Project description:Solar powered water evaporation is a green and environmentally friendly water treatment technology, which is a hot research topic for water purification at present. Advanced structural design and hydrophilic photothermal materials have achieved efficient solar evaporation of pure water, but the long-term stability of high salinity desalination has become a problem that cannot be ignored in practical applications. In order to solve this problem, a hydrophobic honeycomb structure MXene/AuNFs composite membrane was proposed in this paper, which used the three-dimensional highly porous microstructure of MXene and multibranched structure of gold nanoflowers particles to improve the light absorption and photothermal conversion efficiency of MXene/AuNFs. At the same time, the surface of the composite membrane was modified with hydrophobic fluorosilane 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFTE). The hydrophobic layer can prevent the accumulation of salt particles on the surface of the membrane, so that the composite film can continue to produce water vapor in a high salt environment. With high utilization rate of light energy, multiple-level geometrical structures of MXene for rapid water transport on the filter membrane and salt barrier on the membrane good stability, the hydrophobic MXene/AuNFs achieves solar evaporation rate of 1.59 kg m-2 h-1 and solar conversion efficiency is 97.8%, and stable operation under simulated sea water conditions under one sun irradiation over more than 10 cycles. The hydrophobic MXene/AuNFs membrane proved to be an efficient and stable photothermal material for solar desalination.
Project description:The herein reported work describes the development of hierarchically-organized fluorescent nanomaterials inspired by plant antenna systems. These hybrid materials are based on nanostructured zeolitic materials (LTL zeolite) doped with laser dyes, which implies a synergism between organic and inorganic moieties. The non-interconnected channeled structure and pore dimensions (7.1 Å) of the inorganic host are ideal to order and align the allocated fluorophores inside, inferring also high thermal and chemical stability. These artificial antennae harvest a broad range of chromatic radiation and convert it into predominant red-edge or alternatively white-light emission, just choosing the right dye combination and concentration ratio to modulate the efficiency of the ongoing energy transfer hops. A further degree of organization can be achieved by functionalizing the channel entrances of LTL zeolite with specific tailor-made (stopcock) molecules via a covalent linkage. These molecules plug the channels to avoid the leakage of the guest molecules absorbed inside, as well as connect the inner space of the zeolite with the outside thanks to energy transfer processes, making the coupling of the material with external devices easier.
Project description:Solar-thermal conversion is considered as a green and simple means to improve the performance of energy storage materials, but often limited by the intrinsic photothermal properties of materials and crude structure design. Herein, inspired by the unique light trapping effect of wide leaf spiral grass during photosynthesis, a biomimetic structural photothermal energy storage system is developed, to further promote the solar thermal-driven pseudo capacitance improvement. In this system, three-dimensional printed tortional Kelvin cell arrays structure with interesting light trapping property functions as "spiral leaf blades" to improve the efficiency of light absorption, while graphene quantum dots/MXene nanohybrids with wide photothermal response range and strong electrochemical activity serve as "chloroplast" for photothermal conversion and energy storage. As expected, the biomimetic structure-enhanced photothermal supercapacitor achieves an ideal solar thermal-driven pseudo capacitance enhancement (up to 304%), an ultrahigh areal capacitance of 10.47 F cm-2 , remarkable photothermal response (surface temperature change of 50.1 °C), excellent energy density (1.18 mWh cm-2 ) and cycling stability (10000 cycles). This work not only offers a novel enhancement strategy for photothermal applications, but also inspires new structure designs for multifunctional energy storage and conversion devices.
Project description:Two-dimensional (2D) boron-based materials are receiving much attention as H2 storage media due to the low atomic mass of boron and the stability of decorating alkali metals on the surface, which enhance interactions with H2. This work investigates the suitability of Li, Na, and K decorations on 2D honeycomb borophene oxide (B2O) for H2 storage, using dispersion corrected density functional theory (DFT-D2). A high theoretical gravimetric density of 8.3 wt % H2 is achieved for the Li-decorated B2O structure. At saturation, each Li binds to two H2 with an average binding energy of -0.24 eV/H2. Born-Oppenheimer molecular dynamics simulations at temperatures of 100, 300, and 500 K demonstrate the stability of the Li-decorated structure and the H2 desorption behavior at different temperatures. Our findings indicate that Li-decorated 2D B2O is a promising material for reversible H2 storage and recommend experimental investigation of 2D B2O as a potential H2 storage medium.
Project description:The conversion of allergic pollen grains into carbon microstructures was carried out through a facile, one-step, solid-state pyrolysis process in an inert atmosphere. The as-prepared carbonaceous particles were further air activated at 300 °C and then evaluated as lithium ion battery anodes at room (25 °C) and elevated (50 °C) temperatures. The distinct morphologies of bee pollens and cattail pollens are resembled on the final architecture of produced carbons. Scanning Electron Microscopy images shows that activated bee pollen carbon (ABP) is comprised of spiky, brain-like, and tiny spheres; while activated cattail pollen carbon (ACP) resembles deflated spheres. Structural analysis through X-ray diffraction and Raman spectroscopy confirmed their amorphous nature. X-ray photoelectron spectroscopy analysis of ABP and ACP confirmed that both samples contain high levels of oxygen and small amount of nitrogen contents. At C/10 rate, ACP electrode delivered high specific lithium storage reversible capacities (590 mAh/g at 50 °C and 382 mAh/g at 25 °C) and also exhibited excellent high rate capabilities. Through electrochemical impedance spectroscopy studies, improved performance of ACP is attributed to its lower charge transfer resistance than ABP. Current studies demonstrate that morphologically distinct renewable pollens could produce carbon architectures for anode applications in energy storage devices.
Project description:Materials can be made strong, but as such they are often brittle and prone to fracture when under stress. Inspired by the exceptionally strong and ductile structure of byssal threads found in certain mussels, we have designed and manufactured a multi-hierarchical steel, based on an inexpensive austenitic stainless steel, which defeats this "conflict" by possessing both superior strength and ductility. These excellent mechanical properties are realized by structurally introducing sandwich structures at both the macro- and nano-scales, the latter via an isometric, alternating, dual-phase crystal phases comprising nano-band austenite and nano-lamellar martensite, without change in chemical composition. Our experiments (transmission and scanning electron microscopy, electron back-scattered diffraction, nano-indentation and tensile tests) and micromechanics simulation results reveal a synergy of mechanisms underlying such exceptional properties. This synergy is key to the development of vastly superior mechanical properties, and may provide a unique strategy for the future development of new super strong and tough (damage-tolerant), lightweight and inexpensive structural materials.
Project description:Ultra-thin flexible films have attracted wide attention because of their excellent ductility and potential versatility. In particular, the energy-harvesting films (EHFs) have become a research hotspot because of the indispensability of power source in various devices. However, the design and fabrication of such films that can capture or transform different types of energy from environments for multiple usages remains a challenge. Herein, the multifunctional flexible EHFs with effective electro-/photo-thermal abilities are proposed by successive spraying Ag microparticles and MXene suspension between on waterborne polyurethane films, supplemented by a hot-pressing. The optimal coherent film exhibits a high electrical conductivity (1.17×104 S m-1), excellent Joule heating performance (121.3 °C) at 2 V, and outstanding photo-thermal performance (66.2 °C within 70 s under 100 mW cm-1). In addition, the EHFs-based single-electrode triboelectric nanogenerators (TENG) give short-circuit transferred charge of 38.9 nC, open circuit voltage of 114.7 V, and short circuit current of 0.82 μA. More interestingly, the output voltage of TENG can be further increased via constructing the double triboelectrification layers. The comprehensive ability for harvesting various energies of the EHFs promises their potential to satisfy the corresponding requirements.
Project description:Solar-driven interfacial evaporation is an ideal technology for seawater desalination, and the corresponding system is mainly composed of a solar evaporator and a condensing collector. The traditional scheme focuses on the evaporation efficiency of the evaporator. Still, it ignores the influence of condensing collection scheme on the overall efficiency, which is one of the obstacles to the practical use of solar seawater desalination. Here, we reported a new solar-driven interfacial evaporation seawater desalination system by studying the influence of the condensation architecture, i.e., vapor flow by a fan and an air pump, sidewall material, transparent cover shape and material, evaporation level, and transparent cover heating, on the apparent collection efficiency of the system. The apparent collection efficiency was up to over 90% after optimization. This study is expected to promote the practical application of solar evaporation desalination technology.
Project description:This article provides the computational prediction of the atomistic architectures resulting from self-assembly of the polar heptapeptide sequences NYNYNYN, SYSYSYS and GYGYGYG. Using a combination of molecular dynamics and a newly developed tool for non-covalent interaction analysis, we uncover the properties of a new class of bionanomaterials, including hydrogen-bonded polar zippers, and the relationship between peptide composition, fibril geometry and weak interaction networks. Our results, corroborated by experimental observations, provide the basis for the rational design of prion-inspired nanomaterials.
Project description:Natural products make up a large proportion of medicine available today. Cannabinoids from the plant Cannabis sativa is one unique class of meroterpenoids that have shown a wide range of bioactivities and recently seen significant developments in their status as therapeutic agents for various indications. Their complex chemical structures make it difficult to chemically synthesize them in efficient yields. Synthetic biology has presented a solution to this through metabolic engineering in heterologous hosts. Through genetic manipulation, rare phytocannabinoids that are produced in low yields in the plant can now be synthesized in larger quantities for therapeutic and commercial use. Additionally, an exciting avenue of exploring new chemical spaces is made available as novel derivatized compounds can be produced and investigated for their bioactivities. In this review, we summarized the biosynthetic pathways of phytocannabinoids and synthetic biology efforts in producing them in heterologous hosts. Detailed mechanistic insights are discussed in each part of the pathway in order to explore strategies for creating novel cannabinoids. Lastly, we discussed studies conducted on biological targets such as CB1, CB2 and orphan receptors along with their affinities to these cannabinoid ligands with a view to inform upstream diversification efforts.