Performance Enhancement of Ionic Polymer-Metal Composite Actuators with Polyethylene Oxide.
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ABSTRACT:
SUBMITTER: Zhao D
PROVIDER: S-EPMC8747705 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:An ionic polymer-metal composite (IPMC) actuator composed of a thin perfluorinated ionomer membrane with electrodes plated on both surfaces undergoes a large bending motion when a low electric field is applied across its thickness. Such actuators are soft, lightweight, and able to operate in solutions and thus show promise with regard to a wide range of applications, including MEMS sensors, artificial muscles, biomimetic systems, and medical devices. However, the variations induced by changing the type of anion on the device deformation properties are not well understood; therefore, the present study investigated the effects of different anions on the ion exchange process and the deformation behavior of IPMC actuators with palladium electrodes. Ion exchange was carried out in solutions incorporating various anions and the actuator tip displacement in deionized water was subsequently measured while applying a step voltage. In the step voltage response measurements, larger anions such as nitrate or sulfate led to a more pronounced tip displacement compared to that obtained with smaller anions such as hydroxide or chloride. In AC impedance measurements, larger anions generated greater ion conductivity and a larger double-layer capacitance at the cathode. Based on these mechanical and electrochemical measurements, it is concluded that the presence of larger anions in the ion exchange solution induces a greater degree of double-layer capacitance at the cathode and results in enhanced tip deformation of the IPMC actuators.
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Project description:The presented research introduces a new Ionic Polymer-Metal-ZnO Composite (IPMZC) demonstrating photoluminescence (PL)-quenching on mechanical bending or application of an electric field. The newly fabricated IPMZC integrates the optical properties of ZnO and the electroactive nature of Ionic Polymer Metal Composites (IPMC) to enable a non-contact read-out of IPMC response. The electro-mechano-optical response of the IPMZC was measured by observing the PL spectra under mechanical bending and electrical regimes. The working range was measured to be 375-475 nm. It was noted that the PL-quenching increased proportionally with the increase in curvature and applied field at 384 and 468 nm. The maximum quenching of 53.4% was achieved with the membrane curvature of 78.74/m and 3.01% when electric field (12.5 × 10(3) V/m) is applied. Coating IPMC with crystalline ZnO was observed to improve IPMC transduction.
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Project description:Ionic polymer-metal composites (IPMCs) have recently received tremendous interest as soft biomimetic actuators and sensors in various bioengineering and human affinity applications, such as artificial muscles and actuators, aquatic propulsors, robotic end-effectors, and active catheters. Main challenges in developing biomimetic actuators are the attainment of high strain and actuation force at low operating voltage. Here we first report a nanostructured electrode surface design for IPMC comprising platinum nanothorn assemblies with multiple sharp tips. The newly developed actuator with the nanostructured electrodes shows a new way to achieve highly enhanced electromechanical performance over existing flat-surfaced electrodes. We demonstrate that the formation and growth of the nanothorn assemblies at the electrode interface lead to a dramatic improvement (3- to 5-fold increase) in both actuation range and blocking force at low driving voltage (1-3 V). These advances are related to the highly capacitive properties of nanothorn assemblies, increasing significantly the charge transport during the actuation process.
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Project description:A polyvinylidene fluoride, sulfonated graphene oxide composite membrane coated with polypyrrole (Ppy) and platinum metal (Pt) was fabricated. The Fourier-transform infrared (FTIR) spectroscopic analysis was done to analyze the functional groups present in the composite material. Deposition of PPy/Pt electrode and surface morphology of PVDF/SGO/Pt/PPy was confirmed by scanning electron microscopic (SEM) images. The capacity of ion exchange and proton conductivity (PC) of PVDF/SGO/Pt/PPy were 1.4 meq g-1 of dry ion exchanger and 4.251 × 10-2 S cm-1, respectively. A two-link flexible manipulator based on the fabricated ionic polymer metal composite (IPMC) membranes was also developed where the electromechanical behaviour of a polymer-based actuator provides an important step in robotics applications.
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Project description:Throat sensing has received increasing demands in recent years, especially for oropharyngeal treatment applications. The conventional videofluoroscopy (VFS) approach is limited by either exposing the patient to radiation or incurring expensive costs on sophisticated equipment as well as well-trained speech-language pathologists. Here, we propose a smart and non-invasive throat sensor that can be fabricated using an ionic polymer-metal composite (IPMC) material. Through the cation's movement inside the IPMC material, the sensor can detect muscle movement at the throat using a self-generated signal. We have further improved the output responses of the sensor by coating it with a corrosive-resistant gold material. A support vector machine algorithm is used to train the sensor in recognizing the pattern of the throat movements, with a high accuracy of 95%. Our proposed throat sensor has revealed its potential to be used as a promising solution for smart healthcare devices, which can benefit many practical applications such as human-machine interactions, sports training, and rehabilitation.
