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Application of Surfactant Modified Natural Zeolites for the Removal of Salicylic Acid-A Contaminant of Emerging Concern.

ABSTRACT: This work aimed to test composites (surfactant modified zeolites prepared by treatment of natural zeolites-clinoptilolite (IZ CLI) and/or phillipsite (PHIL75)-rich tuffs with two different amounts of cationic surfactants: cetylpyridinium chloride (CPyCl) and Arquad^® 2HT-75 (ARQ)) for the adsorption of salicylic acid (SA)-a common contaminant of emerging concern. Adsorption of SA was studied at different initial drug concentrations (in the range of 2-100 mg/L) in water solution. The Langmuir isotherm model showed the highest adsorption was achieved by bilayer composite of IZ CLI and CPyCl-around 11 mg/g. Kinetic runs were performed by using the initial drug concentration of 20 mg/L in the time interval from 0 to 75 min and pseudo-second order had good correlation with experimental data. The influence of the four different temperatures on the SA adsorption was also investigated and thermodynamic parameters suggested that the adsorption drug onto composites is an exothermic and nonspontaneous process, followed by the decrease of randomness at the solid/liquid interface during the adsorption. Zeta potential and Fourier-transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) had been performed for the characterization of composites after adsorption of SA confirming the presence of the drug at composite surfaces.

SUBMITTER: Smiljanic D

PROVIDER: S-EPMC8708488 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Removal of Hazardous Contaminants from Water by Natural and Zwitterionic Surfactant-modified Clay.

Project description:In this study, natural clay (NC) was collected from Saudi Arabia and modified by cocamidopropyl betaine (CAPB) at different conditions (CAPB concentration, reaction time, and reaction temperature). NC and modified clay (CAPB-NC) were characterized using X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, and N2 adsorption at 77 K. The adsorption efficiency of NC and CAPB-NC toward Pb2+ and reactive yellow 160 dye (RY160) was evaluated. The adsorption process was optimized in terms of solution initial pH and adsorbent dosage. Finally, the adsorption kinetics and isotherms were studied. The results indicated that NC consists of agglomerated nonporous particles composed of quartz and kaolinite. CAPB modification reduced the specific surface area and introduced new functional groups by adsorbing on the NC surface. The concentration of CAPB affects the adsorption of RY160 tremendously; the optimum concentration was 2 times the cation exchange capacity of NC. The equilibrium adsorption capacity of CAPB-NC toward RY160 was about 6 times that of NC and was similar for Pb2+. The adsorption process followed the pseudo-second-order kinetics for both adsorptive. RY160 adsorption on CAPB-NC occurs via multilayer formation while Pb2+ adsorption on NC occurs via monolayer formation..

| S-EPMC7114751 | biostudies-literature

Enhanced Sorption Performance of Natural Zeolites Modified with pH-Fractionated Humic Acids for the Removal of Methylene Blue from Water.

Project description:This work explores the effect of humic acids (HA) fractionation on the sorption ability of a natural zeolite (NYT)-HA adduct. HA were extracted from compost, fractionated via the pH fractionation method, and characterized via UV-Vis spectroscopy and gel permeation chromatography. The HA samples were immobilized onto NYT via thermal treatment. The resulting adducts (NYT-HA) were tested for their ability to remove methylene blue (MB) from an aqueous solution. It was found that the sorption performance of NYT-HA strongly depends on the chemical characteristics of humic acids. Sorption capacity increased with the molecular weight and hydrophobicity degree of the HA fractions. Hydrophobic and π-π interactions are likely the primary mechanisms by which MB interacts with HA. The sorption kinetic data conform to the pseudo-second-order model. The Freundlich isotherm model adequately described the sorption equilibrium and revealed that the uptake of MB onto NYT-HA is endothermic in nature.

| S-EPMC10609103 | biostudies-literature

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| S-EPMC3798008 | biostudies-other

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| S-EPMC7588452 | biostudies-literature

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| S-EPMC9416908 | biostudies-literature

A Robust Flow-Through Platform for Organic Contaminant Removal.

Project description:Achieving the greatest cleanup efficiency with minimal footprint remains a paramount goal of the water treatment industry. Toxic organic compounds threaten drinking water safety and require effective pretreatment. Hydroxyl radicals produced by the Fenton process (Fe2+/H2O2) destroy organic contaminants based on their strong oxidation potential. An upgraded reaction using solid catalysts, referred to as the Fenton-like process, was recently adopted to avoid the ferric sludge generation during the conventional Fenton process. However, most heterogeneous Fenton-like catalysts operate optimally at pH 3-5 and quite weakly in near-neutral water bodies. Here, we evaluate the feasibility of an electrolytically localized acid compartment (referred to as the Ella process) produced by electrochemical water splitting under flow-through conditions to facilitate the Fenton-like process. The Ella process boosts the activity of an immobilized iron oxychloride catalyst >10-fold, decomposing organic pollutants at a high flow rate. The robust performance in complex water bodies further highlights the promise of this platform.

| S-EPMC8341378 | biostudies-literature

Earth Abundant Oxidation Catalysts for Removal of Contaminants of Emerging Concern from Wastewater: Homogeneous Catalytic Screening of Monomeric Complexes.

Project description:Twenty novel Mn, Fe, and Cu complexes of ethylene cross-bridged tetraazamacrocycles with potentially copolymerizable allyl and benzyl pendant arms were synthesized and characterized. Multiple X-ray crystal structures demonstrate the cis-folded pseudo-octahedral geometry forced by the rigidifying ethylene cross-bridge and show that two cis coordination cites are available for interaction with substrate and oxidant. The Cu complexes were used to determine kinetic stability under harsh acidic and high-temperature conditions, which revealed that the cyclam-based ligands provide superior stabilization with half-lives of many minutes or even hours in 5 M HCl at 50-90 °C. Cyclic voltammetry studies of the Fe and Mn complexes reveal reversible redox processes indicating stabilization of Fe2+/Fe3+ and Mn2+/Mn3+/Mn4+ oxidation states, indicating the likelihood of catalytic oxidation for these complexes. Finally, dye-bleaching experiments with methylene blue, methyl orange, and rhodamine B demonstrate efficient catalytic decolorization and allow selection of the most successful monomeric catalysts for copolymerization to produce future heterogeneous water purification materials.

| S-EPMC10536317 | biostudies-literature

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Project description:Sulfur polymers produced through 'inverse vulcanization' exhibit various attributes, such as photocatalytic activity and a high capacity to adsorb heavy metals. Nevertheless, there is a lack of research investigating the use of sulfur polymers as materials for the removal of organic contaminants. In this work, porous sulfur polymers (PSPs) were synthesized from elemental sulfur and 1,3-diisopropenylbenzene, with porosity introduced via salt templating. The result is a material that can strongly adsorb and chemically neutralize a model organic contaminant (caffeine). PSPs show adsorption up to 5 times higher than a leading adsorption material (activated carbon). Furthermore, either the adsorption or degradation processes can govern the removal efficiency depending on the synthesis parameters of PSPs. This is the first-ever report demonstrating sulfur polymers as effective materials for removing emerging contaminants from water. The versatile synthesis of sulfur polymers offers variation, which means that there is much more to explore in this exciting research area.

| S-EPMC10999450 | biostudies-literature

Effect of Exchangeable Ions in Natural and Modified Zeolites on Ag Content, Ag Nanoparticle Formation and Their Antibacterial Activity.

Project description:To broaden the application of silver nanoparticles (AgNPs), which are well-known antibacterial agents, they are supported on different substrates to prevent aggregation, increase their surface area and antibacterial efficiency, and to be separated from the system more effectively at the end of treatment. To produce nanocomposites that consist of silver nanoparticles on natural and modified zeolites, silver ions (Ag+) were loaded onto zeolite (natural, Na-modified, H-modified) and then thermally reduced to AgNPs. The effect of the exchangeable cations in zeolite on Ag+ uptake, AgNPs formation, size and morphology was investigated by the TEM, SEM, EDX, XPS, UV-vis, XRD and BET methods. The silver amount in the nanocomposites decreased in the following order Na-modified zeolite > natural zeolite > H-modified zeolite. Microscopic techniques showed formation of AgNPs of 1-14 nm on natural and Na-modified zeolite, while the diameter of metal particles on H-modified zeolite was 12-42 nm. Diffuse reflectance UV-vis and XPS methods revealed the presence of both silver ions and AgNPs in the materials indicating that partial reduction of Ag+ ions took place upon heating at 400 °C in air. Additionally, antibacterial properties of the nanocomposites were tested against Escherichia coli, and it was found that Ag-containing composites originating from the Na-modified zeolite demonstrated the highest activity.

| S-EPMC8347238 | biostudies-literature

Study of Water Adsorption on EDTA-Modified LTA Zeolites.

Project description:The present work deals with the study of water adsorption on acid-modified zeolites A. Commercial zeolites 4A (Na form) and 5A (Ca form) were subjected to EDTA dealumination, and their structure, textural properties and stability were checked by XRD, EDX, NMR and N2 physisorption analyses. The water adsorption isotherms of the parent zeolites and their modified forms were measured at a temperature of 25 °C and up to a relative pressure of 0.9. The results show that the treatment with EDTA drastically changes the structural properties of the zeolites and increases the water adsorption capacity by up to 10%. The changes depend on the type of extra-framework cations (Na+ and Ca2+) and the EDTA concentration.

| S-EPMC9027755 | biostudies-literature

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