Dataset Information

Constructing helical nanowires via polymerization-induced self-assembly.

ABSTRACT: While reliable strategies for constructing block copolymer (BCP) nanowires have been developed, helical nanowires are rarely reported in polymerization-induced self-assembly (PISA). Herein, in this work, a new strategy for constructing helical nanowires was developed via PISA mediated by a fluorinated stabilizer block. Ultralong nanowires with helical structure can be readily produced in a wide range of block compositions. In addition, the generality of this strategy was well testified by expanding monomer types. The achiral BCP nano-objects underwent a morphology transition from spheres to helical nanowires during aging. We believe this work will provide a general strategy for producing helical nanowires through PISA of achiral BCPs.

SUBMITTER: Chen Q

PROVIDER: S-EPMC8695331 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Constructing helical nanowires <i>via</i> polymerization-induced self-assembly.

Chen Qiumeng Q Li Yahui Y Liu Ming M Wu Xuan X Shen Jianliang J Shen Liangliang L

RSC advances 20210201 15

While reliable strategies for constructing block copolymer (BCP) nanowires have been developed, helical nanowires are rarely reported in polymerization-induced self-assembly (PISA). Herein, in this work, a new strategy for constructing helical nanowires was developed <i>via</i> PISA mediated by a fluorinated stabilizer block. Ultralong nanowires with helical structure can be readily produced in a wide range of block compositions. In addition, the generality of this strategy was well testified by ...[more]

PMID: 35423399

Similar Datasets

Project description:Polymerization-induced self-assembly (PISA) is a useful formulation for readily obtaining nanoparticles from block copolymers in situ. Reversible addition-fragmentation chain-transfer (RAFT) emulsion polymerization is utilized as one of the PISA formulations. Various factors have so far been investigated for obtaining nonspherical particles via RAFT emulsion polymerization, such as the steric structure of the shell, the glass-transition temperature (T g) of the core-forming block, and the water solubility of the core-forming monomer. This study focuses on core-forming blocks without changing the structure of the shell-forming block. In particular, we elucidate the balance between T g for the core-forming block and the water solubility of the core monomer. A series of alkyl methacrylates, such as methyl methacrylate (MMA), ethyl methacrylate (EMA), and n-propyl methacrylate (PrMA), are emulsion-polymerized in the presence of a poly[poly(ethylene glycol) methyl ether methacrylate] (PPEGMA) macromolecular chain-transfer agent via the RAFT process. The resulting in situ morphology changes to form shapes such as spheres, worms (toroids), and vesicles are systematically investigated. The properties of the core that determine whether a morphological change occurs from spheres are (i) the solubility of the core-forming monomer in water, (ii) the relationship between T g for the core-forming block and the polymerization temperature, and (iii) the hydrophobic core volume, which changes the packing parameter. These factors allow prediction of the block copolymer morphology produced during RAFT emulsion polymerization of other methacrylates such as n-butyl methacrylate (BuMA), tetrahydrofurfuryl methacrylate (THFMA) with physical properties of the homopolymer (poly(tetrahydrofurfuryl methacrylate) (PTHFMA)) between those for poly(MMA) (PMMA) and PBuMA, and 1-adamantyl methacrylate (ADMA) with low monomer solubility in water and high T g of the homopolymer (PADMA).

Dataset Information

Constructing helical nanowires via polymerization-induced self-assembly.

Publications

Constructing helical nanowires <i>via</i> polymerization-induced self-assembly.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets