CB600, and the mixture of these biochars with apatite applied at 5% or 10% (w/w) could immobilize lead and zinc in soil and reduce the threat to the surrounding environment. Therefore, biochar derived from corn cob and apatite could be promising materials for immobilizing heavy metals in multiple-contaminated soil.

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Optimization of process parameters of self-purging microwave pyrolysis of corn cob for biochar production.

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Optimization of process parameters of self-purging microwave pyrolysis of corn cob for biochar production.

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