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Natural Polymers-Based Materials: A Contribution to a Greener Future.

ABSTRACT: Natural polymers have emerged as promising candidates for the sustainable development of materials in areas ranging from food packaging and biomedicine to energy storage and electronics. In tandem, there is a growing interest in the design of advanced materials devised from naturally abundant and renewable feedstocks, in alignment with the principles of Green Chemistry and the 2030 Agenda for Sustainable Development. This review aims to highlight some examples of the research efforts conducted at the Research Team BioPol4fun, Innovation in BioPolymer-based Functional Materials and Bioactive Compounds, from the Portuguese Associate Laboratory CICECO-Aveiro Institute of Materials at the University of Aveiro, regarding the exploitation of natural polymers (and derivatives thereof) for the development of distinct sustainable biobased materials. In particular, focus will be given to the use of polysaccharides (cellulose, chitosan, pullulan, hyaluronic acid, fucoidan, alginate, and agar) and proteins (lysozyme and gelatin) for the assembly of composites, coatings, films, membranes, patches, nanosystems, and microneedles using environmentally friendly strategies, and to address their main domains of application.

SUBMITTER: Silva ACQ

PROVIDER: S-EPMC8747056 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Greener synthesis of chemical compounds and materials.

Project description:Modern trends in the greener synthesis and fabrication of inorganic, organic and coordination compounds, materials, nanomaterials, hybrids and nanocomposites are discussed. Green chemistry deals with synthesis procedures according to its classic 12 principles, contributing to the sustainability of chemical processes, energy savings, lesser toxicity of reagents and final products, lesser damage to the environment and human health, decreasing the risk of global overheating, and more rational use of natural resources and agricultural wastes. Greener techniques have been applied to synthesize both well-known chemical compounds by more sustainable routes and completely new materials. A range of nanosized materials and composites can be produced by greener routes, including nanoparticles of metals, non-metals, their oxides and salts, aerogels or quantum dots. At the same time, such classic materials as cement, ceramics, adsorbents, polymers, bioplastics and biocomposites can be improved or obtained by cleaner processes. Several non-contaminating physical methods, such as microwave heating, ultrasound-assisted and hydrothermal processes or ball milling, frequently in combination with the use of natural precursors, are of major importance in the greener synthesis, as well as solventless and biosynthesis techniques. Non-hazardous solvents including ionic liquids, use of plant extracts, fungi, yeasts, bacteria and viruses are also discussed in relation with materials fabrication. Availability, necessity and profitability of scaling up green processes are discussed.

| S-EPMC6894553 | biostudies-literature

Microporous Materials Based on Norbornadiene-Based Cross-Linked Polymers.

Project description:New microporous homopolymers were readily prepared from norbornadiene-2,5, its dimer and trimer by addition (vinyl) polymerization of the corresponding monomers with 60⁻98% yields. As a catalyst Pd-N-heterocyclic carbene complex or Ni(II) 2-ethylhexanoate activated with Na⁺[B(3,5-(CF₃)₂C₆H₃)₄]- or methylaluminoxane was used. The synthesized polynorbornenes are cross-linked and insoluble. They are glassy and amorphous polymers. Depending on the nature of the catalyst applied, BET surface areas were in the range of 420⁻970 m²/g. The polymers with the highest surface area were obtained in the presence of Pd-catalysts from the trimer of norbornadiene-2,5. The total pore volume of the polymers varies from 0.39 to 0.79 cm³/g, while the true volume of micropores was 0.14⁻0.16 cm³/g according to t-plot. These polymers gave CO₂ uptake from 1.2 to 1.9 mmol/g at 273 K and 1 atm. The porous structure of new polymers was also studied by means of wide-angle X-ray diffraction and positron annihilation lifetime spectroscopy.

| S-EPMC6401845 | biostudies-other

Gelatin-Tannin-Based Greener Binder Technology for Stone Shot and Stone Wool Materials: A Detailed Study.

Project description:The detailed study presented herein of gelatins modified with tannins as greener binder systems for stone wool and related materials has unveiled a versatile technology that offers a wide range of possibilities for tailor-making properties toward various application areas. Thus, high unaged and aged mechanical strengths in combination with low water solubilities may generally be obtained from the use of gelatins with higher gel strength (and hence, generally, higher molecular weights), low-to-mid range tannin addition levels (3-20%), alkali metal hydroxides for pH adjustment, and final pH in the range 8-9. Comparatively low water uptake properties may be obtained using higher gel strength type A gelatins, lower tannin addition levels, alkali metal hydroxides for pH adjustment, and lower final pH. Even lower water uptake properties may then be obtained using Ca(OH)2 in place of alkali metal hydroxides. If desired, higher water uptakes may be obtained using type B gelatins (or lower gel strength gelatins in general), higher tannin addition levels, and higher final pH. Mechanistic studies indicated that the optimal modification of gelatin with the tannin component occurs via several pathways.

| S-EPMC8674984 | biostudies-literature

Trehalose and trehalose-based polymers for environmentally benign, biocompatible and bioactive materials.

Project description:Trehalose is a non-reducing disaccharide that is found in many organisms but not in mammals. This sugar plays important roles in cryptobiosis of selaginella mosses, tardigrades (water bears), and other animals which revive with water from a state of suspended animation induced by desiccation. The interesting properties of trehalose are due to its unique symmetrical low-energy structure, wherein two glucose units are bonded face-to-face by 1-->1-glucoside links. The Hayashibara Co. Ltd., is credited for developing an inexpensive, environmentally benign and industrial-scale process for the enzymatic conversion of alpha-1,4-linked polyhexoses to alpha,alpha-D-trehalose, which made it easy to explore novel food, industrial, and medicinal uses for trehalose and its derivatives. Trehalosechemistry is a relatively new and emerging field, and polymers of trehalose derivatives appear environmentally benign, biocompatible, and biodegradable. The discriminating properties of trehalose are attributed to its structure, symmetry, solubility, kinetic and thermodynamic stability and versatility. While syntheses of trehalose-based polymer networks can be straightforward, syntheses and characterization of well defined linear polymers with tailored properties using trehalose-based monomers is challenging, and typically involves protection and deprotection of hydroxyl groups to attain desired structural, morphological, biological, and physical and chemical properties in the resulting products. In this review, we will overview known literature on trehalose's fascinating involvement in cryptobiology; highlight its applications in many fields; and then discuss methods we used to prepare new trehalose-based monomers and polymers and explain their properties.

| S-EPMC6245314 | biostudies-literature

Materials, energy, water, and emissions nexus impacts on the future contribution of PV solar technologies to global energy scenarios.

Project description:PV technologies are increasingly making significant contribution to global energy generation (GEG), attributed to their high potential of increasing efficiency, cost reduction, and improving energy security. These technologies however rely on metals that are identified as critical due to risks associated with their supply, and other materials that require energy and water for their production. In this paper, a comprehensive assessment of required materials for PV technologies, an analysis of their materials inflows, outflows, and stocks, an estimate of their maximum contribution to global energy scenarios (GES), and an estimate of energy and water required for their material production and associated CO2 emissions under the nexus approach, have been carried out using a dynamic material flow-stock model. A total of 100 energy-material nexus scenarios, which combines 10 GES and 10 materials scenarios, have been analysed. Results indicate that although most GES are difficult to be realized under current PV technologies market share and condition; these technologies could make significant contribution to GEG in future. The three commercial thin-film PV technologies could produce between 3% and 22% of electricity generation in IEA-450 scenario. Energy required for PV materials production is expected to reach between 5.9% and 11.8% of electricity generated (EG) by PV solar and between 0.76% and 1.52% of total EG in IEA-450 scenario by 2050. CO2 emissions associated with material production are expected to be between 0.94% and 2.2% of total CO2 emissions in IEA-450 scenario by 2050.

| S-EPMC6917800 | biostudies-literature

Designing High-Refractive Index Polymers Using Materials Informatics.

Project description:A machine learning strategy is presented for the rapid discovery of new polymeric materials satisfying multiple desirable properties. Of particular interest is the design of high refractive index polymers. Our in silico approach employs a series of quantitative structure⁻property relationship models that facilitate rapid virtual screening of polymers based on relevant properties such as the refractive index, glass transition and thermal decomposition temperatures, and solubility in standard solvents. Exploration of the chemical space is carried out using an evolutionary algorithm that assembles synthetically tractable monomers from a database of existing fragments. Selected monomer structures that were further evaluated using density functional theory calculations agree well with model predictions.

| S-EPMC6415069 | biostudies-literature

Three Carbazole-Based Polymers as Potential Anodically Coloring Materials for High-Contrast Electrochromic Devices.

