Super-Flexible Freestanding BiMnO₃ Membranes with Stable Ferroelectricity and Ferromagnetism.

ABSTRACT: Multiferroic materials with flexibility are expected to make great contributions to flexible electronic applications, such as sensors, memories, and wearable devices. In this work, super-flexible freestanding BiMnO₃ membranes with simultaneous ferroelectricity and ferromagnetism are synthesized using water-soluble Sr₃ Al₂ O₆ as the sacrificial buffer layer. The super-flexibility of BiMnO₃ membranes is demonstrated by undergoing an ≈180° folding during an in situ bending test, which is consistent with the results of first-principles calculations. The piezoelectric signal under a bending radius of ≈500 µm confirms the stable existence of electric polarization in freestanding BiMnO₃ membranes. Moreover, the stable ferromagnetism of freestanding BiMnO₃ membranes is demonstrated after 100 times bending cycles with a bending radius of ≈2 mm. 5.1% uniaxial tensile strain is achieved in freestanding BiMnO₃ membranes, and the piezoresponse force microscopy (PFM) phase retention behaviors confirm that the ferroelectricity of membranes can survive stably up to the strain of 1.7%. These super-flexible membranes with stable ferroelectricity and ferromagnetism pave ways to the realizations of multifunctional flexible electronics.

SUBMITTER: Jin C 

PROVIDER: S-EPMC8693045 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature