Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Safe and Stable Lithium Metal Batteries Enabled by an Amide-Based Electrolyte.

ABSTRACT:

Highlights

A novel amide-based nonflammable electrolyte is proposed. The formation mechanism and solvation chemistry are investigated by molecular dynamics simulations and density functional theory. An inorganic/organic-rich solid electrolyte interphase with an abundance of LiF, Li₃N and Li-N-C is in situ formed, leading to spherical lithium deposition. The amide-based electrolyte can enable stable cycling performance at room temperature and 60 ℃. The formation of lithium dendrites and the safety hazards arising from flammable liquid electrolytes have seriously hindered the development of high-energy-density lithium metal batteries. Herein, an emerging amide-based electrolyte is proposed, containing LiTFSI and butyrolactam in different molar ratios. 1,1,2,2-Tetrafluoroethyl-2,2,3,3-tetrafluoropropylether and fluoroethylene carbonate are introduced into the amide-based electrolyte as counter solvent and additives. The well-designed amide-based electrolyte possesses nonflammability, high ionic conductivity, high thermal stability and electrochemical stability (> 4.7 V). Besides, an inorganic/organic-rich solid electrolyte interphase with an abundance of LiF, Li₃N and Li-N-C is in situ formed, leading to spherical lithium deposition. The formation mechanism and solvation chemistry of amide-based electrolyte are further investigated by molecular dynamics simulations and density functional theory. When applied in Li metal batteries with LiFePO₄ and LiMn₂O₄ cathode, the amide-based electrolyte can enable stable cycling performance at room temperature and 60 ℃. This study provides a new insight into the development of amide-based electrolytes for lithium metal batteries.

SUBMITTER: Wu W

PROVIDER: S-EPMC8753956 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Nonflammable quasi-solid-state electrolyte for stable lithium-metal batteries.

Project description:Rechargeable lithium batteries with high-voltage/capacity cathodes are regarded as promising high-energy-density energy-storage systems. Nevertheless, these systems are restricted by some critical challenges, such as flammable electrolyte, lithium dendrite formation and rapid capacity fade at high voltage and elevated temperature. In this work, we report a quasi-solid-state composite electrolyte (QCE) prepared by in situ polymerization reactions. The electrolyte consists of polymer matrix, inorganic filler, nonflammable plasticizers and Li salt, and shows a good thermal stability, a moderate ionic conductivity of 2.8 × 10-4 S cm-1 at 25 °C, and a wide electrochemical window up to 6.7 V. The batteries with the QCE show good electrochemical performance when coupled with lithium metal anode and LiCoO2 or LiNi0.8Mn0.1Co0.1O2 cathodes. Pouch-type batteries with the QCE also exhibit stable cycling, and can tolerate abuse testes such as folding, cutting and nail penetration. The in situ formed fluorides and phosphides from the plasticizers stabilize the interfaces between the QCE and electrodes, which enables stable cycling of Li metal batteries.

| S-EPMC9076527 | biostudies-literature

Interface chemistry of an amide electrolyte for highly reversible lithium metal batteries.

Project description:Metallic lithium is a promising anode to increase the energy density of rechargeable lithium batteries. Despite extensive efforts, detrimental reactivity of lithium metal with electrolytes and uncontrolled dendrite growth remain challenging interconnected issues hindering highly reversible Li-metal batteries. Herein, we report a rationally designed amide-based electrolyte based on the desired interface products. This amide electrolyte achieves a high average Coulombic efficiency during cycling, resulting in an outstanding capacity retention with a 3.5 mAh cm-2 high-mass-loaded LiNi0.8Co0.1Mn0.1O2 cathode. The interface reactions with the amide electrolyte lead to the predicted solid electrolyte interface species, having favorable properties such as high ionic conductivity and high stability. Operando monitoring the lithium spatial distribution reveals that the highly reversible behavior is related to denser deposition as well as top-down stripping, which decreases the formation of porous deposits and inactive lithium, providing new insights for the development of interface chemistries for metal batteries.

| S-EPMC7442789 | biostudies-literature

Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries.

Project description:The electrochemical instability of ether-based electrolyte solutions hinders their practical applications in high-voltage Li metal batteries. To circumvent this issue, here, we propose a dilution strategy to lose the Li+/solvent interaction and use the dilute non-aqueous electrolyte solution in high-voltage lithium metal batteries. We demonstrate that in a non-polar dipropyl ether (DPE)-based electrolyte solution with lithium bis(fluorosulfonyl) imide salt, the decomposition order of solvated species can be adjusted to promote the Li+/salt-derived anion clusters decomposition over free ether solvent molecules. This selective mechanism favors the formation of a robust cathode electrolyte interphase (CEI) and a solvent-deficient electric double-layer structure at the positive electrode interface. When the DPE-based electrolyte is tested in combination with a Li metal negative electrode (50 μm thick) and a LiNi0.8Co0.1Mn0.1O2-based positive electrode (3.3 mAh/cm2) in pouch cell configuration at 25 °C, a specific discharge capacity retention of about 74% after 150 cycles (0.33 and 1 mA/cm2 charge and discharge, respectively) is obtained.

| S-EPMC9935899 | biostudies-literature

A Fiber-Based 3D Lithium Host for Lean Electrolyte Lithium Metal Batteries.

Project description:3D hosts are promising to extend the cycle life of lithium metal anodes but have rarely been implemented with lean electrolytes thus impacting the practical cell energy density. To overcome this challenge, a 3D host that is lightweight and easy to fabricate with optimum pore size that enables full utilization of its pore volume, essential for lean electrolyte operations, is reported. The host is fabricated by casting a VGCF (vapor-grown carbon fiber)-based slurry loaded with a sparingly soluble rubidium nitrate salt as an additive. The network of fibers generates uniform pores of ≈3 µm in diameter with a porosity of 80%, while the nitrate additive enhances lithiophilicity. This 3D host delivers an average coulombic efficiency of 99.36% at 1 mA cm-2 and 1 mAh cm-2 for over 860 cycles in half-cell tests. Full cells containing an anode with 1.35-fold excess lithium paired with LiNi0.8 Mn0.1 Co0.1 O2 (NMC811) cathodes exhibit capacity retention of 80% over 176 cycles at C/2 under a lean electrolyte condition of 3 g Ah-1 . This work provides a facile and scalable method to advance 3D lithium hosts closer to practical lithium-metal batteries.

| S-EPMC8981896 | biostudies-literature

Highly Conductive Polyoxanorbornene-Based Polymer Electrolyte for Lithium-Metal Batteries.

Project description:This present study illustrates the synthesis and preparation of polyoxanorbornene-based bottlebrush polymers with poly(ethylene oxide) (PEO) side chains by ring-opening metathesis polymerization for solid polymer electrolytes (SPE). In addition to the conductive PEO side chains, the polyoxanorbornene backbones may act as another ion conductor to further promote Li-ion movement within the SPE matrix. These results suggest that these bottlebrush polymer electrolytes provide impressively high ionic conductivity of 7.12 × 10-4 S cm-1 at room temperature and excellent electrochemical performance, including high-rate capabilities and cycling stability when paired with a Li metal anode and a LiFePO4 cathode. The new design paradigm, which has dual ionic conductive pathways, provides an unexplored avenue for inventing new SPEs and emphasizes the importance of molecular engineering to develop highly stable and conductive polymer electrolytes for lithium-metal batteries (LMB).

| S-EPMC10520635 | biostudies-literature

Concentrated LiODFB Electrolyte for Lithium Metal Batteries.

Project description:Nowadays, lithium (Li) metal batteries arouse widespread concerns due to its ultrahigh specific capacity (3,860 mAh g-1). However, the growth of Li dendrites has always limited their industrial development. In this paper, the use of concentrated electrolyte with lithium difluoro(oxalate)borate (LiODFB) salt in 1, 2-dimethoxyethane (DME) enables the good cycling of a Li metal anode at high Coulombic efficiency (up to 98.1%) without dendrite growth. Furthermore, a Li/Li cell can be cycled at 1 mA cm-2 for over 3,000 h. Besides, compared to conventional LiPF6-carbonate electrolyte, Li/LiFePO4 cells with 4 M LiODFB-DME exhibit superior electrochemical performances, especially at high temperature (65°C). These outstanding performances can be certified to the increased availability of Li+ concentration and the merits of LiODFB salt. We believe that the concentrated LiODFB electrolyte is help to enable practical applications for Li metal anode in rechargeable batteries.

| S-EPMC6657587 | biostudies-literature

Self-healing solid polymer electrolyte based on imine bonds for high safety and stable lithium metal batteries.

