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Kinetic Study on High-Temperature H2S Removal over Mn-Based Regenerable Sorbent Using Deactivation Model.


ABSTRACT: The kinetics of high-temperature H2S removal over Mn/Al sorbents prepared by co-precipitation method was investigated in a fixed-bed reactor using a deactivation model. The initial sorption rate constant (k 0), deactivation rate constant (k d), apparent activation energy (E a), and deactivation energy (E d) were obtained. The k 0 and k d values of Mn/Al sorbents are much higher than those of pure Mn2O3. This indicates that Mn/Al sorbents have higher reactivity on the removal of H2S and less diffusion resistance caused by the formation of the sulfided product. The E a and E d values for the sorbent with the Mn content (wt %) of 35.4% are 38.18 and 31.05 kJ/mol, respectively. The deactivation model gives excellent predictions for the H2S breakthrough curves in the sulfidation-regeneration process.

SUBMITTER: Wang J 

PROVIDER: S-EPMC8792942 | biostudies-literature |

REPOSITORIES: biostudies-literature

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