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Effect of Length of Cellulose Nanofibers on Mechanical Reinforcement of Polyvinyl Alcohol.

ABSTRACT: Cellulose nanofibers (CNF), representing the nano-structured cellulose, have attained an extensive research attention due to their sustainability, biodegradability, nanoscale dimensions, large surface area, unique optical and mechanical performance, etc. Different lengths of CNF can lead to different extents of entanglements or network-like structures through van der Waals forces. In this study, a series of polyvinyl alcohol (PVA) composite films, reinforced with CNF of different lengths, were fabricated via conventional solvent casting technique. CNF were extracted from jute fibers by tuning the dosage of sodium hypochlorite during the TEMPO-mediated oxidation. The mechanical properties and thermal behavior were observed to be significantly improved, while the optical transparency decreased slightly (Tr. > 75%). Interestingly, the PVA/CNF20 nanocomposite films exhibited higher tensile strength of 34.22 MPa at 2 wt% filler loading than the PVA/CNF10 (32.55 MPa) while displayed higher elastic modulus of 482.75 MPa than the PVA/CNF20 films (405.80 MPa). Overall, the findings reported in this study provide a novel, simple and inexpensive approach for preparing the high-performance polymer nanocomposites with tunable mechanical properties, reinforced with an abundant and renewable material.

SUBMITTER: Wang M

PROVIDER: S-EPMC8747125 | biostudies-literature |

REPOSITORIES: biostudies-literature

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