Project description:Due to their low flammability, good dimensional stability and chemical stability, solid polymer electrolytes are currently attracting extensive interest for building lithium metal batteries. But severe safety issues such as cracks or breakage, resulting in short circuits will prevent their widespread application. Here, we report a new design of self-healing solid polymer electrolyte (ShSPE) based on imine bonds, fabricated from varying amounts of polyoxyethylenebis(amine) and terephthalaldehyde through a simple Schiff base reaction. Moreover, adding diglycidyl ether of bisphenol A improves the flexibility and high stretchability of the polymer electrolyte. The polymer networks exhibit good thermal stability and excellent self-healing characteristics. The ShSPE with the highest NH2-PEG-NH2 content (ShSPE-3) has an improved lithium ion transference number of 0.39, and exhibits an electrochemical stability up to 4.5 V vs. Li/Li+. ShSPE-3 shows the highest ionic conductivity of 1.67 × 10-4 S cm-1 at 60 °C. Besides, the interfacial stability of ShSPE-3 is promoted and the electrolyte membrane exhibits good cycling performance with LiFePO4, and the LiFePO4/Li cell exhibits an initial discharge capacity of 141.3 mA h g -1. These results suggest that self-healing solid polymer electrolytes are promising candidates for high safety and stable lithium metal batteries.

| S-EPMC8694013 | biostudies-literature

Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries

Project description:Fluorination of ether solvents is an effective strategy to improve the electrochemical stability of non-aqueous electrolyte solutions in lithium metal batteries. However, excessive fluorination detrimentally impacts the ionic conductivity of the electrolyte, thus limiting the battery performance. Here, to maximize the electrolyte ionic conductivity and electrochemical stability, we introduce the targeted trifluoromethylation of 1,2-dimethoxyethane to produce 1,1,1-trifluoro-2,3-dimethoxypropane (TFDMP). TFDMP is used as a solvent to prepare a 2 M non-aqueous electrolyte solution comprising bis(fluorosulfonyl)imide salt. This electrolyte solution shows an ionic conductivity of 7.4 mS cm–1 at 25 °C, an oxidation stability up to 4.8 V and an efficient suppression of Al corrosion. When tested in a coin cell configuration at 25 °C using a 20 μm Li metal negative electrode, a high mass loading LiNi0.8Co0.1Mn0.1O2-based positive electrode (20 mg cm–2) with a negative/positive (N/P) capacity ratio of 1, discharge capacity retentions (calculated excluding the initial formation cycles) of 81% after 200 cycles at 0.1 A g–1 and 88% after 142 cycles at 0.2 A g–1 are achieved. Fluorination of solvents, useful for non-aqueous lithium-based batteries, improves the electrochemical stability but decreases the ionic conductivity. Here, the authors report a targeted functionalization of an ether solvent to balance the electrolyte ionic conductivity and oxidative stability.

| S-EPMC9849263 | biostudies-literature

Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries.

Project description:Lithium metal is a promising anode candidate for the next-generation rechargeable battery due to its highest specific capacity (3860 mA h g-1) and lowest potential, but low Coulombic efficiency and formation of lithium dendrites hinder its practical application. Here, we report a self-formed flexible hybrid solid-electrolyte interphase layer through co-deposition of organosulfides/organopolysulfides and inorganic lithium salts using sulfur-containing polymers as an additive in the electrolyte. The organosulfides/organopolysulfides serve as "plasticizer" in the solid-electrolyte interphase layer to improve its mechanical flexibility and toughness. The as-formed robust solid-electrolyte interphase layers enable dendrite-free lithium deposition and significantly improve Coulombic efficiency (99% over 400 cycles at a current density of 2 mA cm-2). A lithium-sulfur battery based on this strategy exhibits long cycling life (1000 cycles) and good capacity retention. This study reveals an avenue to effectively fabricate stable solid-electrolyte interphase layer for solving the issues associated with lithium metal anodes.The practical application of lithium metal anodes suffers from the poor Coulombic efficiency and growth of lithium dendrites. Here, the authors report an approach to enable the self-formation of stable and flexible solid-electrolyte interphase layers which serve to address both issues.

| S-EPMC5636837 | biostudies-literature

A new ether-based electrolyte for dendrite-free lithium-metal based rechargeable batteries.

Project description:A new ether-based electrolyte to match lithium metal electrode is prepared by introducing 1, 4-dioxane as co-solvent into lithium bis(fluorosulfonyl)imide/1,2-dimethoxyethane solution. Under the synergetic effect of solvents and salt, this simple liquid electrolyte presents stable Li cycling with dendrite-free Li deposition even at relatively high current rate, high coulombic efficiency of ca. 98%, and good anodic stability up to ~4.87 V vs Li RE. Its excellent performance will open up a new possibility for high energy-density rechargeable Li metal battery system.

| S-EPMC4754942 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data