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Screen Printed Copper and Tantalum Modified Potassium Sodium Niobate Thick Films on Platinized Alumina Substrates.

ABSTRACT: We show how sintering in different atmospheres affects the structural, microstructural, and functional properties of ~30 μm thick films of K_0.5Na_0.5NbO₃ (KNN) modified with 0.38 mol% K_5.4Cu_1.3Ta₁₀O₂₉ and 1 mol% CuO. The films were screen printed on platinized alumina substrates and sintered at 1100 °C in oxygen or in air with or without the packing powder (PP). The films have a preferential crystallographic orientation of the monoclinic perovskite phase in the [100] and [-101] directions. Sintering in the presence of PP contributes to obtaining phase-pure films, which is not the case for the films sintered without any PP notwithstanding the sintering atmosphere. The latter group is characterized by a slightly finer grain size, from 0.1 μm to ~2 μm, and lower porosity, ~6% compared with ~13%. Using piezoresponse force microscopy (PFM) and electron backscatter diffraction (EBSD) analysis of oxygen-sintered films, we found that the perovskite grains are composed of multiple domains which are preferentially oriented. Thick films sintered in oxygen exhibit a piezoelectric d₃₃ coefficient of 64 pm/V and an effective thickness coupling coefficient k_t of 43%, as well as very low mechanical losses of less than 0.5%, making them promising candidates for lead-free piezoelectric energy harvesting applications.

SUBMITTER: Kmet B

PROVIDER: S-EPMC8658548 | biostudies-literature |

REPOSITORIES: biostudies-literature

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