Project description:Three carbazole-based conjugated polymers (poly(3,6-di(2-thienyl)carbazole) (PDTC), poly(2,7-bis(carbazol-9-yl)-9,9-spirobifluorene) (PS2CBP), and poly(3,6-bis(N-carbazole)-N-ethylcarbazole) (PCEC)) are synthesized using electrochemical polymerization. The spectroelectrochemical studies indicate that the PDTC, PS2CBP, and PCEC films show reversible electrochromic behaviors in their redox states, and the PS2CBP film shows a distinct color transition with four various colors (gray at 0 V, grayish-green at 1.0 V, moss green at 1.2 V, and foliage green at 1.4 V). The maximum optical contrast of the PS2CBP and PCEC films is 39.83% at 428 nm and 32.41% at 420 nm, respectively, in an ionic liquid solution. Dual-type electrochromic devices (ECDs) that employ PDTC, PS2CBP, or PCEC film as an anodic layer, and PProDOT-Et₂ film as a cathodic layer, were constructed. The as-prepared PCEC/PProDOT-Et₂ ECD shows high optical contrast (38.25% at 586 nm) and high coloration efficiency (369.85 cm² C-1 at 586 nm), and the PS2CBP/PProDOT-Et₂ ECD shows high optical contrast (34.45% at 590 nm), good optical memory, and good long-term cycling stability.

| S-EPMC6431872 | biostudies-other

Risk of natural disturbances makes future contribution of Canada's forests to the global carbon cycle highly uncertain.

Project description:A large carbon sink in northern land surfaces inferred from global carbon cycle inversion models led to concerns during Kyoto Protocol negotiations that countries might be able to avoid efforts to reduce fossil fuel emissions by claiming large sinks in their managed forests. The greenhouse gas balance of Canada's managed forest is strongly affected by naturally occurring fire with high interannual variability in the area burned and by cyclical insect outbreaks. Taking these stochastic future disturbances into account, we used the Carbon Budget Model of the Canadian Forest Sector (CBM-CFS3) to project that the managed forests of Canada could be a source of between 30 and 245 Mt CO(2)e yr(-1) during the first Kyoto Protocol commitment period (2008-2012). The recent transition from sink to source is the result of large insect outbreaks. The wide range in the predicted greenhouse gas balance (215 Mt CO(2)e yr(-1)) is equivalent to nearly 30% of Canada's emissions in 2005. The increasing impact of natural disturbances, the two major insect outbreaks, and the Kyoto Protocol accounting rules all contributed to Canada's decision not to elect forest management. In Canada, future efforts to influence the carbon balance through forest management could be overwhelmed by natural disturbances. Similar circumstances may arise elsewhere if global change increases natural disturbance rates. Future climate mitigation agreements that do not account for and protect against the impacts of natural disturbances, for example, by accounting for forest management benefits relative to baselines, will fail to encourage changes in forest management aimed at mitigating climate change.

| S-EPMC2234182 | biostudies-literature

Extracellular matrix-based intracortical microelectrodes: Toward a microfabricated neural interface based on natural materials.

Project description:Extracellular matrix (ECM)-based implantable neural electrodes (NEs) were achieved using a microfabrication strategy on natural-substrate-based organic materials. The ECM-based design minimized the introduction of non-natural products into the brain. Further, it rendered the implants sufficiently rigid for penetration into the target brain region and allowed them subsequently to soften to match the elastic modulus of brain tissue upon exposure to physiological conditions, thereby reducing inflammatory strain fields in the tissue. Preliminary studies suggested that ECM-NEs produce a reduced inflammatory response compared with inorganic rigid and flexible approaches. In vivo intracortical recordings from the rat motor cortex illustrate one mode of use for these ECM-NEs.

| S-EPMC6258041 | biostudies-literature

Biocatalytic Synthesis and Polymerization via ROMP of New Biobased Phenolic Monomers: A Greener Process toward Sustainable Antioxidant Polymers.

Project description:Antioxidant norbornene-based monomers bearing biobased sterically hindered phenols (SHP)-NDF (norbornene dihydroferulate) and NDS (norbornene dihydrosinapate)-have been successfully prepared through biocatalysis from naturally occurring ferulic and sinapic acids, respectively, in presence of Candida antarctica Lipase B (Cal-B). The ring opening metathesis polymerization (ROMP) of these monomers was investigated according to ruthenium catalyst type (GI) vs. (HGII) and monomer to catalyst molar ratio ([M]/[C]). The co-polymerization of antioxidant functionalized monomer (NDF or NDS) and non-active norbornene (N) has also been performed in order to adjust the number of SHP groups present per weight unit and tune the antioxidant activity of the copolymers. The polydispersity of the resulting copolymers was readily improved by a simple acetone wash to provide antioxidant polymers with well-defined structures. After hydrogenation with p-toluenesulfonylhydrazine (p-TSH), the radical scavenging ability of the resulting saturated polymers was evaluated using ?,?-diphenyl-?-picrylhydrazyl (DPPH) analysis. Results demonstrated that polymers bearing sinapic acid SHP exhibited higher antiradical activity than the polymer bearing ferulic acid SHP. In addition it was also shown that only a small SHP content was needed in the copolymers to exhibit a potent antioxidant activity.

| S-EPMC5744638 | biostudies-literature

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