PV in the circular economy, a dynamic framework analyzing technology evolution and reliability impacts.
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ABSTRACT:
SUBMITTER: Ovaitt S
PROVIDER: S-EPMC8683597 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:The concept of a circular economy (CE) is gaining increasing attention from policy makers, industry, and academia. There is a rapidly evolving debate on definitions, limitations, the contribution to a wider sustainability agenda, and a need for indicators to assess the effectiveness of circular economy measures at larger scales. Herein, we present a framework for a comprehensive and economy-wide biophysical assessment of a CE, utilizing and systematically linking official statistics on resource extraction and use and waste flows in a mass-balanced approach. This framework builds on the widely applied framework of economy-wide material flow accounting and expands it by integrating waste flows, recycling, and downcycled materials. We propose a comprehensive set of indicators that measure the scale and circularity of total material and waste flows and their socioeconomic and ecological loop closing. We applied this framework in the context of monitoring efforts for a CE in the European Union (EU28) for the year 2014. We found that 7.4 gigatons (Gt) of materials were processed in the EU and only 0.71 Gt of them were secondary materials. The derived input socioeconomic cycling rate of materials was therefore 9.6%. Further, of the 4.8 Gt of interim output flows, 14.8% were recycled or downcycled. Based on these findings and our first efforts in assessing sensitivity of the framework, a number of improvements are deemed necessary: improved reporting of wastes, explicit modeling of societal in-use stocks, introduction of criteria for ecological cycling, and disaggregated mass-based indicators to evaluate environmental impacts of different materials and circularity initiatives.
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Project description:Healthy pond ecosystems are critical for achieving several sustainable development goals (SDG) through numerous ecosystem services (e.g., flood control, nutrient retention, and carbon sequestration). However, the socio-economic and ecological value of ponds is often underestimated compared to the larger water bodies. Ponds are highly vulnerable to mounting land-use pressures (e.g., urban expansion, and agriculture intensification) and environmental changes, leading to degradation and loss of the pond ecosystem. The narrow utilitarian use-based conservation fails to recognize the multiple anthropogenic pressures and provides narrow solutions which are inefficient to regenerate the degraded pond ecosystem. In this paper, we holistically examined the legal challenges (policies) and key anthropogenic and environmental pressures responsible for pond degradation in India. The country is strongly dedicated to attaining SDG and circular economy (CE) through aquatic ecosystem conservation and restoration. Considerable efforts are required at the administration level to recognize the contribution of pond ecosystem services in attaining global environmental goals and targets. Worldwide restoration strategies were reviewed, and a framework for pond restoration and conservation was proposed, which includes policies and incentives, technologies such as environmental-DNA (e-DNA), life cycle assessment (LCA), and other ecohydrological measures. Nature-based solutions (NBS) offer a sustainable and cost-effective approach to restoring the pond's natural processes. Furthermore, linkage between the pond ecosystem and the CE was assessed to encourage a regenerative system for biodiversity conservation. This study informs the need for extensive actions and legislative reforms to restore and conserve the pond ecosystems.Supplementary informationThe online version contains supplementary material available at 10.1007/s13157-022-01624-9.
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Project description:Bioplastics - typically plastics manufactured from bio-based polymers - stand to contribute to more sustainable commercial plastic life cycles as part of a circular economy, in which virgin polymers are made from renewable or recycled raw materials. Carbon-neutral energy is used for production and products are reused or recycled at their end of life (EOL). In this Review, we assess the advantages and challenges of bioplastics in transitioning towards a circular economy. Compared with fossil-based plastics, bio-based plastics can have a lower carbon footprint and exhibit advantageous materials properties; moreover, they can be compatible with existing recycling streams and some offer biodegradation as an EOL scenario if performed in controlled or predictable environments. However, these benefits can have trade-offs, including negative agricultural impacts, competition with food production, unclear EOL management and higher costs. Emerging chemical and biological methods can enable the 'upcycling' of increasing volumes of heterogeneous plastic and bioplastic waste into higher-quality materials. To guide converters and consumers in their purchasing choices, existing (bio)plastic identification standards and life cycle assessment guidelines need revision and homogenization. Furthermore, clear regulation and financial incentives remain essential to scale from niche polymers to large-scale bioplastic market applications with truly sustainable impact.
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Project description:The rapid growth of the livestock sector in some areas of Europe has caused an imbalance between the generation of livestock manure and the availability of agricultural soil for its direct application as a fertilizer. Since the transport of pig slurry to other areas with nutrient-deficient soils is costly from an economic point of view due to its high water content, the application of new technologies for the concentration of this waste is considered key for reducing management costs. Consequently, the main objective of this study was to demonstrate the potential of vibratory shear enhanced processing (VSEP) operated with reverse osmosis membranes to recover nutrients from the liquid fractions of pig slurry (LF-pig slurry) and digestate (LF-digestate) and obtain concentrated fertilizing products. Use of the VSEP unit permitted reductions in the water contents of the LF-pig slurry and LF-digestate, around 77% and 67%, respectively. Both VSEP concentrates were characterized by their significant nutrient contents and showed a nitrogen fertilizer replacement value similar to that of mineral fertilizer as demonstrated in a barley crop pot-test, although the salinity of the digestate concentrate was identified as a key limitation, negatively impacting the agronomic yield of the test crop.
| S-EPMC9501425 | biostudies-literature
Project description:Circular Economy (CE) is a growing topic, especially in the European Union, that promotes the responsible and cyclical use of resources possibly contributing to sustainable development. CE is an umbrella concept incorporating different meanings. Despite the unclear concept, CE is turned into defined action plans supported by specific indicators. To understand what indicators used in CE measure specifically, we propose a classification framework to categorise indicators according to reasoning on what (CE strategies) and how (measurement scope). Despite different types, CE strategies can be grouped according to their attempt to preserve functions, products, components, materials, or embodied energy; additionally, indicators can measure the linear economy as a reference scenario. The measurement scope shows how indicators account for technological cycles with or without a Life Cycle Thinking (LCT) approach; or their effects on environmental, social, or economic dimensions. To illustrate the classification framework, we selected quantitative micro scale indicators from literature and macro scale indicators from the European Union 'CE monitoring framework'. The framework illustration shows that most of the indicators focus on the preservation of materials, with strategies such as recycling. However, micro scale indicators can also focus on other CE strategies considering LCT approach, while the European indicators mostly account for materials often without taking LCT into account. Furthermore, none of the available indicators can assess the preservation of functions instead of products, with strategies such as sharing platforms, schemes for product redundancy, or multifunctionality. Finally, the framework illustration suggests that a set of indicators should be used to assess CE instead of a single indicator.
| S-EPMC6559262 | biostudies-literature
Project description:This paper investigates the economy-wide impact of the uptake of circular economy (CE) measures for the small open economy (SOE) of Belgium, in particular the impact of fiscal policies in support of lifetime extension through repair activities of household appliances. The impact assessment is completed by means of a computable general equilibrium model as this allows quantification of both the direct and indirect economic and environmental impact of simulated shocks. The results show that different fiscal policy types can steer an economy into a more circular direction. However, depending on the policy type, the impact on the SOE's macroeconomic structure and level of circularity differs. Furthermore, common claims attributed to a CE (e.g. local job creation or decreased import dependence) can be, but are not always, valid. Hence, policy-makers must prioritize their most important macroeconomic goals and opt for an according fiscal policy. Finally, this paper finds that the CO2 equivalent emissions calculated from a production (or territorial) perspective increase, while they decrease from a consumption perspective. This is explained by the substitution of international activities by local circular activities. This comparative analysis advocates for the consumption approach to assess the CE's impact on CO2 equivalent emissions.Supplementary informationThe online version contains supplementary material available at 10.1007/s00168-021-01079-6.
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Project description:The stricter regulation regarding the use of fluorinated gases (F-gases), as a consequence of their high Global Warming Potential (GWP), represents a challenge for the refrigeration industry. The design of alternatives requires the recycling of the low to moderate GWP compounds from current refrigerant blends. However, there is not a developed and standardized technology available to recover them, and once the life cycle of the refrigeration equipment has ended, most gases are incinerated. Fluorinated ionic liquids (FILs) can effectively perform as absorbents to the complex separation of F-gas mixtures. In this work, a methodology based on the COSMO-RS thermodynamic package integrated into an Aspen Plus process simulator was used to evaluate the performance of an FIL to recover difluoromethane (R-32) from the commercial blend R-407F. The environmental sustainability of the recovery process (circular economy scenario) was analyzed with a life cycle assessment (LCA) approach, comparing the obtained results with the conventional R-32 production (benchmark scenario). The results reveal a 30% recovery of 98 wt % R-32 suitable for further reuse with environmental load reduction in the 86-99% range compared to the R-32 production. This study can guide the development of new F-gas recovery technologies to improve the environmental impacts of these compounds from a circular economy perspective.
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Project description:The synthesis and bottom-up assembly of nanocellulose by microbes offers unique advantages to tune and meet key design criteria-rapid renewability, low toxicity, scalability, performance, and degradability-for multi-functional, circular economy textiles. However, development of green processing methods that meet these criteria remains a major research challenge. Here, we harness microbial biofabrication of nanocellulose and draw inspiration from ancient textile techniques to engineer sustainable biotextiles with a circular life cycle. The unique molecular self-organization of microbial nanocellulose (MC) combined with bio-phosphorylation with a lecithin treatment yields a compostable material with superior mechanical and flame-retardant properties. Specifically, treatment of MC with a lecithin-phosphocholine emulsion makes sites available to modulate cellulose cross-linking through hydroxyl, phosphate and methylene groups, increasing the interaction between cellulose chains. The resultant bioleather exhibits enhanced tensile strength and high ductility. Bio-phosphorylation with lecithin also redirects the combustion pathway from levoglucosan production towards the formation of foaming char as an insulating oxygen barrier, for outstanding flame retardance. Controlled color modulation is demonstrated with natural dyes. Life cycle impact assessment reveals that MC bioleather has up to an order of magnitude lower carbon footprint than conventional textiles, and a thousandfold reduction in the carcinogenic impact of leather production. Eliminating the use of hazardous substances, these high performance materials disrupt linear production models and strategically eliminate its toxicity and negative climate impacts, with widespread application in fashion, interiors and construction. Importantly, the biotextile approach developed in this study demonstrates the potential of biofabrication coupled with green chemistry for a circular materials economy.
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Project description:Improving the public's awareness of and engagement with sustainable practices is essential for transitioning from a linear to a circular economy (CE). This task is not trivial; however, research into new ways of effectively supporting awareness and engagement, especially in view of digitalization trends, is still missing. In this study, we investigate the ability of augmented reality (AR) technology to improve awareness of CE practices and to engage citizens, inclusively, in the CE approach. Specifically, we report on the development of a novel AR engagement tool and present the results of two studies undertaken using this tool to assess the reliability and validity of this engagement practice. The first study focuses on the citizens of a municipality in Greece, and the second focuses on the general public outside the municipality boundaries. Attributes related to user engagement, such as novelty, aesthetics, perceived usability, endurability, focused attention, self-efficacy, perceived learning, and interest in the topic, were assessed, as were factors affecting these attributes related to the participants' knowledge of CE principles and exposure to similar technologies. The two studies indicate that the AR engagement tool increased social inclusion and community cohesion and was able to successfully bring CE principles and benefits to the public's attention. Higher engagement levels were observed in participants who had limited exposure to the concept of CE prior to using the AR tool, and its use was found to improve their confidence and interest in CE. This study aspires to contribute to the ongoing discourse on the use of mobile AR and to support further evidence-based development of digital tools for public awareness and engagement.Supplementary informationThe online version contains supplementary material available at 10.1007/s43615-021-00137-7.
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Project description:Polyethylene terephthalate is one of the most abundantly used polymers, but also a significant pollutant in oceans. Due to growing environmental concerns, polyethylene terephthalate alternatives are highly sought after. Here we present readily recyclable polyethylene terephthalate analogues, made entirely from woody biomass. Central to the concept is a two-step noble metal free catalytic sequence (Cu20-PMO catalyzed reductive catalytic fractionation and Raney Ni mediated catalytic funneling) that allows for obtaining a single aliphatic diol 4-(3-hydroxypropyl) cyclohexan-1-ol in high isolated yield (11.7 wt% on lignin basis), as well as other product streams that are converted to fuels, achieving a total carbon yield of 29.5%. The diol 4-(3-hydroxypropyl) cyclohexan-1-ol is co-polymerized with methyl esters of terephthalic acid and furan dicarboxylic acid, both of which can be derived from the cellulose residues, to obtain polyesters with competitive Mw and thermal properties (Tg of 70-90 °C). The polymers show excellent chemical recyclability in methanol and are thus promising candidates for the circular economy.
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