Lattice site-dependent metal leaching in perovskites toward a honeycomb-like water oxidation catalyst.

ABSTRACT: Metal leaching during water oxidation has been typically observed in conjunction with surface reconstruction on perovskite oxide catalysts, but the role of metal leaching at each geometric site has not been distinguished. Here, we manipulate the occurrence and process of surface reconstruction in two model ABO₃ perovskites, i.e., SrSc_0.5Ir_0.5O₃ and SrCo_0.5Ir_0.5O₃, which allow us to evaluate the structure and activity evolution step by step. The occurrence and order of leaching of Sr (A-site) and Sc/Co (B-site) were controlled by tailoring the thermodynamic stability of B-site. Sr leaching from A-site mainly generates more electrochemical surface area for the reaction, and additional leaching of Sc/Co from B-site t

SUBMITTER: Chen Y 

PROVIDER: S-EPMC8664262 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature