Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bi-Functional Paraffin@Polyaniline/TiO₂/PCN-222(Fe) Microcapsules for Solar Thermal Energy Storage and CO₂ Photoreduction.

ABSTRACT: A novel type of bi-functional microencapsulated phase change material (MEPCM) microcapsules with thermal energy storage (TES) and carbon dioxide (CO₂) photoreduction was designed and fabricated. The polyaniline (PANI)/titanium dioxide (TiO₂)/PCN-222(Fe) hybrid shell encloses phase change material (PCM) paraffin by the facile and environment-friendly Pickering emulsion polymerization, in which TiO₂ and PCN-222(Fe) nanoparticles (NPs) were used as Pickering stabilizer. Furthermore, a ternary heterojunction of PANI/(TiO₂)/PCN-222(Fe) was constructed due to the tight contact of the three components on the hybrid shell. The results indicate that the maximum enthalpy of MEPCMs is 174.7 J·g^-1 with encapsulation efficiency of 77.2%, and the thermal properties, chemical composition, and morphological structure were well maintained after 500 high-low temperature cycles test. Besides, the MEPCM was employed to reduce CO₂ into carbon monoxide (CO) and methane (CH₄) under natural light irradiation. The CO evolution rate reached up to 45.16 μmol g^-1 h^-1 because of the suitable band gap and efficient charge migration efficiency, which is 5.4, 11, and 62 times higher than pure PCN-222(Fe), PANI, and TiO₂, respectively. Moreover, the CO evolution rate decayed inapparently after five CO₂ photoreduction cycles. The as-prepared bi-functional MEPCM as the temperature regulating building materials and air purification medium will stimulate a potential application.

SUBMITTER: Sun W

PROVIDER: S-EPMC8746944 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Solar Light Photoactive Floating Polyaniline/TiO2 Composites for Water Remediation.

Project description:In the present study, the development of innovative polyurethane-polyaniline/TiO2 modified floating materials applied in the sorption and photodegradation of rhodamine B from water matrix under solar light irradiation is reported. All the materials were fabricated with inexpensive and easy approaches and were properly characterized. The effect of the kind of polyaniline (PANI) dopant on the materials' behavior was investigated, as well as the role of the conducting polymer in the pollutant abatement on the basis of its physico-chemical characteristics. Rhodamine B is removed by adsorption and/or photodegradation processes depending on the type of doping agent used for PANI protonation. The best materials were subjected to recycle tests in order to demonstrate their stability under the reaction conditions. The main transformation products formed during the photodegradation process were identified by ultraperformance liquid chromatography-mass spectrometry (UPLC/MS). The results demonstrated that photoactive floating PANI/TiO2 composites are useful alternatives to common powder photocatalysts for the degradation of cationic dyes.

| S-EPMC8619583 | biostudies-literature

Raspberry-Like Microspheres of Core-Shell Cr2 O3 @TiO2 Nanoparticles for CO2 Photoreduction.

Project description:To promote the interaction of p-n semiconductors, raspberry-like microspheres of core-shell Cr2 O3 @TiO2 nanoparticles have been fabricated through a five-step process. Raman spectroscopy of products calcined at various temperatures reveal that the titania shell causes crystal distortion of the Cr2 O3 core, without changing the microstructures of the fabricated core-shell microspheres. In situ and time-resolved synchrotron-based powder XRD reveals the formation of monoclinic TiO2 in the fourth step, but these monoclinic TiO2 nanocrystals undergo a phase transition when the applied calcination temperature is above 550?°C. As a result, TiO2 (B), a magnéli phase of Ti4 O7 and Cr2 Ti6 O15 compounds, resulting from inner doping between Cr2 O3 and TiO2 , is formed. The close interaction of Cr2 O3 and TiO2 forms a p-n junction that decreases the recombination of photogenerated electron-hole pairs, leading to enhanced production of CH4 by photocatalytic reduction of CO2 .

| S-EPMC6972636 | biostudies-literature

Highly-dispersed boron-doped graphene nanosheets loaded with TiO2 nanoparticles for enhancing CO2 photoreduction.

Project description:Boron doped graphene nanosheets (B-GR) as a p-type semiconductor, provides much more edges to facilitate the loading of TiO2 nanoparticles (P25). Highly-dispersed P25/B-GR nanosheets with the size of 20-50 nm, are successfully synthesized by the vacuum activation and ultraphonic method. The nanosized morphology can decrease the local density of defects which are induced by the boron substitutional doping, and make the B-GR keeping excellent conductivity and p-type transport property. Ti-O-C bonds are formed during the mixing process, which could efficiently transfer the electrons from TiO2 to B-GR and the holes from B-GR to TiO2. The tunable bandgap of B-GR determines the large potential application of P25/B-GR in the photoreduction of CO2 and other gaseous organic pollutants.

| S-EPMC5385886 | biostudies-literature

Electrocatalytic and Solar-Driven CO2 Reduction to CO with a Molecular Manganese Catalyst Immobilized on Mesoporous TiO2.

Project description:Electrocatalytic CO2 reduction to CO was achieved with a novel Mn complex, fac-[MnBr(4,4'-bis(phosphonic acid)-2,2'-bipyridine)(CO)3 ] (MnP), immobilized on a mesoporous TiO2 electrode. A benchmark turnover number of 112±17 was attained with these TiO2 |MnP electrodes after 2 h electrolysis. Post-catalysis IR spectroscopy demonstrated that the molecular structure of the MnP catalyst was retained. UV/vis spectroscopy confirmed that an active Mn-Mn dimer was formed during catalysis on the TiO2 electrode, showing the dynamic formation of a catalytically active dimer on an electrode surface. Finally, we combined the light-protected TiO2 |MnP cathode with a CdS-sensitized photoanode to enable solar-light-driven CO2 reduction with the light-sensitive MnP catalyst.

| S-EPMC5074277 | biostudies-literature

Accelerated Thermal Cycling Test of Microencapsulated Paraffin Wax/Polyaniline Made by Simple Preparation Method for Solar Thermal Energy Storage.

Project description:Microencapsulated paraffin wax/polyaniline was prepared using a simple in situ polymerization technique, and its performance characteristics were investigated. Weight losses of samples were determined by Thermal Gravimetry Analysis (TGA). The microencapsulated samples with 23% and 49% paraffin showed less decomposition after 330 °C than with higher percentage of paraffin. These samples were then subjected to a thermal cycling test. Thermal properties of microencapsulated paraffin wax were evaluated by Differential Scanning Calorimeter (DSC). Structure stability and compatibility of core and coating materials were also tested by Fourier transform infrared spectrophotometer (FTIR), and the surface morphology of the samples are shown by Field Emission Scanning Electron Microscopy (FESEM). It has been found that the microencapsulated paraffin waxes show little change in the latent heat of fusion and melting temperature after one thousand thermal recycles. Besides, the chemical characteristics and structural profile remained constant after one thousand thermal cycling tests. Therefore, microencapsulated paraffin wax/polyaniline is a stable material that can be used for thermal energy storage systems.

| S-EPMC5452494 | biostudies-other

Intermolecular cascaded ?-conjugation channels for electron delivery powering CO2 photoreduction.

Project description:Photoreduction of CO2 to fuels offers a promising strategy for managing the global carbon balance using renewable solar energy. But the decisive process of oriented photogenerated electron delivery presents a considerable challenge. Here, we report the construction of intermolecular cascaded ?-conjugation channels for powering CO2 photoreduction by modifying both intramolecular and intermolecular conjugation of conjugated polymers (CPs). This coordination of dual conjugation is firstly proved by theoretical calculations and transient spectroscopies, showcasing alkynyl-removed CPs blocking the delocalization of electrons and in turn delivering the localized electrons through the intermolecular cascaded channels to active sites. Therefore, the optimized CPs (N-CP-D) exhibiting CO evolution activity of 2247??mol?g-1?h-1 and revealing a remarkable enhancement of 138-times compared to unmodified CPs (N-CP-A).

| S-EPMC7051963 | biostudies-literature

Insights into the role of CuO in the CO2 photoreduction process.

Project description:The CO2 photoreduction process to produce light hydrocarbons is known to be influenced by the presence of CuO nanoparticles, but the actual role of this material, whether as a catalyst or a reactant, has not yet been revealed. In this work, we investigate the role of CuO nanoparticles produced by a solvothermal method as a catalyst in CO2-saturated water reaction media under UV light, considering the effects of different electrolytes (Na2C2O4, KBrO3, and NaOH) and temperatures on nanoparticle phase and activity. The electrolyte strongly influenced product selectivity (NaOH led to evolution of CH4, Na2C2O4 to CO, and KBrO3 to O2) and induced CuO phase change. A long-term analysis of these processes indicated that during the initial steps, CuO acted as a reactant, rather than as a catalyst, and was converted to CuCO3.Cu(OH)2, while the as-converted material acted as a catalyst in CO2 photoreduction, with conversion values comparable to those reported in the literature.

| S-EPMC6361925 | biostudies-literature

Photoreduction of Shewanella oneidensis Extracellular Cytochromes by Organic Chromophores and Dye-Sensitized TiO2.

Project description:The transfer of photoenergized electrons from extracellular photosensitizers across a bacterial cell envelope to drive intracellular chemical transformations represents an attractive way to harness nature's catalytic machinery for solar-assisted chemical synthesis. In Shewanella oneidensis MR-1 (MR-1), trans-outer-membrane electron transfer is performed by the extracellular cytochromes MtrC and OmcA acting together with the outer-membrane-spanning porin?cytochrome complex (MtrAB). Here we demonstrate photoreduction of solutions of MtrC, OmcA, and the MtrCAB complex by soluble photosensitizers: namely, eosin?Y, fluorescein, proflavine, flavin, and adenine dinucleotide, as well as by riboflavin and flavin mononucleotide, two compounds secreted by MR-1. We show photoreduction of MtrC and OmcA adsorbed on RuII -dye-sensitized TiO2 nanoparticles and that these protein-coated particles perform photocatalytic reduction of solutions of MtrC, OmcA, and MtrCAB. These findings provide a framework for informed development of strategies for using the outer-membrane-associated cytochromes of MR-1 for solar-driven microbial synthesis in natural and engineered bacteria.

| S-EPMC5215560 | biostudies-literature

Ti3+-self doped brookite TiO2 single-crystalline nanosheets with high solar absorption and excellent photocatalytic CO2 reduction.

Project description:Black brookite TiO2 single-crystalline nanosheets with outstanding photocatalytic activity toward CO2 reduction is prepared by a facile oxidation-based hydrothermal reaction method combined with post-annealing treatment. Large amount of Ti(3+) defects are introduced into the bulk of brookite nanoparticles, which increases the solar energy absorption and enhances the photocatalytic activity.

| S-EPMC4810378 | biostudies-other

Ordered colloidal clusters constructed by nanocrystals with valence for efficient CO2 photoreduction.

Project description:The ability to construct discrete colloidal clusters (CCs) as complex as molecular clusters is limited due to the lack of available colloidal building blocks and specific directional bonds. Here, we explore a strategy to organize anisotropic Prussian blue analog nanocrystals (NCs) toward CCs with open and highly ordered structures, experimentally realizing colloidal analogs to zeolitic clathrate structures. The directional interactions are derived from either crystallographic or morphological anisotropy of the NCs and achieved by the interplay of epitaxial growth, oriented attachment, and local packing. We attribute these interparticle interactions to enthalpic and entropic valences that imitate hybridized atomic orbitals of sp 3 d 2 octahedron and sp 3 d 3 f cube. Benefiting from the ordered multilevel porous structures, the obtained CCs exhibit greatly enhanced catalytic activity for CO2 photoreduction. Our work offers some fundamental insights into directional bonding among NCs and opens an avenue that promises access to unique CCs with unprecedented structures and applications.

| S-EPMC6910840 | biostudies-literature