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Project description:Controllable linear actuation of polypyrrole (PPy) is the envisaged goal where only one ion dominates direction (here anions) in reversible redox cycles. PPy with polyethylene oxide (PEO) doped with dodecylbenzenesulfonate forms PPy-PEO/DBS films (PPy-PEO), which are applied in propylene carbonate (PC) solvent with electrolytes such as 1-ethyl-2,3-dimethylimidazolium trifluoromethanesulfonate (EDMICF3SO3), sodium perchlorate (NaClO4) and tetrabutylammonium hexafluorophosphate (TBAPF6) and compared in their linear actuation properties with pristine PPy/DBS samples. PPy-PEO showed for all applied electrolytes that only expansion at oxidation appeared in cyclic voltammetric studies, while pristine PPy/DBS had mixed-ion actuation in all electrolytes. The electrolyte TBAPF6-PC revealed for PPy-PEO best results with 18% strain (PPy/DBS had 8.5% strain), 2 times better strain rates, 1.8 times higher electronic conductivity, 1.4 times higher charge densities and 1.5 times higher diffusion coefficients in comparison to PPy/DBS. Long-term measurements up to 1000 cycles at 0.1 Hz revealed strain over 4% for PPy-PEO linear actuators, showing that combination of PPy/DBS with PEO gives excellent material for artificial muscle-like applications envisaged for smart textiles and soft robotics. FTIR and Raman spectroscopy confirmed PEO content in PPy. Electrochemical impedance spectroscopy (EIS) of PPy samples revealed 1.3 times higher ion conductivity of PPy-PEO films in PC solvent. Scanning electron microscopy (SEM) was used to investigate morphologies of PPy samples, and EDX spectroscopy was conducted to determine ion contents of oxidized/reduced films.
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Project description:Ionic polymer-metal composites (IPMCs) have attracted attention in recent years due to their integration of actuation and sensing functions. As one of the main sensing functions of IPMCs, humidity sensing has been of consistent interest in wearable health monitors and artificial skin. However, there are still some technical challenges in that classical IPMCs have poor humidity sensing performance due to their dense surface electrode, and IPMCs are damaged easily due to an electrode/membrane mismatch. In this work, through the spraying and electrodepositing process, we developed an efficient method to rapidly prepare a Au-shell-Ag-NW (silver nanowire)-based IPMC with high strength, low surface resistance and excellent humidity sensing performance. Meanwhile, we optimized the preparation method by clarifying the influence of solvent type and electrodepositing time on the performance of the Au-shell-Ag-NW-based IPMC, thus effectively improving the humidity sensing effect and strength of the IPMC. Compared with previous research, the humidity electrical response (~9.6 mV) of the Au-shell-Ag-NW-based IPMC is at least two orders of magnitude higher than that of the classical IPMC (~0.41 mV), which is mainly attributed to the sparse gap structure for promoting the exchange of water molecules in the environment and Nafion membrane, a low surface resistance (~3.4 Ohm/sq) for transmitting the signal, and a seamless connection between the electrode and Nafion membrane for fully collecting the ion charges in the Nafion membrane. Additionally, the Au-shell-Ag-NW-based IPMC could effectively monitor the human breathing process, and the humidity sensing performance did not change after being exposed to the air for 4 weeks, which further indicates that the Au-shell-Ag-NW-based IPMC has good application potential due to its efficient preparation technology, high stability and good reproducibility.
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Project description:Flexible electronics has received widespread concern and research. As a most-fundamental step and component, polymer metallization to introduce conductive electrode is crucial in successful establishment and application of flexible and stretchable electronic system. Ionic polymer-metal composite (IPMC) is such an attractive flexible mechanical sensor with significant advantages of passive and space-discriminative capability. Generally, the IPMC sensor is fabricated by the electroless plating method to form structure of ionic polymer membrane sandwiched with two metallic electrodes. In order to obtain high-quality interface adhesion and conductivity between polymer and metal, the plating process for IPMC sensor is usually time-consuming and uncontrollable and has low reproducibility, which make it difficult to use in practice and in large-scale. Here, a manufacturable method and equipment with short processing time and high reproducibility for fabricating IPMC sensors by in situ plasma etching and magnetron sputtering depositing on flexible substrates is developed. First, the new method shortens the fabrication period greatly from 2 weeks to 2 h to obtain IPMC sensors with sizes up to 9 cm × 9 cm or arrays in various patterns. Second, the integrated operation ensures all sample batch stability and performance repeatability. In a typical IPMC sensor, nearly 200 mV potential signal due to ion redistribution induced by bending strain under 1.6% can be produced without any external power supply, which is much higher than the traditional electroless plating sensor. This work verified that the in situ plasma etching and magnetron sputtering deposition could significantly increase the interface and surface conductivity of the flexible devices, resulting in the present high sensitivity as well as linear correlation with strain of the IPMC sensor. Therefore, this introduced method is scalable and believed to be used to metalize flexible substrates with different metals, providing a new route to large-scale fabrication of flexible devices for potential wearable applications in real-time monitoring human motion and human-machine interaction.
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